Processing of PP/MWCNT nanocomposites and coating them with plasmonic NPs. (Credit: Sara Fateixa et al., 2023)

Affordably Detecting Water Pollutants Using 3D Printed Lattices And Plasmonic Nanoparticles

June 10, 2023 by Maya Posch 6 Comments

Although detecting pollution in surface waters has become significantly easier over the years, testing for specific pollutants still requires the taking of samples that are then sent to a laboratory for analysis. For something like detecting pesticide run-off, this can be a cumbersome and expensive procedure. But a 3D printed sensor demonstrated by [Sara Fateixa] and international colleagues offers hope that such tests can soon be performed in the field. The most expensive part of this setup is the portable Raman spectrometer that is used to detect the adsorbed molecules on the printed test strips.

The printed structure itself forms a plasmonic structure with gold or silver as the plasmonic metals deposited on the polypropylene (PP) and multi-walled carbon nanotube (MWCNT, 4% by weight) material. The mixture of PP and MWCNTs is to use both the bio-compatible properties of the former, while using the latter to make the PP significantly easier to print with and enhancing its mechanical properties.

Hamamatsu Raman Spectroscopy SERS Detection Module C13560.

For the experiment, researchers used a few prepared sensors to detect herbicides, including paraquat. This herbicide is cheap, widely used, and banned in various countries. After dissolving it in low concentrations in both tap water and sea water, a 3D printed sensor with Ag coating was was exposed to each sample before being left to dry at room temperature. Afterwards a Hamamatsu C13560 portable Raman spectrometer was used to analyze the sensors using surface-enhanced Raman scattering (SERS). The combination of plasmonic structures and Raman scattering means a significantly enhanced sensitivity, on the order of singular molecules, and is what makes SERS such a useful analytical technique.

In the resulting scan results, the herbicides showed up clearly, and further long-duration testing of newly printed sensors showed them to be very stable, even after 150 days of being stored. This makes it a promising new way to affordably and quickly perform tests for pollution, requiring only minimal local infrastructure to produce and analyze the sensors.

Heading: Processing of PP/MWCNT nanocomposites and coating them with plasmonic NPs. (Credit: Sara Fateixa et al., 2023)

Tree Planting Festivals, Air Cannons, Self-Burying Seeds, And The Complexities Of Reforestation

June 8, 2023 by Maya Posch 20 Comments

At first glance the problem of how to plant trees would seem to be a straightforward one: take a seed, jam it into the soil and let nature take its course. Or alternatively do much the same with a sapling that already got a start in a nice, comfortable greenhouse before leaving it to its own devices. To the average person this is generally the point where it’s considered a ‘done deal’, but one only has to take a look at the average survival rate of saplings out in the wild to perish that thought.

Each environment offers its own set of challenges when it comes to reforestation, which can perhaps be considered ironic as many of these trees are being planted where forests used to be, albeit centuries ago in many cases. There are the easy spots, such as flat fields, with rich soil, ample rain and mild weather, to the challenging terrain of Iceland, or mountainous terrain. Here the logistics are challenging and where once rich forests flourished, the very landscape seems adamant to reject this botanic intrusion.

Further complicating matters here are the myriad of reasons why we’re looking at planting so many new trees that it has even become an internet thing, as with the 2019 ‘Team Trees’ 20 million new trees challenge. So how did we get here, why exactly are we doing all of this, and how much of these attempts do bear fruit?

Continue reading “Tree Planting Festivals, Air Cannons, Self-Burying Seeds, And The Complexities Of Reforestation” →

Royal Navy Tests Quantum Navigation

June 7, 2023 by Al Williams 33 Comments

GPS has changed the way we get around the globe. But if you command a warship, you must think about what you would do if an adversary destroyed or compromised your GPS system. The Royal Navy and Imperial College London think a quantum navigation system might be the answer.
Of course, Heisenberg says you can’t know your speed and position simultaneously. But at the real-world level, you can apparently get close enough. The quantum sensors in question are essentially accelerometers. Unlike conventional accelerometers, though, these devices use ultracold atoms to make very precise measurements using a laser optical ruler, which means they do not drift as rapidly as, say, the accelerometer in your phone. Navigating with accelerometers is well understood, but the issue is how often you have to correct your computed position with an actual reference due to drift and other error accumulation. You can see a Sky News report on the trial below. Continue reading “Royal Navy Tests Quantum Navigation” →

The Integral Molten Salt Reactor And The Benefits Of Having A Liquid Fission Reactor

June 7, 2023 by Maya Posch 48 Comments

Although to most the term ‘fission reactor’ brings to mind something close to the commonly operated light-water reactors (LWRs) which operate using plain water (H₂O) as coolant and with sluggish, thermal neutrons, there are a dizzying number of other designs possible. Some of these have been in use for decades, like Canada’s heavy water (D₂O) reactors (CANDU), while others are only now beginning to take their first step towards commercialization.

These include helium-cooled, high-temperature reactors like China’s HTR-PM, but also a relatively uncommon type developed by Terrestrial Energy, called the Integral Molten Salt Reactor (IMSR). This Canadian company recently passed phase 2 of the Canadian Nuclear Safety Commission’s (CNSC) pre-licensing vendor review. What makes the IMSR so interesting is that as the name suggests, it uses molten salts: both for coolant and the low-enriched uranium fuel, while also breeding fuel from fertile isotopes that would leave an LWR as part of its spent fuel.

So why would you want your fuel to be fluid rather than a solid pellet like in most reactors today?

Continue reading “The Integral Molten Salt Reactor And The Benefits Of Having A Liquid Fission Reactor” →

Microsculptures 3D Printed With Advanced Macromolecular “Inks”

June 5, 2023 by Lewin Day 3 Comments

When we think about 3D printing, our mind often jumps to hot nozzles squirting out molten plastic. Other popular techniques include flashing bright light into resin, or using lasers to fuse together metal powders. All these techniques are great at producing parts with complicated geometries at desktop scales.

However, it’s also possible to 3D print at altogether microscopic scales. Researchers in Germany have now developed advanced macromolecular “inks” that can be used to create microscopic 3D sculptures with finer control than ever before.

Continue reading “Microsculptures 3D Printed With Advanced Macromolecular “Inks”” →

3D Printing Safety (According To The UL)

June 4, 2023 by Al Williams 17 Comments

If you want to start a heated discussion in 3D printing circles, ask people about the requirements to print safely. Is ABS safe to print without ventilation? Can you drink out of a PLA cup? How nasty is that photo resin if you spill it on yourself? If you are at home, it’s more or less up to you. But if you are building a shared hackerspace, a corporate workstation, or a classroom, these questions might come up, and now, the UL has your answer. The UL200B document is aimed at 3D printers in “institutions of higher education,” but we imagine what’s good for the university is good for us, too.

The 45-page document isn’t an easy read. It does cover both “material extrusion” and “vat photopolymerization” technology. In fact, they identify seven “most common” processes ranging from powder bed fusion, energy deposition, and more. The work results from a UL task force with participants from Harvard, Princeton, and Carnegie-Mellon. We were surprised there didn’t seem to be any industry representation, but maybe that was on purpose.

With extrusion printing — what we’d call FDM — the focus seems to be on ultra-fine particles and volatile organic compounds (VOCs). However, the level of VOCs rose up to six times with resin printers when compared to FDM. Filters helped with ABS, nylon, and ASA, and polycarbonate/ABS. The paper does acknowledge that PLA is probably safer, although it is quick to point out that PLA with additives may not be as safe as plain PLA. If you want a quick summary, check out Table 2, starting on page 23.

The rest of the document is about creating a safety plan for all the printers that might be on a college campus — that might not be as interesting. However, you’ll want to skip forward to the appendix section. It has some data about relevant industrial standards and other data.

This is a great step in analyzing the risks of 3D printing. Of course, laser printers and copiers also spew micro-particles, and we seem to have survived those for a number of decades. Still, more data is good — you should be informed to make decisions about your health and safety. We didn’t see much in the document that covered food safety, something we’ve talked about before. If you want to monitor your VOC exposure, we got you.

Overall design of retina-inspired NB perovskite PD for panchromatic imaging. (Credit: Yuchen Hou et al., 2023)

Perovskite Sensor Array Emulates Human Retina For Panchromatic Imaging

June 2, 2023 by Maya Posch 13 Comments

The mammalian retina is a complex system consisting out of cones (for color) and rods (for peripheral monochrome) that provide the raw image data which is then processed into successive layers of neurons before this preprocessed data is sent via the optical nerve to the brain’s visual cortex. In order to emulate this system as closely as possible, researchers at Penn State University have created a system that uses perovskite (methylammonium lead bromide, MAPbX₃) RGB photodetectors and a neuromorphic processing algorithm that performs similar processing as the biological retina.

Panchromatic imaging is defined as being ‘sensitive to light of all colors in the visible spectrum’, which in imaging means enhancing the monochromatic (e.g. RGB) channels using panchromatic (intensity, not frequency) data. For the retina this means that the incoming light is not merely used to determine the separate colors, but also the intensity, which is what underlies the wide dynamic range of the Mark I eyeball. In this experiment, layers of these MAPbX₃ (X being Cl, Br, I or combination thereof) perovskites formed stacked RGB sensors.

The output of these sensor layers was then processed in a pretrained convolutional neural network, to generate the final, panchromatic image which could then be used for a wide range of purposes. Some applications noted by the researchers include new types of digital cameras, as well as artificial retinas, limited mostly by how well the perovskite layers scale in resolution, and their longevity, which is a long-standing issue with perovskites. Another possibility raised is that of powering at least part of the system using the energy collected by the perovskite layers, akin to proposed perovskite-based solar panels.

(Heading: Overall design of retina-inspired NB perovskite PD for panchromatic imaging. (Credit: Yuchen Hou et al., 2023) )