The bed of a small CNC machine is shown. A plastic tub is on the bed, and in the tub is a sheet of metal under a pale green solution. In place of the spindle of the CNC, there is a rectangular orange tube extending down into the solution. A red wire runs to this tube, and a black wire runs to the sheet of metal in the tub.

Painting In Metal With Selective Electroplating

July 24, 2025 by Aaron Beckendorf 5 Comments

Most research on electroplating tries to find ways to make it plate parts more uniformly. [Ajc150] took the opposite direction, though, with his selective electroplating project, which uses an electrode mounted on a CNC motion system to electrochemically print images onto a metal sheet (GitHub repository).

Normally, selective electroplating would use a mask, but masks don’t allow gradients to be deposited. However, electroplating tends to occur most heavily at the point closest to the anode, and the effect gets stronger the closer the anode is. To take advantage of this effect, [ajc150] replaced the router of an inexpensive 3018 CNC machine with a nickel anode, mounted an electrolyte bath in the workspace, and laid a flat steel cathode in it. When the anode moves close to a certain point on the steel cathode, most of the plating takes place there.

To actually print an image with this setup, [ajc150] wrote a Python program to convert an image into set of G-code instructions for the CNC. The darker a pixel of the image was, the longer the electrode would spend over the corresponding part of the metal sheet. Since darkness wasn’t linearly proportional to plating time, the program used a gamma correction function to adjust times, though this did require [ajc150] to recalibrate the setup after each change. The system works well enough to print recognizable images, but still has room for improvement. In particular, [ajc150] would like to extend this to a faster multi-nozzle system, and have the algorithm take into account spillover between the pixel being plated and its neighbors.

This general technique is reminiscent of a metal 3D printing method we’ve seen before. We more frequently see this process run in reverse to cut metal.

Bipolar Uranium Extraction From Seawater With Ultra-Low Cell Voltage

June 11, 2025 by Maya Posch 52 Comments

As common as uranium is in the ground around us, the world’s oceans contain a thousand times more uranium (~4.5 billion tons) than can be mined today. This makes extracting uranium as well as other resources from seawater a very interesting proposition, albeit it one that requires finding a technological solution to not only filter out these highly diluted substances, but also do so in a way that’s economically viable. Now it seems that Chinese researchers have recently come tantalizingly close to achieving this goal.

The anode chemical reaction to extract uranium. (Credit: Wang et al., Nature Sustainability, 2025)

The used electrochemical method is described in the paper (gift link) by [Yanjing Wang] et al., as published in Nature Sustainability. The claimed recovery cost of up to 100% of the uranium in the seawater is approximately $83/kilogram, which would be much cheaper than previous methods and is within striking distance of current uranium spot prices at about $70 – 85.

Of course, the challenge is to scale up this lab-sized prototype into something more industrial-sized. What’s interesting about this low-voltage method is that the conversion of uranium oxide ions to solid uranium oxides occurs at both the anode and cathode unlike with previous electrochemical methods. The copper anode becomes part of the electrochemical process, with UO₂ deposited on the cathode and U₃O₈ on the anode.

Among the reported performance statistics of this prototype are the ability to extract UO₂²⁺ ions from an NaCl solution at concentrations ranging from 1 – 50 ppm. At 20 ppm and in the presence of Cl^– ions (as is typical in seawater), the extraction rate was about 100%, compared to ~9.1% for the adsorption method. All of this required only a cell voltage of 0.6 V with 50 mA current, while being highly uranium-selective. Copper pollution of the water is also prevented, as the dissolved copper from the anode was found on the cathode after testing.

The process was tested on actual seawater (East & South China Sea), with ten hours of operation resulting in a recovery rate of 100% and 85.3% respectively. With potential electrode optimizations suggested by the authors, this extraction method might prove to be a viable way to not only recover uranium from seawater, but also at uranium mining facilities and more.

Grid overlayed onto a mason jar. Across the grid are high voltage purple coronas.

High Voltage For Extreme Ozone

May 21, 2025 by Ian Bos 3 Comments

Don’t you hate it when making your DIY X-ray machine you make an uncomfortable amount of ozone gas? No? Well [Hyperspace Pirate] did, which made him come up with an interesting idea. While creating a high voltage supply for his very own X-ray machine, the high voltage corona discharge produced a very large amount of ozone. However, normally ozone is produced using lower voltage, smaller gaps, and large surface areas. Naturally, this led [Hyperspace Pirate] to investigate if a higher voltage method is effective at producing ozone.

Using a custom 150kV converter, [Hyperspace Pirate] was able to test the large gap method compared to the lower voltage method (dielectric barrier discharge). An ammonia reaction with the ozone allowed our space buccaneer to test which method was able to produce more ozone, as well as some variations of the designs.

Continue reading “High Voltage For Extreme Ozone” →

Homebrew PH Meter Uses Antimony Electrode

November 15, 2024 by Dan Maloney 11 Comments

Understanding the nature of pH has bedeviled beginning (and not-so-beginning) chemistry students for nearly as long as chemistry has had students. It all seems so arbitrary, being the base-10 log of the inverse of hydrogen ion concentration and with a measurement range of 0 to 14. Add to that the electrochemical reactions needed to measure pH electronically, and it’s enough to make your head spin.

Difficulties aside, [Markus Bindhammer] decided to tackle the topic and came up with this interesting digital pH meter as a result. Measuring pH electronically is all about the electrode, or rather a pair of electrodes, one of which is a reference electrode. The potential difference between the electrodes when dipped into the solution under test correlates to the pH of the solution. [Markus] created his electrode by drawing molten antimony into a length of borosilicate glass tubing containing a solid copper wire as a terminal. The reference electrode was made from another piece of glass tubing, also with a copper terminal but filled with a saturated solution of copper(II) sulfate and plugged with a wooden skewer soaked in potassium nitrate.

In theory, this electrode system should result in a linear correlation between the pH of the test solution and the potential difference between the electrodes, easily measured with a multimeter. [Marb]’s results were a little different, though, leading him to use a microcontroller to scale the electrode output and display the pH on an OLED.

The relaxing video below shows the build process and more detail on the electrochemistry involved. It might be worth getting your head around this, since liquid metal batteries based on antimony are becoming a thing.

Continue reading “Homebrew PH Meter Uses Antimony Electrode” →

Building A Multi-Purpose Electrochemistry Device

September 13, 2024 by Dave Rowntree 12 Comments

We don’t get enough electrochemistry hacks on these pages, so here’s [Markus Bindhammer] of YouTube/Marb’s lab fame to give us a fix with their hand-built general-purpose electrochemistry device.

The basic structure is made from plyboard cut to size on a table saw and glued’n’screwed together. The top and front are constructed from an aluminium sheet bent to shape with a hand-bender. A laser-printed front panel finishes the aesthetic nicely, contrasting with the shiny aluminium. The electrode holders are part of off-the-shelf chemistry components, with the electrical contacts hand-made from components usually used for constructing stair handrails. Inside, a 500 RPM 12 V DC geared motor is mounted, driving a couple of small magnets. A PWM motor speed controller provides power. This allows a magnetic stirrer to be added for relevant applications. Power for the electrochemical cell is courtesy of a Zk-5KX buck-boost power supply with a range of 0 – 36 V at up to 5 A with both CV and CC modes. A third electrode holder is also provided as a reference electrode for voltammetry applications. A simple and effective build, we reckon!

Over the years, we’ve seen a few electrochemical hacks, like this DIY electroplating pen, a DIY electrochemical machining rig, and finally, a little something about 3D printing metal electrochemically.

Continue reading “Building A Multi-Purpose Electrochemistry Device” →

DIY Chemistry Points The Way To Open Source Blood Glucose Testing

January 4, 2024 by Dan Maloney 16 Comments

Every diabetic knows that one of the major burdens of the disease is managing supplies. From insulin to alcohol wipes, diabetes is a resource-intensive disease, and running out of anything has the potential for disaster. This is especially true for glucose test trips, the little electrochemical dongles that plug into a meter and read the amount of glucose in a single drop of blood.

As you might expect, glucose test strips are highly proprietary, tightly regulated, and very expensive. But the chemistry that makes them work is pretty simple, which led [Markus Bindhammer] to these experiments with open source glucose testing. It’s all part of a larger effort at developing an open Arduino glucometer, a project that has been going on since 2016 but stalled in part thanks to supply chain difficulties on the chemistry side, mainly in procuring glucose oxidase, an enzyme that oxidizes glucose. The reaction creates hydrogen peroxide, which can be measured to determine the amount of glucose present.

With glucose oxidase once again readily available — from bakery and wine-making suppliers — [Markus] started playing with the chemistry. The first reaction in the video below demonstrates how iodine and starch can be used as a reagent to detect peroxide. A tiny drop of glucose solution turns the iodine-starch suspension a deep blue color in the presence of glucose oxidase.

While lovely, colorimetric reactions such as these aren’t optimal for analyzing blood, so reaction number two uses electrochemistry to detect glucose. Platinum electrodes are bathed in a solution of glucose oxidase and connected to a multimeter. When glucose is added to the solution, the peroxide produced lowers the resistance across the electrodes. This is essentially what’s going on in commercial glucose test strips, as well as in continuous glucose monitors.

Hats off to [Markus] for working so diligently on this project. We’re keenly interested in this project, and we’ll be following developments closely. Continue reading “DIY Chemistry Points The Way To Open Source Blood Glucose Testing” →

A cartoon vehicle is connected to two wires. One is connected to an illustrated Li anode and the other to a γ-sulfur/carbon nanofiber electrode. Lithium ions and organic carbonate representations float between the two electrodes below the car. A red dotted line between the electrodes symbolizes the separator.

Lithium Sulfur Battery Cycle Life Gets A Boost

January 24, 2023 by Navarre Bartz 11 Comments

Lithium sulfur batteries are often touted as the next major chemistry for electric vehicle applications, if only their cycle life wasn’t so short. But that might be changing soon, as a group of researchers at Drexel University has developed a sulfur cathode capable of more than 4000 cycles.

Most research into the Li-S couple has used volatile ether electrolytes which severely limit the possible commercialization of the technology. The team at Drexel was able to use a carbonate electrolyte like those already well-explored for more traditional Li-ion cells by using a stabilized monoclinic γ-sulfur deposited on carbon nanofibers.

The process to create these cathodes appears less finicky than previous methods that required tight control of the porosity of the carbon host and also increases the amount of active material in the cathode by a significant margin. Analysis shows that this phase of sulfur avoids the formation of intermediate fouling polysulfides which accounts for it’s impressive cycle life. As the authors state, this is far from a commercial-ready system, but it is a major step toward the next generation of batteries.

We’ve covered the elements lithium and sulfur in depth before as well as an aluminum sulfur battery that could be big for grid storage.