Polymer Networks Make Better 3D Prints

October 17, 2020 by Al Williams 5 Comments

Biological machines such as human and animal bodies are quite incredible. Your body seamlessly incorporates materials as different as muscle, bone, and tendons into an integrated whole. Now Texas A&M researchers think they can imitate nature using polymer networks that have a tunable stiffness. As a bonus, similar to biological devices, the material spontaneously self-heals.

The trick relies on the Diels-Alder reaction which is a cycloaddition reaction of a conjugated diene to an alkene. Diels-Alder-based polymers or DAPs will bond together even when they have different physical characteristics and they undergo a reversible reaction to heat which offers shape-memory and healing capability.

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Transparent And Flexible Circuits

May 17, 2019 by Al Williams 4 Comments

German researchers have a line on 3D printed circuitry, but with a twist. Using silver nanowires and a polymer, they’ve created flexible and transparent circuits. Nanowires in this context are only 20 nanometers long and only a few nanometers thick. The research hopes to print things like LEDs and solar cells.

Of course, nothing is perfect. The material has a sheet resistance as low as 13Ω/sq and the optical transmission was as high as 90%. That sounds good until you remember the sheet resistance of copper foil on a PCB is about 0.0005Ω.

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Plastics: Acrylic

January 16, 2019 by Dan Maloney 32 Comments

If anything ends up on the beds of hobbyist-grade laser cutters more often than birch plywood, it’s probably sheets of acrylic. There’s something strangely satisfying about watching a laser beam trace over a sheet of the crystal-clear stuff, vaporizing a hairs-breadth line while it goes, and (hopefully) leaving a flame-polished cut in its wake.

Acrylic, more properly known as poly(methyl methacrylate) or PMMA, is a wonder material that helped win a war before being developed for peacetime use. It has some interesting chemistry and properties that position it well for use in the home shop as everything from simple enclosures to laser-cut parts like gears and sprockets.

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ABS: Three Plastics In One

December 11, 2018 by Dan Maloney 31 Comments

It would be really hard to go through a typical day in the developed world without running across something made from ABS plastic. It’s literally all over the place, from toothbrush handles to refrigerator interiors to car dashboards to computer keyboards. Many houses are plumbed with pipes extruded from ABS, and it lives in rolls next to millions of 3D-printers, loved and hated by those who use and misuse it. And in the form of LEGO bricks, it lurks on carpets in the dark rooms of children around the world, ready to puncture the bare feet of their parents.

ABS is so ubiquitous that it makes sense to take a look at this material in terms of its chemistry and its properties. As we’ll see, ABS isn’t just a single plastic, but a mixture that takes the best properties of its components to create one of the most versatile plastics in the world.

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PLA: The Plastic That Grows

September 12, 2018 by Dan Maloney 67 Comments

If you’ve ever taken a coast-to-coast car trip across the United States, the one thing that’s sure to impress you is the mind-bogglingly immense amount of corn that we grow here. If you take the northern route — I’ve done it seven times, so I know it by heart — you’ll see almost nothing but corn from Ohio to Montana. The size of the fields is simply staggering, and you’re left wondering, “Do we really eat all this corn?”

The simple answer is no, we don’t. We grow way more corn than we can eat or, once turned into alcohol, drink. We do feed a lot to animals, many of which subsequently end up as burgers or pork chops. But even after all that, and after accounting for exports, we still have a heck of a lot of corn to put to work. There are lots of industrial uses for this surplus corn, though, and chances are pretty good you’ve got an ear or two worth coiled up next to your 3D-printer, in the form of polylactic acid, or PLA.

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Stephanie Kwolek: Saving Lives With Kevlar

March 13, 2018 by Dan Maloney 41 Comments

Like most accidents, it happened in an instant that seemed to last an eternity. I had been felling trees for firewood all afternoon, and in the waning light of a cold November day, I was getting ready to call it quits. There was one tiny little white pine sapling left that I wanted to clear, no thicker than my arm. I walked over with my Stihl MS-290, with a brand new, razor sharp chain. I didn’t take this sapling seriously — my first mistake — and cut right through it rather than notching it. The tree fell safely, and I stood up with both hands on the saw. Somehow I lost my footing, swiveled, and struck my left knee hard with the still-running chainsaw. It kicked my knee back so hard that it knocked me to the ground.

In another world, that would likely have a been a fatal injury — I was alone, far from the house, and I would have had mere minutes to improvise a tourniquet before bleeding out. But as fate would have it, I was protected by my chainsaw chaps, full of long strands of the synthetic fiber Kevlar.

The chain ripped open the chaps, pulled the ultrastrong fibers out, and instantly jammed the saw. I walked away feeling very stupid, very lucky, and with not a scratch on me. Although I didn’t realize it at the time, I owed my life to Stephanie Kwolek.

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Self-assembling Polymers Support Silicone 3D Prints

May 18, 2017 by Dan Maloney 12 Comments

We all know what the ultimate goal of 3D printing is: to be able to print parts for everything, including our own bodies. To achieve that potential, we need better ways to print soft materials, and that means we need better ways to support prints while they’re in progress.

That’s the focus of an academic paper looking at printing silicone within oil-based microgels. Lead author [Christopher S. O’Bryan] and team from the Soft Matter Research Lab at the University of Florida Gainesville have developed a method using self-assembling polymers soaked in mineral oil as a matrix into which silicone elastomers can be printed. The technique takes advantage of granular microgels that are “jammed” into a solid despite being up to 95% solvent. Under stress, such as that exerted by the nozzle of a 3D printer, the solid unjams into a flowing liquid, allowing the printer to extrude silicone. The microgel instantly jams back into a solid again, supporting the silicone as it cures.

[O’Bryan] et al have used the technique to print a model trachea, a small manifold, and a pump with ball valves. There are Quicktime videos of the finished manifold and pump in action. While we’ve covered flexible printing options before, this technique is a step beyond and something we’re keen to see make it into the hobby printing market.

[LonC], thanks for the tip.