electrochemistry

15 Articles

Homebrew PH Meter Uses Antimony Electrode

November 15, 2024 by 11 Comments

Understanding the nature of pH has bedeviled beginning (and not-so-beginning) chemistry students for nearly as long as chemistry has had students. It all seems so arbitrary, being the base-10 log of the inverse of hydrogen ion concentration and with a measurement range of 0 to 14. Add to that the electrochemical reactions needed to measure pH electronically, and it’s enough to make your head spin.

Difficulties aside, [Markus Bindhammer] decided to tackle the topic and came up with this interesting digital pH meter as a result. Measuring pH electronically is all about the electrode, or rather a pair of electrodes, one of which is a reference electrode. The potential difference between the electrodes when dipped into the solution under test correlates to the pH of the solution. [Markus] created his electrode by drawing molten antimony into a length of borosilicate glass tubing containing a solid copper wire as a terminal. The reference electrode was made from another piece of glass tubing, also with a copper terminal but filled with a saturated solution of copper(II) sulfate and plugged with a wooden skewer soaked in potassium nitrate.

In theory, this electrode system should result in a linear correlation between the pH of the test solution and the potential difference between the electrodes, easily measured with a multimeter. [Marb]’s results were a little different, though, leading him to use a microcontroller to scale the electrode output and display the pH on an OLED.

The relaxing video below shows the build process and more detail on the electrochemistry involved. It might be worth getting your head around this, since liquid metal batteries based on antimony are becoming a thing.

Continue reading “Homebrew PH Meter Uses Antimony Electrode” →

Building A Multi-Purpose Electrochemistry Device

September 13, 2024 by 12 Comments

We don’t get enough electrochemistry hacks on these pages, so here’s [Markus Bindhammer] of YouTube/Marb’s lab fame to give us a fix with their hand-built general-purpose electrochemistry device.

The basic structure is made from plyboard cut to size on a table saw and glued’n’screwed together. The top and front are constructed from an aluminium sheet bent to shape with a hand-bender. A laser-printed front panel finishes the aesthetic nicely, contrasting with the shiny aluminium. The electrode holders are part of off-the-shelf chemistry components, with the electrical contacts hand-made from components usually used for constructing stair handrails. Inside, a 500 RPM 12 V DC geared motor is mounted, driving a couple of small magnets. A PWM motor speed controller provides power. This allows a magnetic stirrer to be added for relevant applications. Power for the electrochemical cell is courtesy of a Zk-5KX buck-boost power supply with a range of 0 – 36 V at up to 5 A  with both CV and CC modes. A third electrode holder is also provided as a reference electrode for voltammetry applications. A simple and effective build, we reckon!

Over the years, we’ve seen a few electrochemical hacks, like this DIY electroplating pen, a DIY electrochemical machining rig, and finally, a little something about 3D printing metal electrochemically.

Continue reading “Building A Multi-Purpose Electrochemistry Device” →

DIY Chemistry Points The Way To Open Source Blood Glucose Testing

January 4, 2024 by 16 Comments

Every diabetic knows that one of the major burdens of the disease is managing supplies. From insulin to alcohol wipes, diabetes is a resource-intensive disease, and running out of anything has the potential for disaster. This is especially true for glucose test trips, the little electrochemical dongles that plug into a meter and read the amount of glucose in a single drop of blood.

As you might expect, glucose test strips are highly proprietary, tightly regulated, and very expensive. But the chemistry that makes them work is pretty simple, which led [Markus Bindhammer] to these experiments with open source glucose testing. It’s all part of a larger effort at developing an open Arduino glucometer, a project that has been going on since 2016 but stalled in part thanks to supply chain difficulties on the chemistry side, mainly in procuring glucose oxidase, an enzyme that oxidizes glucose. The reaction creates hydrogen peroxide, which can be measured to determine the amount of glucose present.

With glucose oxidase once again readily available — from bakery and wine-making suppliers — [Markus] started playing with the chemistry. The first reaction in the video below demonstrates how iodine and starch can be used as a reagent to detect peroxide. A tiny drop of glucose solution turns the iodine-starch suspension a deep blue color in the presence of glucose oxidase.

While lovely, colorimetric reactions such as these aren’t optimal for analyzing blood, so reaction number two uses electrochemistry to detect glucose. Platinum electrodes are bathed in a solution of glucose oxidase and connected to a multimeter. When glucose is added to the solution, the peroxide produced lowers the resistance across the electrodes. This is essentially what’s going on in commercial glucose test strips, as well as in continuous glucose monitors.

Hats off to [Markus] for working so diligently on this project. We’re keenly interested in this project, and we’ll be following developments closely. Continue reading “DIY Chemistry Points The Way To Open Source Blood Glucose Testing” →

A cartoon vehicle is connected to two wires. One is connected to an illustrated Li anode and the other to a γ-sulfur/carbon nanofiber electrode. Lithium ions and organic carbonate representations float between the two electrodes below the car. A red dotted line between the electrodes symbolizes the separator.

Lithium Sulfur Battery Cycle Life Gets A Boost

January 24, 2023 by 11 Comments

Lithium sulfur batteries are often touted as the next major chemistry for electric vehicle applications, if only their cycle life wasn’t so short. But that might be changing soon, as a group of researchers at Drexel University has developed a sulfur cathode capable of more than 4000 cycles.

Most research into the Li-S couple has used volatile ether electrolytes which severely limit the possible commercialization of the technology. The team at Drexel was able to use a carbonate electrolyte like those already well-explored for more traditional Li-ion cells by using a stabilized monoclinic γ-sulfur deposited on carbon nanofibers.

The process to create these cathodes appears less finicky than previous methods that required tight control of the porosity of the carbon host and also increases the amount of active material in the cathode by a significant margin. Analysis shows that this phase of sulfur avoids the formation of intermediate fouling polysulfides which accounts for it’s impressive cycle life. As the authors state, this is far from a commercial-ready system, but it is a major step toward the next generation of batteries.

We’ve covered the elements lithium and sulfur in depth before as well as an aluminum sulfur battery that could be big for grid storage.

Raspberry Pi biosensor with screen-printed electrodes

Raspberry Pi And PpLOGGER Make A Low-Cost Chemiluminescence Detector

December 31, 2022 by 11 Comments

[Laena] and her colleagues at the La Trobe Institute for Molecular Science in Melbourne, Australia used a Raspberry Pi to make a low-cost electrochemiluminescence (ECL) detector to measure inflammation markers, which could be used to detect cardiovascular disease or sepsis early enough to give doctors a better chance at saving a patient’s life.

ECL reactions emit light as a result of an electrically-activated chemical reaction, making them very useful for detecting biochemical markers in blood, saliva, or other biological samples.  ECL setups are fundamentally fairly straightforward. The device includes a voltage reference generator to initiate the chemical reaction and a photomultiplier tube (PMT) to measure the emitted light. The PMT outputs a current which is then converted to a voltage using a transimpedance amplifier (TIA). That signal is then sampled by the DAQCplate expansion board and the live output can be viewed in ppLOGGER in real-time.

Using the RPi allowed the team to do some necessary, but pretty simple signal processing, like converting the TIA voltage back to a photocurrent and integrating the current to obtain the ECL intensities. They mention the added signal processing potential of the RPi was a huge advantage of their setup over similar devices, however, simple integration can be done pretty easily on most any microcontroller. Naturally, they compared their device to a standard ECL setup and found that the results were fairly comparable between the two instruments. Their custom device showed a slightly lower limit of detection than the standard setup.

Their device costs roughly $1756 USD in non-bulk quantities with the PMT being the majority of the cost ($1500). Even at almost $2000, their device provides more than $8000 in savings compared to ECL instruments on the market. Though cost is much more than just the bill of materials, we like seeing the community making efforts to democratize science, and [Laena] and her colleagues did just that. I wonder if they can help us figure out the venus fly trap while they’re at it?

Picture of NanoStat in 3D-printed enclosure with LiPo battery and US quarter for scale.

An ESP32-Based Potentiostat

December 27, 2022 by 3 Comments

Ever wanted to make your own wireless chemical sensor? Researchers from the University of California, Irvine (UC Irvine) have got you covered with their ESP32-based potentiostat.

We’ve talked about potentiostats here on Hackaday before. Potentiostats are instruments that analyze the electrical properties of an electroactive chemical cell. Think oxidation and reduction reactions (redox) from your chemistry course, if you can remember that far back. Potentiostats can be used in several different modes/configurations, but the general idea is for these instruments to induce redox reactions within a given electroactive chemical cell and then measure the resulting current produced by the reaction. By measuring the current, researchers can determine the concentration of a known substance within a sample or even determine the identity of an unknown substance, to name a few potential applications.

These instruments have become mainstays in research labs around the world and have incredible utility in the consumer space. Glucometers, devices used to measure blood glucose levels, are an example of technologies that have made their way into everyday life due to the advances made in electrochemistry and potentiostat research over the last few decades. Given their incredible utility to scientific research and medical technologies, a great deal of effort has gone into democratizing potentiostats, making them more available to the general public for educational and hobbyist purposes. Of course, any medical applications must go through rigorous testing and approvals by each country’s appropriate governing bodies. So we’re talking more non-medical purposes here.

The first popular open-source, DIY potentiostat was the CheapStat, which we’ve covered here on Hackaday before. Since then, developing newer and more advanced open-source potentiostats has become a popular endeavor within the scientific community. The researchers from UC Irvine wanted to put their own special spin on the open-source potentiostat craze and they did so with their inclusion of the ESP32 as their main processor. This obviously opens up them up do a whole host (see what we did there) of wireless capabilities that others before them have not explored.

With the ESP32, they developed a nice web-based GUI that makes controlling and collecting data from the potentiostat very seamless and user-friendly. You can imagine the great possibilities here. Teacher-led classroom demonstrations where the instructor can easily access each student’s device over the cloud to help troubleshoot or explain results. Developing soil monitoring sensors that can be deployed all around a farm to remotely collect data on feed, soil composition, and plant health. The possibilities here sure are promising.

We hope you’ll dive into their paper as it’s well worth a read. Happy hacking, Hackaday.

Low Cost Metal 3D Printing By Electrochemistry

January 23, 2021 by 80 Comments

[Billy Wu] has been writing for a few years about electrochemical 3D printing systems that can handle metal. He’s recently produced a video that you can see below about the process. Usually, printing in metal means having a high-powered laser and great expense. [Wu’s] technique is an extension of electroplating.

Boiling down the gist of the process, the print head is a syringe full of electroplating solution. Instead of plating a large object, you essentially electroplate on tiny areas. The process is relatively slow and if you speed it up too much, the result will have undesirable properties. But there are some mind-bending options here. By using print heads with different electrolytes, you can print using different metals. For example, the video shows structures made of both copper and nickel. You can also reverse the current and remove metal instead of depositing it.

This looks like something you could pretty readily replicate in a garage. Electroplating is well-understood and the 3D motion parts could be a hacked 3D printer. Sure, the result is slow but, after all, slow is a relative term. You might not mind taking a few days to print a metal object compared to the cost and trouble of creating it in other ways. Of course, since this is copper, we also have visions of printing circuit board traces on a substrate. We imagine you’d have to coat the board with something to make it conductive and then remove that after all the copper was in place. When you build this, be sure to tell us about it.

We’ve seen electroplating pens before and that’s really similar to this idea. Of course, you can also make your 3D prints conductive and plate them which is probably faster but isn’t really fully metal.

Continue reading “Low Cost Metal 3D Printing By Electrochemistry” →