Turning Energy Drinks Into Rocket Fuel

Sometimes claimed to give you wings, energy drinks can, at the very least, be used to make rockets fly. This is what [Nate Scovill] did in a recent video, where cans of the sugary stuff are processed to give a rocket its proverbial wings.

The basic concept is so-called rocket candy, which uses the fact that sugar is a pretty decent fuel type that — when combined with an oxidizer like potassium nitrate — can be turned into solid rocket fuel. Naturally it’d be easiest to start off with a pure source of sucrose or sorbitol for the sugar, but what if you only have access to cans of sugary soda?

Removing the moisture from the energy drink was the obvious first step, as water and rocket fuel aren’t a great mix. Adding and mixing potassium nitrate to the resulting thick syrup created the fuel-oxidizer mixture, also known as rocket fuel. This did take a detour involving removing the carbonation using a vacuum chamber, as CO2 and fire do not really like each other either.

We previously covered making your own rocket candy, though it’s far from the only rocket fuel that can be made at home using products bought at the local supermarket. Obviously, doing so comes with a whole heap of risks, not least of which is the notion that the difference between a rocket and a bomb is a pretty thin and fuzzy line that you do not want to accidentally cross.

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Polystyrene Foam Can Be Gasoline With Some Help

Styrofoam – or closed-cell extruded polystyrene (XPS) foam if you want to be precise – is one of those materials that is both super versatile for packaging and insulation, but also a menace when it comes to disposal, even if you ignore that the monomer styrene (C8H8) is a known mutagenic toxin. One of the more creative ways to deal with the metric tons of polystyrene waste generated each year is to turn it into gasoline, as demonstrated by [Lowered Expectations] in a recent video.

With polystyrene being just another hydrocarbon polymer, the idea of turning these polymers into the mixture of hydrocarbon chains we call ‘gasoline’ isn’t so crazy. The problem is mostly doing it in a way that makes some economic sense and doesn’t risk turning your domicile into a hazmat risk site or threaten the health of you, your loved ones and the neighborhood.

The method demonstrated in the video uses fairly basic methods involving pyrolysis and distillation. The first step involves dissolving the polystyrene in gasoline that was previously recovered from stale gasoline, which is another dangerously fun science experiment. This creates a thick slurry that’s then put into the distillation flask for the heating phase.

After testing the distillates for spark ignition the useful distillates were combined with fuel stabilizer added. Before tossing this into a gasoline engine tank for further testing, the concerns of auto-polymerization of styrene monomers are addressed, which requires special inhibiters.

Although this mixture runs a gasoline generator just fine, a borescope inspection of the cylinders showed a build-up of a shiny, gummy residue. There’s also the issue that this mixture contains styrene monomers, which are as noted very unhealthy to breathe in from either the fuel or any remaining monomers in the exhaust. Definitely not something to try at home, basically.

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Turning Fruits Into Ethylene And Ethane Refrigerant

One of the best parts about DIY chemistry and physics projects is that you get to decide how early in the supply chain you want to begin, such as with [Hyperspace Pirate]’s adventures in ethanol production from sugar fermentation. Although you can certainly just buy packs of sugar and yeast from the store and pretend that this will be helpful once the world embraces its Mad Max era, you may as well start with the stuff that actually grows on trees, like fruit.

While you could use the ethanol produced this way as ethanol fuel in combustion engines and the like, you can also turn the ethanol into ethylene and ethane. That way you can fill up your refrigerator, freezer, and air conditioner to keep your perishable foods and yourself fresh as the outside world descends into highly questionable fashion choices.

Even outside such a scenario it makes sense to generate your own ethane and ethylene, due to how much these refrigerants cost. Once you have the ethanol, some aluminium oxide catalyst at 350°C is enough to produce ethylene and water. Producing ethane is admittedly a bit more involved, requiring acetobacter bacteria to produce acetic acid, along with baking soda, a platinum anode and a few more odds and ends.

Producing butene and even longer chains from ethylene is also possible as a next step, but this gets even hairier than producing ethane from ethanol, so we’re likely to see this in a future update after all the low-hanging fruit has been harvested.

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How To Rebuild An 1800s Victorian Leclanché Cell

The 19th century was an absolutely electrifying era, including in a literal sense. Although the phenomenon of electricity had been known by that time for centuries, actually making it do useful work was a much taller order. Aside from big, coal-powered generators, there also was a need for a more compact electrochemical solution, such as in the form of a wet or dry cell. One of the first major commercial successes here came in the form of the Leclanché cell, such as the genuine version that [Big Clive] found in an old UK building’s attic and has now revived.

Invented in 1866 by French scientist Georges Leclanché, the Leclanché cell features an ammonium chloride electrolyte solution, carbon cathode and zinc anode. There’s also a manganese dioxide depolarizer for preventing hydrogen build-up. Here water is the solvent for the ammonium chloride (also known as sal ammoniac).

The version that [Clive] got his grubby mitts on features a glass container, an already partially consumed zinc electrode and a slightly cracked porous ceramic tub that contains the carbon electrode and the manganese dioxide. After placing the components inside the specially shaped glass jar and filling it with an electrolyte mixture of one part ammonium chloride and four parts water by weight, the cell starts generating its approximate 1.4 VDC.

This type of wet cell was very popular, being essentially ‘rechargeable’ by topping up the water and replacing the zinc electrode consumable. They did suffer from a voltage drop-off during use due to increasing internal resistance, something that got improved upon with the zinc-carbon dry cell. Itself effectively an evolution of the Leclanché wet cell.

From there zinc-carbon dry cells got replaced with alkalines, which itself got mostly replaced by NiMH and Li-ion cells. Despite more than a hundred years between the electrochemical cell that [Clive] featured in his video and today’s batteries, it’s clear that this wet cell was quite literally just the Victorian-era equivalent of an alkaline AA cell.

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Microdistillery For Microchemistry

Much like radio operators being encouraged to use the least possible amount of power to make a contact, chemists have a similar rule encouraging using the least amount of materials in experiments. Not only is this rooted in economics, but in safety as well; if something goes wrong it’s generally good if there’s not excess amounts of reactants. With modern techniques, though, it’s possible to bring experimental chemistry down to incredibly small scales, and [Marb’s lab] found that they needed a custom built still for these new, diminutive experiments.

The first step is to build the heating component of the still. This is provided with a few custom aluminum parts for the base and a pair of heaters originally meant for 3D printers, with the assembled unit wrapped in insulation. The heater accomodates a 25 mL round-bottom flask. Temperature control of the heating mantle is provided by a controller mounted to a DIN rail which receives power from a 24V power supply, and an additional temperature probe is added to measure the temperature of the distillate. A test run with water shows the small still quickly and efficiently evaporating the water up to a condenser.

Although building a still doesn’t have to be technically difficult, building something this small that’s effective and safe is a bit more challenging than a backyard moonshining operation. Scaling chemical reactions down can often be a challenge but is possible with the right mindset and equipment. We’ve seen miniaturization of many things that we might not have expected including hydrogen production, aluminum smelting, and even the construction of a microscope.

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Solid-State Batteries Take To The Sky

There always seem to be a handful of revolutionary technologies perpetually out of reach: fusion energy, quantum computers, and full self-driving cars are always in this list, and it seems like there’s also some battery technology which will finally let us fully decouple from fossil fuels in there as well. Although lithium batteries have allowed some ground-based electric transportation, the energy density is still not enough to enable full electrification, especially for things like aircraft. Solid state batteries may be on the verge of changing some of this, though, and a team has recently put them to work in a test aircraft to help make some headway with this novel battery chemistry.

The main contributing factor of these batteries’ improved energy densities is the ability to use a solid lithium anode, which has much higher energy density than the graphite-based anodes in modern liquid electrolyte batteries. Solid state batteries also have improved safety, since the solid electrolyte is generally not flammable and the battery itself is less prone to thermal runaway. The tests in this aircraft, a modified motorized glider, bear this out as well. With a standard lithium ion pack the team was able to harness 250 Wh/kg and with their new solid state battery they managed 410 Wh/kg, which let them fly the craft up to 24,000 feet (7,315 m) with the help of some wing-mounted solar panels.

Of course, a motorized glider is a long way away from battery-powered commercial flights, but tests like this are an important step on the way to de-carbonizing one of the more impactful industries on the planet, as well as hopefully making it less expensive to operate aircraft in the way EVs are generally much cheaper to operate than their internal combustion equivalents. But the limiting factor to adopting solid state batteries isn’t going to be implementation but rather the discovery of a cost effective way to manufacture them at scale. It’s the same reason we haven’t seen mass adoption of things like algae-based biodiesel or economic carbon capture yet.

Building An Organic Flow Battery Based On Green Tea

As simple of a concept flow batteries are, the used chemicals can still be somewhat problematic in the context of a school experiment. To this end [Markus Bindhammer] decided to implement a flow battery version that uses compounds from green tea for its electrolyte, based on a German research paper from 2016.

The flow battery construction from the paper by Rosenberg et al., 2016.

These organic flow batteries can use gallic acid, pyrogallol as well as the polyphenols in green tea, making them rather safe even in the hands of more careless students. The demonstrated flow battery uses a carbon electrode with activated carbon around it to increase surface area, a platinum wire electrode, and a graphite foil as third electrode.

In the paper a silver electrode is also used, along with the additional electrodes, and a terracotta flower pot as the barrier between the carbon and graphite electrodes, with [Markus] further explaining that there are fortunately cheaper options than what he is using, especially with the flower pot instead of a special ceramic vessel.

The electrolyte solution has epigallocatechin gallate (EGCG) dissolved in it, which here comes in the form of finely ground green tea powder (commonly known as matcha), which so happens to be pretty rich in this substance. In the below graphic by [Markus] you can see the complete set of solutions and other relevant details.

Of course, the performance of this type of flow cell isn’t amazing, with a cell voltage of less than a volt and a few mA of current, but it’s enough to spin a small fan, and to light up a few LEDs. This would be more than enough to demonstrate the reaction and flow cells in general, as long as you don’t mind donating some tasty matcha to science.

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