redox

5 Articles

Homebrew PH Meter Uses Antimony Electrode

November 15, 2024 by 11 Comments

Understanding the nature of pH has bedeviled beginning (and not-so-beginning) chemistry students for nearly as long as chemistry has had students. It all seems so arbitrary, being the base-10 log of the inverse of hydrogen ion concentration and with a measurement range of 0 to 14. Add to that the electrochemical reactions needed to measure pH electronically, and it’s enough to make your head spin.

Difficulties aside, [Markus Bindhammer] decided to tackle the topic and came up with this interesting digital pH meter as a result. Measuring pH electronically is all about the electrode, or rather a pair of electrodes, one of which is a reference electrode. The potential difference between the electrodes when dipped into the solution under test correlates to the pH of the solution. [Markus] created his electrode by drawing molten antimony into a length of borosilicate glass tubing containing a solid copper wire as a terminal. The reference electrode was made from another piece of glass tubing, also with a copper terminal but filled with a saturated solution of copper(II) sulfate and plugged with a wooden skewer soaked in potassium nitrate.

In theory, this electrode system should result in a linear correlation between the pH of the test solution and the potential difference between the electrodes, easily measured with a multimeter. [Marb]’s results were a little different, though, leading him to use a microcontroller to scale the electrode output and display the pH on an OLED.

The relaxing video below shows the build process and more detail on the electrochemistry involved. It might be worth getting your head around this, since liquid metal batteries based on antimony are becoming a thing.

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Illustrated Kristina with an IBM Model M keyboard floating between her hands.

Keebin’ With Kristina: The One With The Tri-lingual Typewriter

January 18, 2022 by 5 Comments

Isn’t it just fantastic when a project finally does what you wanted it to do in the first place? [Simon Merrett] isn’t willing to compromise when it comes to the Aerodox. His original vision for the keyboard was a wireless, ergonomic split that could easily switch between a couple of PCs. Whereas some people are more into making layout after layout, [Simon] keeps pushing forward with this same design, which is sort of a mashup between the ErgoDox and the Redox, which is itself a wireless version of the ErgoDox.

The Aerodox has three nRF51822 modules — one for the halves to communicate, one for the control half to send key presses, and a third on the receiver side. [Simon] was using two AA cells to power each one, and was having trouble with the range back to the PC.

The NRFs want 3.3 V, but will allegedly settle for 2 V when times are hard. [Simon] added a boost converter to give each a solid 3.3 V, and the Aerodox became reliable enough to be [Simon]’s daily driver. But let’s go back to the as-yet-unrealized potential part.

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Redox Redux: Split Keeb Gets A Num Pad

June 10, 2021 by 7 Comments

What’s the worst thing about split keyboards? If they have one general fault, it’s that almost none of them have a number pad. If you can fly on that thing, but struggle with using the top row numbers, you will miss the num pad terribly, trust us. So what’s the answer? Design your own keyboard, of course. [ToasterFuel] had enough bread lying around to cook up a little experiment for his first keyboard build, and we think the result is well done, which is kind of rare for first keebs.

This design is based on the Redox, itself a remix of the ErgoDox that aims to address the common complaints about the latter — it’s just too darn big, and the thumb clusters are almost unusable. We love how customized this layout is, with its sprinkling of F keys and Escape in the Caps Lock position. Under those keycaps you’ll find 100% Cherry MX greens, so [ToasterFuel] must have pretty strong fingers to pound those super clackers.

Everything else under the hood is pretty standard, with a pair of Arduino Pro Micros running the show. [ToasterFuel] had to wire up the whole thing by hand because of the num pad, and we’re impressed that he built this entire project in just three weeks. And that includes writing his own firmware!

Already found or built a split you love, but still miss the num pad? Why not build one to match your keyboard?

Cheap PSoC Enables Electrochemistry Research

August 4, 2018 by 8 Comments

You may think electrochemistry sounds like an esoteric field where lab-coated scientists labor away over sophisticated instruments and publish papers that only other electrochemists could love. And you’d be right, but only partially, because electrochemistry touches almost everything in modern life. For proof of that look no further than your nearest pocket, assuming that’s where you keep your smartphone and the electrochemical cell that powers it.

Electrochemistry is the study of the electrical properties of chemical reactions and does indeed need sophisticated instrumentation. That doesn’t mean the instruments have to break the grant budget, though, as [Kyle Lopin] shows with this dead-simple potentiostat built with one chip and one capacitor. A potentiostat controls the voltage on an electrode in an electrochemical cell. Such cells have three electrodes — a working electrode, a reference electrode, and a counter electrode. The flow of electrons between these electrodes and through the solutions under study reveal important properties about the reduction and oxidation states of the reaction. Rather than connect his cell to an expensive potentiostat, [Kyle] used a Cypress programmable system-on-chip development board to do everything. All that’s needed is to plug the PSoC into a USB port for programming, connect the electrodes to GPIO pins, and optionally add a 100 nF capacitor to improve the onboard DAC’s accuracy. The video below covers the whole process, albeit with a barely audible voiceover.

Still not sure about electrochemistry? Check out this 2018 Hackaday Prize entry that uses the electrochemistry of life to bring cell phones back to life.

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See If You Can Reverse Engineer This Scrap Metal Battery

November 5, 2016 by 46 Comments

We got quite a few tips in about a paper from Vanderbilt about a cool scrap metal battery they’ve been playing with. They made some pretty bold claims and when we fed the numbers in they pretty much say they’ve got a battery you can make at home, that can hold half as much as a lead acid, can be made out of scraps in a cave (even if you’re not Tony Stark), charge super fast,and can cycle 5,000 times without appreciable capacity loss.  Needless to say that’s super cool.

Of course, science research is as broken as ever and the paper was hidden behind a paywall. Through mysterious powers such as the library and bothering people we were able to get past this cunning defense and read the paper. Unfortunately the paper reads more like a brag track than a useful experimental guide on how to build the dang battery. It’s also possible that our copy was missing some pages. Anyway, we want to do science!

Anyway, here’s what we know. The battery is based on an ancient battery called the Baghdad Battery. The ancient battery supposedly used iron and copper with a mystery electrolyte. The scrap battery, however, is made from scrap iron and scrap brass. The iron makes sense, but why brass? Well, brass has copper in it, and you can still get at it chemically even if it’s alloyed.

To that end, the next step was to throw some oxygen atoms in with those pesky Fe and Cu ones. The goal is to get a redox reaction going. If you do it right you can achieve pseudocapacitance. To to this the researchers used “common household chemicals and voltages” to anodize the iron and copper inside the brass. The press photo have them holding a gallon of muratic acid, if that helps. We don’t know, but if they can jam a few oxygen atoms in there then so can we!

After that it’s all about sitting the electrodes in a bath of potassium hydroxide. We guess you can scrape the inside of an AA for that. Anyway, the paper’s light on process but the battery seems really cool. They’re not pursuing this research for commercialization, instead going the OSHW route. They hope to get to the point where anyone can just grind up a bunch of scrap steel and brass, maybe throw it in a birdcage, anodize it, and get a super long life battery for grid use for less than a lead acid. If any of you manage to build one of these drop us a tip!