Big Chemistry: Fuel Ethanol

If legend is to be believed, three disparate social forces in early 20th-century America – the temperance movement, the rise of car culture, and the Scots-Irish culture of the South – collided with unexpected results. The temperance movement managed to get Prohibition written into the Constitution, which rankled the rebellious spirit of the descendants of the Scots-Irish who settled the South. In response, some of them took to the backwoods with stills and sacks of corn, creating moonshine by the barrel for personal use and profit. And to avoid the consequences of this, they used their mechanical ingenuity to modify their Fords, Chevrolets, and Dodges to provide the speed needed to outrun the law.

Though that story may be somewhat apocryphal, at least one of those threads is still woven into the American story. The moonshiner’s hotrod morphed into NASCAR, one of the nation’s most-watched spectator sports, and informed much of the car culture of the 20th century in general. Unfortunately, that led in part to our current fossil fuel predicament and its attendant environmental consequences, which are now being addressed by replacing at least some of the gasoline we burn with the same “white lightning” those old moonshiners made. The cost-benefit analysis of ethanol as a fuel is open to debate, as is the wisdom of using food for motor fuel, but one thing’s for sure: turning corn into ethanol in industrially useful quantities isn’t easy, and it requires some Big Chemistry to get it done.
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Copper Candle Burns Forever… Just Add Fuel

[Zen Garden Oasis] wanted to heat and light a space using a candle. But candles aren’t always convenient since they burn down and, eventually, you must replace them. So he built copper candles using a common copper pipe and an old glass jar. Of course, the candle still takes fuel that you have to replace, but the candle itself doesn’t burn down.

The basic idea is that the copper tube holds a high-temperature carbon wick that stays saturated with fuel. The fuel burns, but the wick material doesn’t. The copper part is actually concentric with a 3/4-inch pipe mostly enclosing a 1/2-inch pipe.

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3D Printed Engine Gets Carburetor

3D printed materials have come a long way in the last decade or so as printers have become more and more mainstream. Printers can use all kinds of different plastics with varying physical characteristics, and there are even printers now for other materials like concrete and metal. But even staying within the realm of the plastic printer can do a lot of jobs you might not expect. [Camden Bowen] recently 3D printed a single-piston engine which nearly worked, and is back with some improvements to it thanks to a small carburetor.

The carburetor itself isn’t 3D printed (although not from lack of trying) — it’s on loan from a weed eater, and is helping to solve a problem with the fuel-air mixture of his original design. Switching from butane to a liquid fuel also solved some problems as well, and using starter fluid also helped to kick off the ignition. Although it ran for a short period of time over several starts, the valve train suffered some damage with the exhaust valves melting in place to the head. This is actually a problem common to any internal combustion engine like this, especially if the fuel-air mixture is too lean, there’s incomplete combustion, the valves aren’t adjusted properly, or any number of other problems. In this case it seems to have been caused by improper engine timing.

It’s actually noteworthy though that the intake valves weren’t burned, meaning that if the engine can be tuned to allow for complete combustion before the exhaust gasses leave the combustion chamber, the plastic 3D printed head and valve train will likely survive much longer operational periods. We’ll certainly look forward to the next iteration of this engine build to see if that’s the case. If 3D printed piston engines aren’t your speed, though, take a look at this jet engine which uses a 3D printed compressor.

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Make Your Own Vinegar

Making fermentation work for us is one of the original hacks that allowed humans to make food last longer, and festivities more interesting. [Mike G] has been experimenting with making his own vinegar, and found the end product to be a delicious addition to his cooking.

The first step is similar to making alcoholic beverages. Take something that contains sugar, like fruit, mix it with water and let stand. Wild yeast will feed on the sugar and create alcohol. Once the alcohol content reaches the 6-12% range, the resulting liquid can be separated from the solids and left exposed to the air. This allows Acetobacter bacteria to convert the alcohol into aceticĀ acid, producing vinegar. The entire process takes around 30 days.

[Mike]’s first round of experiments was mainly with fresh fruit, with the addition of raisins. To prevent white mold from forming the mixtures should be stirred daily, but life got in the way and mold got out of control on all the fruits, except for the raisins. This gave [Mike] the to try another round with dried fruit, which was significantly less prone to mold, and produced deliciously flavored vinegar. [Mike] also demonstrated their use in a couple of mouth-watering dishes.

The DIY vinegar production process is just begging for some fermentation monitoring and automation tech. We’ve seen plenty of sourdough and beer production projects, which we suspect could also be applied to vinegar production with some minor changes.

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Will A Kettle Filled With Alcohol Boil Dry?

The average home kettle is set up to switch off automatically when water reaches its boiling point. But would a kettle filled with alcohol, which has a significantly lower boiling point, actually turn off? [Steve Mould] set out to find out.

The prediction was that a kettle full of 40% strength vodka would boil dry, as the vodka would evaporate before it actually got to a hot enough temperature to cause the kettle’s cutout mechanism to kick in. The experiment was done outside to minimise the dangers from the ethanol vapor. As it turns out, the vapor from the boiling vodka is about 80% ethanol and just 20% water, so eventually the mixture left in the kettle is mostly water and it boils hot enough to trigger the cutout mechanism.

However, the experiment doesn’t end there. Trying again with 99% ethanol, when the fluid started boiling, the kettle switched off even more quickly. So what’s going on?

The kettle in question uses a bimetallic strip, which trips the switch off in the base of the kettle when it gets too hot. There’s also a tube inside the kettle that carries vapor from the internal cavity and lets it pass over the bimetallic strip. When the liquid inside the kettle boils, it forces hot vapor through the tube, out of the kettle and over the bimetallic strip.

This strip triggers at a temperature significantly lower than the boiling point of water; indeed, as long as the liquid in the kettle is fairly hot and is boiling enough to force vapor out the tube, the kettle will switch off. [Steve] points out that it’s a good mechanism, as this mechanism allows the kettle to respond to boiling itself, rather than the arbitrary 100 C point which water technically only boils at when one is at sea level.

It’s an interesting look at a safety system baked into something many of us use every day without even thinking. It’s not the first time we’ve seen [Steve] dive deep into the world of tea-making apparatus, either. Video after the break.

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Faster IPA Recycling For Your Resin Print Workflow

If you’ve printed with photopolymer resins, you know that you need alcohol. Lots of alcohol. It makes sense that people would like to reuse the alcohol both to be environmentally responsible and to save a little money. The problem is that the alcohol eventually becomes so dirty that you have to do something. Given time, the polymer residue will settle to the bottom and you can easily pour off most of the clean liquid. You can also use filters with some success. But [Makers Mashup] had a different idea. Borrowing inspiration from water treatment plants, he found a chemical that will hasten the settling process. You can see a video of his process below.

The experimentation started with fish tank clarifier, which is — apparently — mostly alum. Alum’s been used to treat wastewater for a long time. Even the ancient Romans used it for that purpose in the first century. Alum causes coagulation and flocculation so that particles in the water wind up sinking to the bottom.

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Art of 3D printer in the middle of printing a Hackaday Jolly Wrencher logo

3D Printering: Wash Parts Better And Make Solvent Last Longer

SLA printing in resin is great, but part washing can be a hassle. The best results come from a two-stage wash, but that also means more material and more processing steps. Fortunately, there are ways to make it easier and more effective. One such way is to use a part washing machine, and I’ll cover a DIY option to make your own, but despite what the advertising implies for the commercial ones, a wash machine isn’t a cure-all.

Let’s go through how to get the best results from part washing, how to make the solvent last as long as possible, and how to dispose of the eventual waste.

Resin-Printed Parts Need Washing

All parts printed in resin emerge from the printer coated in syrupy, uncured goop. This needs to be removed completely, or the print ends up sticky and no amount of drying or additional UV curing will change that. (There is a way to fix sticky prints, but it’s better to avoid the situation in the first place.)

Simple part washing can be done with nothing more than a jar in which to rinse and soak a small part for about ten minutes, but agitation and a secondary wash will go a long way toward better and more consistent results. As mentioned, part washing machines like to present themselves as a one-appliance solution, but best results still come from a two-stage wash, and that means some additional steps.

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