a–d, Crystal structures of the 1CzTrz-F (a,b) and 3CzTrz-F (c,d) compounds, determined by XRD. a,c, Diagrams of the two dimers of both crystallographic unit cells to show the molecular packing. b,d, Spatial arrangement of the acceptor–donor contacts in the 3D crystal structure. The triazine acceptor and the carbazole donor units are coloured orange and blue, respectively. The green features in d indicate co-crystallized chloroform molecules. (Credit: Oskar Sachnik et al., 2023)

Eliminating Charge-Carrier Trapping In Organic Semiconductors

August 13, 2023 by Maya Posch 4 Comments

For organic semiconductors like the very common organic light-emitting diode (OLED), the issue of degradation due to contaminants that act as charge traps is a major problem. During the development of OLEDs, this was very pronounced in the difference between the different colors and the bandgap which they operated in. Due to blue OLEDs especially being sensitive to these charge traps, it still is the OLED type that degrades the quickest as contaminants like oxygen affect it the strongest. Recent research published in Nature Materials from researchers at the Max Planck Institute for Polymer Research by Oskar Sachnik and colleagues (press release) may however have found a way to shield the electron-carrying parts of organic semiconductors from such contaminants.

Current density (J)–voltage (V) characteristics of electron- and hole-only devices of 3CzTrz and TPBi. (Credit: Oskar Sachnik et al., 2023)

In current organic semiconductors TPBi is used for electron transport, whereas for this research triazine (Trz, as electron acceptor) and carbozole (Cz, as donor) were used and compared with the properties of leading-edge TPBi. While a few other formulations in the study did not show remarkable results, one compound (3CzTrz) was found using X-ray diffraction (XRD) to have a structure as shown on the right in the heading image, with the carbozole (in blue) forming essentially channels along which electrons can move, while shielded from contaminants by the triazine.

Using this research it might be possible to create organic semiconductors in the future which are free of charge-traps, and both efficiency and longevity of this type of semiconductor (including OLEDs and perovskites) can be improved immensely.

No Moving Parts LiDAR

July 6, 2023 by Al Williams 29 Comments

Self-driving cars often use LiDAR — think of it as radar using light beams. One limitation of existing systems is they need some method of scanning the light source around, and that means moving parts. Researchers at the University of Washington have created a laser on a chip that uses acoustic waves to bend the laser, avoiding physically moving parts. The paper is behind a paywall, but the University has a summary poster, and you can also find an overview over on [Geekwire].

The resulting IC uses surface acoustic waves and can image objects more than 100 feet away. We would imagine this could be helpful for other applications like 3D scanning, too. The system weighs less than a conventional setup, too, so that would be valuable in drones and similar applications.

Continue reading “No Moving Parts LiDAR” →

A LEGO Camera You Just Might Own Yourself

March 25, 2023 by Jenny List 6 Comments

A camera makes for an interesting build for anyone, because it’s an extremely accessible technology that can be made from materials as simple as cardboard. More robust cameras often require significant work, but what if you could make a usable camera from LEGO? It’s a project taken on by [Zung92], who hasn’t simply made a working 35 mm camera from everyone’s favorite construction toy — he’s also managed to make it exude retro style. Best of all, you can vote for it on the LEGO Ideas website, and you might even get the chance to have one for yourself.

Frustratingly there’s little in the way of in-depth technical detail on the Ideas website, but he does mention that it was a challenge to make it light proof. Even the lens is a LEGO part, and if diffraction-based photography isn’t for you there’s also a pinhole option. We look forward to seeing this camera progress, and we hope we’ll see it advance to becoming a LEGO Ideas kit.

This is an extremely polished design, but surprisingly, it’s not our first LEGO camera.

Thanks [Michael] for the tip.

Hackaday Links: September 25, 2022

September 25, 2022 by Dan Maloney 15 Comments

Looks like there’s trouble out at L2, where the James Webb Space Telescope suffered a mechanical anomaly back in August. The issue, which was just announced this week, involves only one of the six imaging instruments at the heart of the space observatory, known as MIRI, the Mid-Infrared Instrument. MIRI is the instrument on Webb that needs the coldest temperatures to work correctly, down to six Kelvins — we’ve talked about the cryocooler needed to do this in some detail. The problem has to do with unexpectedly high friction during the rotation of a wheel holding different diffraction gratings. These gratings are rotated into the optical path for different measurements, but apparently the motor started drawing excessive current during its move, and was shut down. NASA says that this only affects one of the four observation modes of MIRI, and the rest of the instruments are just fine at this time. So they’ve got some troubleshooting to do before Webb returns to a full program of scientific observations.

There’s an old saying that, “To err is human, but to really screw things up takes a computer.” But in Russia, to really screw things up it takes a computer and a human with a really poor grasp on just how delicately balanced most infrastructure systems are. The story comes from Moscow, where someone allegedly spoofed a massive number of fake orders for taxi rides (story in Russian, Google Translate works pretty well) through the aggregator Yandex.Taxi on the morning of September 1. The taxi drivers all dutifully converged on the designated spot, but instead of finding their fares, they just found a bunch of other taxis milling about and mucking up traffic. Yandex reports it has already added protection against such attacks to its algorithm, so there’s that at least. It’s all fun and games until someone causes a traffic jam.

Continue reading “Hackaday Links: September 25, 2022” →

Blu-ray Microscope Uses Blood Cells As Lenses

April 22, 2022 by Anne Ogborn 12 Comments

When you think of high-throughput ptychographic cytometry (wait, you do think about high throughput ptychographic cytometry, right?) does it bring to mind something you can hack together from an old Blu-ray player, an Arduino, and, er, some blood? Apparently so for [Shaowei Jiang] and some of his buddies in this ACS Sensors Article.

For those of you who haven’t had a paper accepted by the American Chemical Society, we should probably clarify things a bit. Ptychography is a computational method of microscopic imaging, and cytometry has to do with measuring the characteristics of cells. Obviously.

This is definitely what science looks like.

Anyway, if you shoot a laser through a sample, it diffracts. If you then move the sample slightly, the diffraction pattern shifts. If you capture the diffraction pattern in each position with a CCD sensor, you can reconstruct the shape of the sample using breathtaking amounts of math.

One hitch – the CCD sensor needs a bunch of tiny lenses, and by tiny we mean six to eight microns. Red blood cells are just that size, and they’re lens shaped. So the researcher puts a drop of their own blood on the surface of the CCD and covers it with a bit of polyvinyl film, leaving a bit of CCD bloodless for reference. There’s an absolutely wild video of it in action here.

Don’t have a Blu-ray player handy? We’ve recently covered a promising attempt at building a homebrew scanning electron microscope which might be more your speed. It doesn’t even require any bodily fluids.

[Thanks jhart99]

A MiniDisc Optical Head Has A Few Surprises Up Its Sleeve

March 24, 2022 by Jenny List 46 Comments

There was an odd era at the start of the 1990s when CDs had taken the lead from vinyl in pre-recorded music, but for consumer recordable formats the analogue cassette was still king. A variety of digital formats came to market to address this, of which Sony’s MiniDisc was the only one to gain significant traction outside the studio. These floppy-disk-like cartridges held a magneto-optical medium , and were the last word in cool until being swept away around the end of the decade by MP3 players. Hackaday alum [Nava Whitford] has disassembled a MiniDisc optical head to document how the physical part of the system worked.

The first surprise is that the MiniDisc was in fact a two-in-one system. The recordable discs were magneto-optical and wrote data by heating the disc with a laser under a magnetic field, while the pre-recorded discs used etched pits and lands in a similar way to the CD. Remembering the technical buzz around the system back in the day, either we audio enthusiasts glossed over this detail, or more likely, Sony’s PR did so to emphasize the all-new aspect of the system.

The teardown goes in depth into how while like a CD player there is a photodiode array involved, the extra components are a diffraction grating and a Wollaston prism, an optical component which splits polarized light into two beams. The photodiode array is more complex than that of a CD player, it’s speculated that this is to detect the different polarized beams as well as for the task of maintaining alignment with the track.

All in all this is a rare chance to look at something we know, but which few of us will probably have dismantled due to its relative scarcity compared to CD mechanisms. Definitely worth a look. Meanwhile if this era is of interest, take a look at a Hack Chat we did a while back looking at the MiniDisc’s would-be competitor.

3D Printed Suncatcher Shines In The Light

February 25, 2022 by Lewin Day 9 Comments

Diffraction gratings create beautiful rainbow patterns when interacting with natural white light, and [audreyobscura] was familiar with their properties. Thus, she set about producing an attractive 3D-printed suncatcher ornament that positively shines in the sun.

The design is straightforward, consisting of a 3D printed frame made of pieces glued together using QuickGrab glue. The pieces come together into a 7-segment star design, with a subtle 3D structure to it which helps add strength in addition to looking good.

Once assembled, sections of plastic diffraction grating are cut to size using a Curio desktop cutter. These are then glued into each segment of the star. While it’s possible to 3D print pieces with diffraction-grating like effects, using the film in this way allows light to pass through the suncatcher to create a more impressive effect.

On a cloudy day, the suncatcher looks almost entirely unassuming. However, when Earth’s nearest star shines, it projects glorious rainbows throughout the room, and letting it sway in the breeze lets the light play across the walls.

It’s a nice build, and a relatively easy ornament to make even if you’re new to 3D printing. We do like a good bit of decoration around here, especially if it’s a tiny version of a real TV. Video after the break.

Continue reading “3D Printed Suncatcher Shines In The Light” →