Day: February 11, 2025

Improving Aluminium-Ion Batteries With Aluminium-Fluoride Salt

February 11, 2025 by 6 Comments

There are many rechargeable battery chemistries, each with their own advantages and disadvantages. Currently lithium-ion and similar (e.g. Li-Po) rule the roost due to their high energy density at least acceptable number of recharge cycles, but aluminium-ion (Al-ion) may become a more viable competitor after a recently published paper by Chinese researchers claims to have overcome some of the biggest hurdles. In the paper as published in ACS Central Science by [Ke Guo] et al. the use of solid-state electrolyte, a charge cycle endurance beating LiFePO4 (LFP) and excellent recyclability are claimed.

It’s been known for a while that theoretically Al-ion batteries can be superior to Li-ion in terms of energy density, but the difficulty lies in the electrolyte, including its interface with the electrodes. The newly developed electrolyte (F-SSAF) uses aluminium-fluoride (AlF3) to provide a reliable interface between the aluminium and carbon electrodes, with the prototype cell demonstrating 10,000 cycles with very little cell degradation. Here the AlF3 provides the framework for the EMIC-AlCl3 electrolyte. FEC (fluoroethylene carbonate) is introduced to resolve electrolyte-electrode interface issues.

A recovery of >80% of the AlF3 during a recycling phase is also claimed, which for a prototype seems to be a good start. Of course, as the authors note in their conclusion, other frameworks than AlF3 are still to be investigated, but this study brings Al-ion batteries a little bit closer to that ever-elusive step of commercialization and dislodging Li-ion.

Hearing What The Bats Hear

February 11, 2025 by 1 Comment

[Iftah] has been exploring the sounds beyond what we can hear, recording ultrasound and pitching it down. He made a short video on the practice, and it’s like a whole new world of sounds exists just outside of our hearing.

For instance, a dropped toothpick sounds like you’ve just dropped a piece of lumber, a broken lightbulb sounds like a shattered window, and a blackbird sounds like a blue whale. Besides simply sounding super, [Iftah] speculates that there’s some regularity here: that as you slow down the sound it sounds like it came from sources that are physically bigger. He follows this up in a second video, but if you just think about the basic physics, it makes sense.

If you’re interested in recording your own ultrasound, there are a bunch of options on the market. With modern audio processors running up to 192 kHz or even 384 kHz out of the box, all that’s missing is the high-frequency-capable microphone. Those aren’t unobtainable anymore either with many MEMS mics performing well above their rated frequency response specs. Recording ultrasound sounds like a fun and not-too-expensive project to us!

Of course, most of the ultrasound recording we’ve seen has been about the bats. Check out the Pipistrelle or this pair of DIY bat detectors for some good background. But after watching [Iftah]’s video, we’re no longer convinced that the cute little insectivores are the coolest thing going on in the ultrasound.

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The Science Behind Making Buildings Comfortably Non-Combustible

February 11, 2025 by 6 Comments

Although the most fire-resistant building is likely a windowless, concrete bunker, this tends to be not the vibe that most home owners go for. This is why over the years construction of buildings in areas prone to bush- and wildfires – i.e. an uncontrolled fire in an area with combustible vegetation – has adapted to find a happy medium between a building that you’d enjoy living in and a building that will not instantly combust the moment an ember from a nearby wildfire gently touches down upon any part of it.

To achieve this feat, the primary means include keeping said combustible vegetation and similar away from the building, and to make the house as resistant to ember attacks as possible. That this approach is effective has been demonstrated over the course of multiple wildfires in California during the past years, whereby houses constructed more recently with these features had a much higher chance of making it through the event unscathed.

Naturally, the devil is in the details, which is why for example the Australian standard for construction in bushfire-prone areas (AS 3959, last updated in 2018, 2009 version PDF) is rather extensive and heavy on details, including multiple Bushfire Attack Level (BAL) ratings that define risk areas and legally required mitigation measures. So what does it take exactly to survive a firestorm bearing down on your abode?

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Precision Reference Puts Interesting Part To Work

February 11, 2025 by 8 Comments

Interesting parts make for interesting projects, and this nifty precision voltage reference has some pretty cool parts, not to mention an interesting test jig.

The heart of [Gaurav Singh]’s voltage reference is an ADR1399, precision shunt reference from Analog Devices. The datasheet makes for pretty good reading and reveals that there’s a lot going on inside the TO-49 case, which looks unusually large thanks to a thick plastic coat. The insulation is needed for thermal stability for the heated Zener diode reference. The device also has a couple of op-amps built in, one that provides closed-loop voltage control and another that keeps the internal temperature at a toasty 95°C. The result is a reference that’s stable over a wide range of operating conditions.

[Gaurav]’s implementation maximizes this special part’s capabilities while making it convenient to use. The PCB has a precision linear regulator that accepts an input voltage from 16 V to 20 V, plus a boost converter that lets you power it from USB-C. The board itself is carefully designed to minimize thermal and mechanical stress, with the ADR1399 separated from the bulk of the board with wide slots. The first video below covers the design and construction of an earlier rev of the board.

One problem that [Gaurav] ran into with these boards was the need to age the reference with an extended period of operation. To aid in that, he built a modular test jig that completed PCBs can be snapped into for a few weeks of breaking in. The jigs attach to a PCB with pogo pins, which mate to test points and provide feedback on the aging process. See the second video for more details on that.

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