Mining And Refining: Pure Silicon And The Incredible Effort It Takes To Get There

November 15, 2021 by Dan Maloney 30 Comments

Were it not for the thin sheath of water and carbon-based life covering it, our home planet would perhaps be best known as the “Silicon World.” More than a quarter of the mass of the Earth’s crust is silicon, and together with oxygen, the silicate minerals form about 90% of the thin shell of rock that floats on the Earth’s mantle. Silicon is the bedrock of our world, and it’s literally as common as dirt.

But just because we have a lot of it doesn’t mean we have much of it in its pure form. And it’s only in its purest form that silicon becomes the stuff that brought our world into the Information Age. Elemental silicon is very rare, though, and so getting appreciable amounts of the metalloid that’s pure enough to be useful requires some pretty energy- and resource-intensive mining and refining operations. These operations use some pretty interesting chemistry and a few neat tricks, and when scaled up to industrial levels, they pose unique challenges that require some pretty clever engineering to deal with.

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Magnesium: Where It Comes From And Why We’re Running Out

November 1, 2021 by Adam Zeloof 94 Comments

Okay, we’re not running out. We actually have tons of the stuff. But there is a global supply chain crisis. Most of the world’s magnesium is processed in China and several months ago, they just… stopped. In an effort to hit energy consumption quotas, the government of the city of Yulin (where most of the country’s magnesium production takes place) ordered 70% of the smelters to shut down entirely, and the remainder to slash their output by 50%. So, while magnesium remains one of the most abundant elements on the planet, we’re readily running out of processed metal that we can use in manufacturing.

Nikon camera body — The magnesium-alloy body of a Nikon d850. Courtesy of Nikon

But, how do we actually use magnesium in manufacturing anyway? Well, some things are just made from it. It can be mixed with other elements to be made into strong, lightweight alloys that are readily machined and cast. These alloys make up all manner of stuff from race car wheels to camera bodies (and the chassis of the laptop I’m typing this article on). These more direct uses aside, there’s another, larger draw for magnesium that isn’t immediately apparent: aluminum production.

But wait, aluminum, like magnesium is an element. So why would we need magnesium to make it? Rest assured, there’s no alchemy involved- just alloying. Much like magnesium, aluminum is rarely used in its raw form — it’s mixed with other elements to give it desirable properties such as high strength, ductility, toughness, etc. And, as you may have already guessed, most of these alloys require magnesium. Now we’re beginning to paint a larger, scarier picture (and we just missed Halloween!) — a disruption to the world’s aluminum supply.

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A Fascinating Plot Twist As Researchers Recreate Classic “Primordial Soup” Experiment

October 31, 2021 by Dan Maloney 46 Comments

Science is built on reproducibility; if someone else can replicate your results, chances are pretty good that you’re looking at the truth. And there’s no statute of limitations on reproducibility; even experiments from 70 years ago are fair game for a fresh look. A great example is this recent reboot of the 1952 Miller-Urey “primordial soup” experiment which ended up with some fascinating results.

At the heart of the Miller-Urey experiment was a classic chicken-and-the-egg paradox: complex organic molecules like amino acids and nucleic acids are the necessary building blocks of life, but how did they arise on Earth before there was life? To answer that, Stanley Miller, who in 1952 was a graduate student of Harold Urey, devised an experiment to see if complex molecules could be formed from simpler substances under conditions assumed to have been present early in the planet’s life. Miller assembled a complicated glass apparatus, filled it with water vapor and gasses such as ammonia, hydrogen, and methane, and zapped it with an electric arc to simulate lightning. He found that a rich broth of amino acids accumulated in the reaction vessel; when analyzed, the sludge was found to contain five of the 20 amino acids.

The Miller-Urey experiment has been repeated over and over again with similar results, but a recent reboot took a different tack and looked at how the laboratory apparatus itself may have influenced the results. Joaquin Criado-Reyes and colleagues found that when run in a Teflon flask, the experiment produced far fewer organic compounds. Interestingly, adding chips of borosilicate glass to the Teflon reaction chamber restored the richness of the resulting broth, suggesting that the silicates in the glassware may have played a catalytic role in creating the organic soup. They also hypothesize that the highly alkaline reaction conditions could create microscopic pits in the walls of the glassware, which would serve as reaction centers to speed up the formation of organics.

This is a great example of a finding that seems to knock a hole in a theory but actually ends up supporting it. On the face of it, one could argue that Miller and Urey were wrong since they only produced organics thanks to contamination from their glassware. And it appears to be true that silicates are necessary for the abiotic generation of organic molecules. But if there was one thing that the early Earth was rich in, it was silicates, in the form of clay, silt, sand, rocks, and dust. So this experiment lends support to the abiotic origin of organic molecules on Earth, and perhaps on other rocky worlds as well.

[Featured image credit: Roger Ressmeyer/CORBIS, via Science History Institute]

How Much Is That Shirt In The (Atmospheric) Window?

October 26, 2021 by Kristina Panos 41 Comments

Summer is fading into a memory now, but as surely as the earth orbits the sun, those hot and sweaty days will return soon enough. And what can you do about it at the level of a single, suffering human being? After all, a person can only remove so much clothing to help cool off. Until someone figures out a way to make those stillsuits from Dune, we need an interim solution in which to drape ourselves.

We’ve seen the whitest paint possible for cooling buildings, and then we saw a newer, whiter and more award-winning paint a few months later. This paint works by the principle of passive cooling. Because of its color and composition, it reflects most light and absorbs some heat, which gets radiated away into the mid-infrared spectrum. It does this by slipping out Earth’s atmospheric window and into space. Now, a team based in China have applied the passive cooling principle to fabric. Continue reading “How Much Is That Shirt In The (Atmospheric) Window?” →

They Milk Cows, Don’t They?

October 18, 2021 by Kristina Panos 90 Comments

You’ve no doubt heard of the many alternatives to cow’s milk that are available these days. Perhaps you’ve even tried a few of them in your quest to avoid lactose. Some coffeehouses have already moved on from soy milk, offering only oat or almond milk instead of 2% and whole. Their reasoning is that soy milk is a highly processed product that can’t be traced back to a single source, which stands in stark contrast to all those bags of single-origin coffee beans.

These nut-based alternatives kicked off what is known as the milk wars — the dairy industry’s fight against labeling plant-based dairy alternatives as ‘milk’ and so on. Well, now it’s getting even more interesting. A company called Perfect Day is making milk using microorganisms that secrete milk proteins. It may sound kind of gross, but it’s essentially microbial fermentation, which is the normal process by which bread, cheese, yogurt, wine, and beer are made.

To be fair, what Perfect Day and other companies are doing is precision fermentation using genetically engineered microorganisms in a bioreactor, so it’s a bit more involved than what you could probably pull off in the basement. Precision fermentation lies somewhere between two modern extremes — plant-based meat and cultured meat. The latter is actual animal tissue grown from stem cells, and is only available at high-end restaurants for exorbitant prices.

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Electric Vehicles, The Gasoline Problem, And Synthetic Fuels

October 18, 2021 by Dan Maloney 115 Comments

When you’re standing at the gas station filling up your car, watching those digits on the pump flip by can be a sobering experience. Fuel prices, especially the price of gasoline, have always been keenly watched, so it’s hard to imagine a time when gasoline was a low-value waste product. But kerosene, sold mainly for lighting, was once king of the petroleum industry, at least before the automobile came along, to the extent that the gasoline produced while refining kerosene was simply dumped into streams to get rid of it.

The modern mind perhaps shudders at the thought of an environmental crime of that magnitude, and we can’t imagine how anyone would think that was a good solution to the problem. And yet we now face much the same problem, as the increasing electrification of the world’s fleet of motor vehicles pushes down gasoline demand. To understand why this is a problem, we’ll start off by taking a look at how crude oil is formed, and how decreasing demand for gasoline may actually cause problems that we should think about before we get too far down the road.

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Making Coffee With Hydrogen

October 9, 2021 by Jenny List 17 Comments

Something of a Holy Grail among engineers with an interest in a low-carbon future is the idea of replacing fossil fuel gasses with hydrogen. There are various schemes, but they all suffer from the problem that hydrogen is difficult stuff to store or transport. It’s not easily liquefied, and the tiny size of its molecule means that many containment materials that are fine for methane simply won’t hold on to it.

[Isographer] has an idea: to transport the energy not as hydrogen but as metallic aluminium, and generate hydrogen by reaction with aqueous sodium hydroxide. He’s demonstrated it by generating enough hydrogen to make a cup of coffee, as you can see in the video below the break.

It’s obviously very successful, but how does it stack up from a green perspective? The feedstocks are aluminium and sodium hydroxide, and aside from the hydrogen it produces sodium aluminate. Aluminium is produced by electrolysis of molten bauxite and uses vast amounts of energy to produce, but since it is often most economic to do so using hydroelectric power then it can be a zero-carbon store of energy. Sodium hydroxide is also produced by an electrolytic process, this time using brine as the feedstock, so it also has the potential to be produced with low-carbon electricity. Meanwhile the sodium aluminate solution is a cisutic base, but one that readily degrades to inert aluminium oxide and hydroxide in the environment. So while it can’t be guaranteed that the feedstock he’s using is low-carbon, it’s certainly a possibility.

So given scrap aluminium and an assortment of jars it’s possible to make a cup of hot coffee. It’s pretty obvious that this technology won’t be used in the home in this way, but does that make it useless? It’s not difficult to imagine energy being transported over distances as heavy-but-harmless aluminium metal, and we’re already seeing a different chemistry with the same goal being used to power vehicles.

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