crystal

48 Articles

Potassium ferrioxalate crystal

Growing Spectacular Gem-Like Crystals From Rust And Simple Ingredients

January 4, 2022 by 33 Comments

When we talk about crystals around here, we’re generally talking about the quartz variety used to make oscillators more stable, or perhaps ruby crystals used to make a laser. We hardly ever talk about homegrown crystals, though, and that’s a shame once you see how easy it is to make beautiful crystals from scratch.

We’ve got to say that we’re impressed by the size and aesthetics of the potassium ferrioxalate crystals [Chase Lean] makes with this recipe, and Zelda fans will no doubt appreciate their resemblance to green rupees. The process starts with rust, or ferric oxide, which can either be purchased or made. [Chase] chose to make his rust by soaking steel wool in a solution of saltwater and peroxide and heating the resulting sludge. A small amount of ferric oxide is added to a solution of oxalic acid, a commonly used cleaning and bleaching agent. Once the rust is dissolved, potassium carbonate is slowly added to the solution, turning it a bright green.

The rest of the process happens more or less naturally, as crystals begin to form in the saturated solution. And boy, did they grow — long, prismatic lime-green crystals, with a beautiful clarity and crisp edges and facets. The crystals don’t last long under light, though — they quickly lose their clarity and become a more opaque green.

[Chase]’s crystal-growing efforts have shown up here before, when he turned humble table salt into beautiful cubic crystals. We find the whole crystal-growing process fascinating, and we’re looking forward to more of this in the future.

Mining And Refining: Pure Silicon And The Incredible Effort It Takes To Get There

November 15, 2021 by 30 Comments

Were it not for the thin sheath of water and carbon-based life covering it, our home planet would perhaps be best known as the “Silicon World.” More than a quarter of the mass of the Earth’s crust is silicon, and together with oxygen, the silicate minerals form about 90% of the thin shell of rock that floats on the Earth’s mantle. Silicon is the bedrock of our world, and it’s literally as common as dirt.

But just because we have a lot of it doesn’t mean we have much of it in its pure form. And it’s only in its purest form that silicon becomes the stuff that brought our world into the Information Age. Elemental silicon is very rare, though, and so getting appreciable amounts of the metalloid that’s pure enough to be useful requires some pretty energy- and resource-intensive mining and refining operations. These operations use some pretty interesting chemistry and a few neat tricks, and when scaled up to industrial levels, they pose unique challenges that require some pretty clever engineering to deal with.

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Growing The World’s Largest Snowflake

March 12, 2021 by 7 Comments

Plenty of areas around the world don’t get any snowfall, so if you live in one of these places you’ll need to travel to experience the true joy of winter. If you’re not willing to travel, though, you could make some similar ice crystals yourself instead. While this build from [Brian] aka [AlphaPhoenix] doesn’t generate a flurry of small ice crystals, it does generate a single enormous one in a very specific way.

The ice that [Brian] is growing is created in a pressure chamber that has been set up specifically for this hexagonal crystal. Unlike common ice that is made up of randomly arranged and varying crystals frozen together, this enormous block of ice is actually one single crystal. When the air is pumped out of the pressure chamber, the only thing left in the vessel is the seed crystal and water vapor. A custom peltier cooler inside with an attached heat sink serves a double purpose, both to keep the ice crystal cold (and growing) and to heat up a small pool of water at the bottom of the vessel to increase the amount of water vapor in the chamber, which will eventually be deposited onto the crystal in the specific hexagonal shape.

The build is interesting to watch, and since the ice crystal growth had to be filmed inside of a freezer there’s perhaps a second hack here which involved getting the camera gear set up in that unusual environment. Either way, the giant snowball of an ice crystal eventually came out of the freezer after many tries, and isn’t the first time we’ve seen interesting applications for custom peltier coolers, either.

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Jan Czochralski And The Silicon Revolution

July 22, 2020 by 39 Comments

If you were to travel back in time to the turn of the previous century and try to convince the average person that the grains of sand on just about any beach would be the basis of an industry worth hundreds of billions of dollars within 100 years, they’d probably have thought you were crazy. Aside from being coarse, rough, and irritating, sand is everywhere, and convincing anyone of its value would be a hard sell, unless your interlocutor was a real estate visionary with an appreciation of the future value of seaside property and a lot of patience.

Fast forward to our time, and we all know the value of the material that comes from common quartz sand: silicon, specifically the ultra-purified crystals of silicon that end up as the wafers we depend on to build the circuitry of life. The trip from beach to chip foundry is a long and non-obvious one which would not have been possible without the insights of an undistinguished Polish student and one-time druggist who discovered the process that made the Information Age possible: Jan Czochralski.

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Pulling A Crystal By Grinding It

May 10, 2020 by 29 Comments

If you own a radio transmitter, from a $10 Baofeng handheld to a $1000 fancy all-band transceiver, setting the frequency is simply a case of dialing in where you want to go. A phase-locked-loop frequency synthesizer or a software-defined radio will generate your frequency, and away you go. There was a time though when synthesizers were impossibly complex and radio amateurs were faced with a simple choice. Use an LC oscillator and put up with drifting in frequency, or use a crystal oscillator, and be restricted to only the frequencies of the crystals you had. [Mark Erdle, AE2EA] modified a 1950s broadcast AM broadcast transmitter for the 1.8MHz amateur band, and his friend [Andy Flowers, K0SM] thought it needed its crystal back for originality rather than the external frequency source [Mark] had provided. He documents the process of modifying a crystal oven and moving a crystal frequency in the video below the break.

A crystal oven is a unit containing the crystal itself alongside a thermostatic heater, and in this one, the crystal was a 1970s-vintage hermetically sealed HC6 device. He modified the oven to take a socket for older FT243 crystals because the quartz element can easily be accessed. [Andy] picked a crystal as close as he could find below the required frequency. He then ground it down with very fine grit on a glass plate, reducing its mass and thus its resonant frequency. We’re taken through the process of getting it close to frequency, but sadly don’t see the etching that he uses for the very last stage. At the end of the video, we see a QSO on the transmitter itself, which is something of an oddity in an age when AM on amateur bands has been supplanted by other modes for decades.

If you’re curious about the transmitter there’s a video thread following its restoration, and if the guts of older radio gear interests you then take a look at this aircraft receiver lovingly brought back to life.

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Gorgeous Clock, And Not A Line Of Code In Sight

March 4, 2020 by 41 Comments

[Harry] dropped us a note to let us know about his completed CMOS clock project, and we’re delighted that he did because it’s gorgeous. It’s a digital clock satisfyingly assembled entirely from hardware logic, without a single line of code. There are three main parts to this kind of digital clock: ensuring a stable time base, allowing for setting the time, and turning the counter outputs into a numerical display.

Keeping accurate time is done with a 32.768 kHz crystal, and using CMOS logic to divide that down to a 1 Hz square wave. From there, keeping track of hours and minutes and seconds is mostly a matter of having counters reset and carry at the appropriate times. Setting the clock is done by diverting the 1 Hz signal so that it directly increments either the hours or minutes counter. The counter values are always shown “live” on six 7-segment displays, which makes it all human-readable.

The whole thing is tastefully enclosed in a glass dome which looks great, but [Harry] helpfully warns prospective makers that such things have an unfortunate side effect of being a fingerprint magnet. Schematics and design files are provided for those who want a closer look.

This clock uses a crystal and divider, but there’s another method for keeping accurate time and that’s to base it off the alternating current frequency of power from the grid. Not a bad method, albeit one that depends on being plugged into the wall.

Penny Diode

A Radio For The Apocalypse

November 15, 2019 by 54 Comments

There’s been a spate of apocalypse related articles over the last few weeks, but when I saw an AM radio made from a hand-wound coil and an oxidized British penny, I couldn’t help but be impressed. We’ve covered foxhole radios, stereotypical radios that are cobbled together from found parts during wartime.

This example uses a variable capacitor for tuning, but that’s technically optional. All that’s really needed is a coil and something to work as a diode. Surprisingly, copper oxide is a semiconductor, and the surface oxidation on a penny is enough to form a rudimentary diode. Though, note, not all pennies have that necessary coating of copper. If a penny has green oxide, it’s likely a candidate.

Need a quickly cobbled together AM radio? Have some wire and a penny? Yeah, watch the video below the break, and you’ll know how to make it happen. When the apocalypse comes, you’ll thank us.

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