Big Chemistry: Catalysts

I was fascinated by the idea of jet packs when I was a kid. They were sci-fi magic, and the idea that you could strap into an oversized backpack wrapped in tinfoil and fly around was very enticing. Better still was when I learned that these things weren’t powered by complicated rockets but by plain hydrogen peroxide, which violently decomposes into water and oxygen when it comes in contact with a metal like silver or platinum. Of course I ran right to the medicine cabinet to fetch a bottle of peroxide to drip on a spoon from my mother’s good silverware set. Needless to say, I was sorely disappointed by the results.

My little impromptu experiment went wrong in many ways, not least because the old bottle of peroxide I used probably had little of the reactive compound left in it. Given enough time, the decomposition of peroxide will happen all by itself. To be useful in a jet pack, this reaction has to proceed much, much faster, which was what the silver was for. The silver (or rather, a coating of samarium nitrate on the silver) acted as a catalyst that vastly increased the rate of peroxide decomposition, enough to produce jets of steam and oxygen with enough thrust to propel the wearer into the air. Using 90% pure peroxide would have helped too.

As it is for jet packs, so it is with industrial chemistry. Bulk chemical processes can rarely be left to their own devices, as some reactions proceed so slowly that they’d be commercially infeasible. Catalysts are the key to the chemistry we need to keep the world running, and reactors full of them are a major feature of many of the processes of Big Chemistry.

Continue reading “Big Chemistry: Catalysts”

A Little Pigment Helps With Laser Glass Engraving

The range of materials suitable for even the cheapest laser cutter is part of what makes them such versatile and desirable tools. As long as you temper your expectations, there’s plenty of material to cut with your 40 watt CO2 laser or at least engrave—just not glass; that’s a tough one.

Or is it? According to [rschoenm], all it takes to engrave glass is a special coating. The recipe is easy: two parts white PVA glue, one part water, and two parts powdered titanium dioxide. The TiO2 is the important part; it changes color when heated by the laser, forming a deep black line that adheres to the surface of the glass. The glue is just there as a binder to keep the TiO2 from being blasted away by the air assist, and the water thins out the goop for easy spreading with a paintbrush. Apply one or two coats, let it dry, and blast away. Vector files work better than raster files, and you’ll probably have to play with settings to get optimal results.

With plain float glass, [rschoenm] gets really nice results. He also tried ceramic tile and achieved similar results, although he says he had to add a drop or two of food coloring to the coating so he could see it against the white tile surface. Acrylic didn’t work, but there are other methods to do that.

Continue reading “A Little Pigment Helps With Laser Glass Engraving”

Hackaday Links Column Banner

Hackaday Links: January 26, 2025

Disappointing news this week for those longing for same-hour Amazon delivery as the retail giant tapped the brakes on its Prime Air drone deliveries. The pause is partially blamed on a December incident at the company’s Pendleton, Oregon test facility, where two MK30 delivery drones collided in midair during light rain conditions. A Bloomberg report states that the crash, which resulted in one of the drones catching fire on the ground, was due to a software error related to the weather. As a result, they decided to ground their entire fleet, which provides 60-minute delivery to test markets in Arizona and Texas, until a software update can be issued.

Continue reading “Hackaday Links: January 26, 2025”

Laser-Cut Metal Endoskeleton Beefs Up 3D Prints

There are limits to what you can do with an FDM printer to make your parts stronger. It really comes down to adding more plastic, like increasing wall thickness or boosting up the infill percentage. Other than that, redesigning the part to put more material where the part is most likely to fail is about the only other thing you can do. Unless, of course, you have access to a fiber laser cutter that can make internal metal supports for your prints.

As [Paul] explains it, this project stemmed from an unfortunate episode where a printed monitor stand failed, sending the LCD panel to its doom. He had taken care to reinforce that part by filling it with fiberglass resin, but to no avail. Unwilling to risk a repeat with a new tablet holder, he decided to test several alternative methods for reinforcing parts. Using a 100 W fiber laser cutter, he cut different internal supports from 0.2 mm steel shim stock. In one case he simply sandwiched the support between two half-thickness brackets, while in another he embedded the steel right into the print. He also made two parts that were filled with epoxy resin, one with a steel support embedded and one without.

The test setup was very simple, just a crane scale to measure the force exerted by pulling down on the part with his foot; crude, but effective. Every reinforced part performed better than a plain printed part with no reinforcement, but the clear winner was the epoxy-filled part with a solid-metal insert. Honestly, we were surprised at how much benefit such a thin piece of metal offered, even when it was directly embedded into the print during a pause.

Not everyone has access to a fiber laser cutter, of course, so this method might not be for everyone. In that case, you might want to check out other ways to beef up your prints, including just splitting them in two.

Continue reading “Laser-Cut Metal Endoskeleton Beefs Up 3D Prints”

Mining And Refining: The Halogens

I was looking at the periodic table of the elements the other day, as one does, when my eye fell upon the right-hand side of the chart. Right next to the noble gases at the extreme edge of the table is a column of elements with similar and interesting properties: the halogens. Almost all of these reactive elements are pretty familiar, especially chlorine, which most of us eat by the gram every day in the form of table salt. As the neighborhoods of the periodic table go, Group 17 is pretty familiar territory.

But for some reason, one member of this group caught my attention: iodine. I realized I had no idea where we get iodine, which led to the realization that apart from chlorine, I really didn’t know where any of the halogens came from. And as usual, that meant I needed to dig in and learn a little bit about the mining and refining of the halogens. At least most of them; as interesting as they may be, we’ll be skipping the naturally occurring but rare and highly radioactive halogen astatine, as well as the synthetic halogen tennessine, which lives just below it in the group.

Continue reading “Mining And Refining: The Halogens”

Hackaday Links Column Banner

Hackaday Links: January 19, 2025

This week, we witnessed a couple of space oopsies as both Starship and New Glenn suffered in-flight mishaps on the same day. SpaceX’s Starship was the more spectacular, with the upper stage of the seventh test flight of the full stack experiencing a “rapid unscheduled disassembly” thanks to a fire developing in the aft section of the stage somewhere over the Turks and Caicos islands, about eight and a half minutes after takeoff from Boca Chica. The good news is that the RUD happened after first-stage separation, and that the Super Heavy booster was not only able to safely return to the pad but also made another successful “chopsticks” landing on the tower. Sorry, that’s just never going to get old.

On the Bezos side of the billionaire rocket club, the maiden flight of Blue Origin’s New Glenn ended with the opposite problem. The upper stage reached orbit, but the reusable booster didn’t make it back to the landing barge parked off the Bahamas. What exactly happened isn’t clear yet, but judging by the telemetry the booster was coming in mighty fast, which may indicate that the engines didn’t restart fully and the thing just broke up when it got into the denser part of the atmosphere.

Continue reading “Hackaday Links: January 19, 2025”

Motorized Coil Tunes Your Ham Antenna On A Budget

When it comes to amateur radio, one size definitely does not fit all. That’s especially true with antennas, which need to be just the right size for the band you’re working, lest Very Bad Things happen to your expensive radio. That presents a problem for the ham who wants the option to work whichever band is active, and doubly so if portable operation is desired.

Of course, there are commercial solutions to this problem, but they tend to be expensive. Luckily [Øystein (LB8IJ)] seems to have found a way around that with this low-cost homebrew motorized antenna coil, which is compatible with the Yaesu Automatic Tuning Antenna System. ATAS is supported by several Yaesu transceivers, including the FT-891 which [Øystein] favors for field operations. ATAS sends signals up the feedline to a compatible antenna, which then moves a wiper along a coil to change the electrical length of the antenna, allowing it to resonate on the radio’s current frequency.

The video below details [Øystein]’s implementation of an ATAS-compatible tuning coil, mainly focusing on the mechanical and electrical aspects of the coil itself, which takes up most of the room inside a 50-mm diameter PVC tube. The bore of the air-core coil has a channel that guides a wiper, which moves along the length of the coil thanks to a motor-driven lead screw. [Øystein] put a lot of work into the wiper, to make it both mechanically and electrically robust. He also provides limit switches to make sure the mechanism isn’t over-driven.

There’s not much detail yet on how the control signals are detected, but a future video on that subject is promised. We’re looking forward to that, but in the meantime, the second video below shows [Øystein] using the tuner in the field, with great results.

Continue reading “Motorized Coil Tunes Your Ham Antenna On A Budget”