Chemistry

120 Articles

As Light As Plastic; As Strong As Steel

February 7, 2022 by 38 Comments

Chemical engineers at MIT have pulled off something that was once thought impossible. By polymerizing material in two different directions at once, they have created a polymer that is very strong. You can read a pre-print version of the paper over on Arxiv.

Polymers owe many of their useful properties to the fact that they make long chains. Molecules known as monomers join together in strings held together by covalent bonds. Polymer chains may be cross-linked which changes its properties, but it has long been thought that material that had chains going through the X and Y axis would have desirable properties, but making these reliably is a challenge.

Part of the problem is that it is hard to line up molecules, even large monomers. If one monomer in the chain rotates a bit, it will create a defect in the 2D structure and that defect will grow rapidly as you add more monomers. The new technique is relatively easy to do and is irreversible which is good because reversible chains tend to have undesirable characteristics like low chemical stability. Synthesis does require a few chemicals like melamine, calcium chloride, pyridine, and trimesic acid. Along with N-Methyl-2-pyrrolidone, the mixture eventually forms a gel. The team took pieces of gel and soaked it in ethanol. With some filtering, ultrasonics, centrifuging, and washing with water and acetone, the material was ready for vacuum drying and was made into a powder.

The powder is dissolved in acid and placed on a spinning silicon wafer to form a polymerized nanofilm. Other 2D films have been produced, of course, such as graphene, but polymer films may have a number of applications. In particular, in contrast to conventional polymers, sheets of this material are impermeable to gas and liquid, which could make it very useful as a coating.

According to the MIT press release, the film’s elastic modulus is about four and six times greater than that of bulletproof glass. The amount of force required to break the material is about twice that of steel. It doesn’t sound like this material will be oozing out of our 3D printers anytime soon. But maybe one day you’ll be able to get 2D super-strong resin.

For all their faults, conventional polymers changed the world as we know it. Some polymers occur naturally, and some use natural ingredients, too.

Screenshot from the video in question, showing 12:54 of the video, demonstrating how the electrons are being exchanged when circuit is completed

Li-ion Battery Low-Level Intricacies Explained Excellently

December 21, 2021 by 7 Comments

There’s a lot of magic in Lithium-ion batteries that we typically take for granted and don’t dig deeper into. Why is the typical full charge voltage 4.2 V and not the more convenient 5 V, why is CC/CV charging needed, and what’s up with all the fires? [The Limiting Factor] released a video that explains the low-level workings of Lithium-ion batteries in a very accessible way – specifically going into ion and electron ion exchange happening between the anode and the cathode, during both the charge and the discharge cycle. The video’s great illustrative power comes from an impressively sized investment of animation, script-writing and narration work – [The Limiting Factor] describes the effort as “16 months of animation design”, and this is no typical “whiteboard sketch” explainer video.

This is 16 minutes of pay-full-attention learning material that will have you glued to your screen, and the only reason it doesn’t explain every single thing about Lithium-ion batteries is because it’s that extensive of a topic, it would require a video series when done in a professional format like this. Instead, this is an excellent intro to help you build a core of solid understanding when it comes to Li-ion battery internals, elaborating on everything that’s relevant to the level being explored – be it the SEI layer and the organic additives, or the nitty-gritty of the ion and electron exchange specifics. We can’t help but hope that more videos like this one are coming soon (or as soon as they realistically can), expanding our understanding of all the other levels of a Li-ion battery cell.

Last video from [The Limiting Factor] was an 1-hour banger breaking down all the decisions made in a Tesla Battery Day presentation in similarly impressive level of detail, and we appreciate them making a general-purpose insight video – lately, it’s become clear we need to go more in-depth on such topics. This year, we’ve covered a great comparison between supercapacitors and batteries and suitable applications for each one of those, as well as explained the automakers’ reluctance to make their own battery cells. In 2020, we did a breakdown of alternate battery chemistries that aim to replace Li-ion in some of its important applications, so if this topic catches your attention, check those articles out, too!

Continue reading “Li-ion Battery Low-Level Intricacies Explained Excellently” →

Plastics: Photopolymers For 3D Printing And Beyond

December 21, 2021 by 9 Comments

Chances are good that if you’ve done any 3D printing, it was of the standard fused deposition modeling variety. FDM is pretty simple stuff — get a bit of plastic filament hot enough, squeeze the molten goo out of a fine nozzle, control the position of the nozzle more or less precisely in three dimensions, and repeat for hours on end until your print is done. To the outsider it looks like magic, but to us it’s just another Saturday afternoon.

Resin printing is another thing altogether, and a lot closer to magic for most of us. The current crop of stereolithography printers just have a high-resolution LCD display between a UV light source and a build tank with a transparent bottom. Prints are built up layer by layer by flashing UV light patterns into the tank as a build plate slowly lifts it up from the resin, like some creature emerging from the primordial goo.

Of course it’s all just science, but if there is any magic in SLA printing, surely it’s in the resins used for it. Their nondescript brown plastic bottles and information-poor labels give little clue as to their ingredients, although their hydrocarbon reek and viscous, sticky texture are pretty good clues. Let’s take a look inside the resin bottle and find out what it is that makes the magic of SLA happen.

Continue reading “Plastics: Photopolymers For 3D Printing And Beyond” →

Water beading up on a feather

PFAS: The Organofluorines Your Biochemist Warned You About

November 22, 2021 by 49 Comments

Sometimes it begins to feel like a tradition that a certain substance or group of substances become highly popular due to certain highly desirable chemical or physical properties, only for these chemicals then to go on to turn out to form a hazard to the biosphere, human life, or both. In the case of per- and polyfluoroalkyl substances (PFAS) it’s no different. Upon the discovery that a subgroup of these – the fluorosurfactants – have the ability to reduce water surface tension significantly more than other surfactants, they began to be used everywhere.

Today, fluorosurfactants are being used in everything from stain repellents to paint, make-up, and foam used by firefighters. In a recent study of 231 cosmetic products bought in the US and Canada (Whitehead et al., 2021), it was found that all of them contained PFAS, even when not listed on the packaging. The problematic part here is that PFASs are very stable, do not decay after disposal, and bioaccumulate in the body where they may have endocrine-disrupting effects.

Some areas have now at least partially banned PFAS, but the evidence for this is so far mixed. Let’s review what we do know at this point, and which alternatives we have to continuing to use these substances. Continue reading “PFAS: The Organofluorines Your Biochemist Warned You About” →

The (Sodium Chloride) Crystal Method

November 20, 2021 by 25 Comments

[Chase’s] post titled “How to Grow Sodium Chloride Crystals at Home” might as well be called “Everything You Always Wanted to Know about Salt Crystals (but Were Afraid to Ask).” We aren’t sure what the purpose of having transparent NaCl crystals are, but we have to admit, they look awfully cool.

Sodium chloride, of course, is just ordinary table salt. If the post were simply about growing random ugly crystals, we’d probably have passed over it. But these crystals — some of them pretty large — look like artisan pieces of glasswork. [Chase] reports that growing crystals looks easy, but growing attractive crystals can be hard because of temperature, dust, and other factors.

You probably have most of what you need. Table salt that doesn’t include iodine, a post, a spoon, a funnel, filter paper, and some containers. You’ll probably want tweezers, too. The cooling rate seems to be very important. There are pictures of what perfect seed crystals look like and what happens when the crystals form too fast. Quite a difference! Once you find a perfectly square and transparent seed crystal, you can use it to make bigger ones.

After the initial instructions, there is roughly half the post devoted to topics like the effect growth rate has on the crystal along with many pictures. There are also notes on how to form the crystals into interesting shapes like stars and pyramids. You can also see what happens if you use iodized salt.

If salt is too tame for you, try tin. Or opt for copper, if you prefer that.

A Fascinating Plot Twist As Researchers Recreate Classic “Primordial Soup” Experiment

October 31, 2021 by 46 Comments

Science is built on reproducibility; if someone else can replicate your results, chances are pretty good that you’re looking at the truth. And there’s no statute of limitations on reproducibility; even experiments from 70 years ago are fair game for a fresh look. A great example is this recent reboot of the 1952 Miller-Urey “primordial soup” experiment which ended up with some fascinating results.

At the heart of the Miller-Urey experiment was a classic chicken-and-the-egg paradox: complex organic molecules like amino acids and nucleic acids are the necessary building blocks of life, but how did they arise on Earth before there was life? To answer that, Stanley Miller, who in 1952 was a graduate student of Harold Urey,  devised an experiment to see if complex molecules could be formed from simpler substances under conditions assumed to have been present early in the planet’s life. Miller assembled a complicated glass apparatus, filled it with water vapor and gasses such as ammonia, hydrogen, and methane, and zapped it with an electric arc to simulate lightning. He found that a rich broth of amino acids accumulated in the reaction vessel; when analyzed, the sludge was found to contain five of the 20 amino acids.

The Miller-Urey experiment has been repeated over and over again with similar results, but a recent reboot took a different tack and looked at how the laboratory apparatus itself may have influenced the results. Joaquin Criado-Reyes and colleagues found that when run in a Teflon flask, the experiment produced far fewer organic compounds. Interestingly, adding chips of borosilicate glass to the Teflon reaction chamber restored the richness of the resulting broth, suggesting that the silicates in the glassware may have played a catalytic role in creating the organic soup. They also hypothesize that the highly alkaline reaction conditions could create microscopic pits in the walls of the glassware, which would serve as reaction centers to speed up the formation of organics.

This is a great example of a finding that seems to knock a hole in a theory but actually ends up supporting it. On the face of it, one could argue that Miller and Urey were wrong since they only produced organics thanks to contamination from their glassware. And it appears to be true that silicates are necessary for the abiotic generation of organic molecules. But if there was one thing that the early Earth was rich in, it was silicates, in the form of clay, silt, sand, rocks, and dust. So this experiment lends support to the abiotic origin of organic molecules on Earth, and perhaps on other rocky worlds as well.

[Featured image credit: Roger Ressmeyer/CORBIS, via Science History Institute]

Google’s Periodic Table

August 13, 2021 by 43 Comments

One of the nice things about the Internet is that you don’t need huge reference books anymore. You really don’t need big wall charts, either. A case in point: what science classroom didn’t have a periodic table of the elements? Now you can just look up an interactive one from Google. They say it is 3D and we suppose that’s the animations of the Bohr model for each atom. You can debate if it is a good idea to show people Bohr models or not, but it is what most of us learned, after all.

While the website is probably aimed more at students, it is a handy way to look up element properties and it is visually attractive, too. You probably remember, the columns are no accident in a periodic table, so the actual format doesn’t vary from one instance of it to another. However, we liked the col coding and the information panel that appears when you click on an element.

Continue reading “Google’s Periodic Table” →