Grocery Store Rocket Fuel: Don’t Try This At Home!

February 25, 2022 by Ryan Flowers 30 Comments

It seems like whenever the topic of rocket science comes up, the conversation quickly shifts to that of rocket fuels. As discussed in the excellent [Scott Manley] video below the break, there are many rocket fuels that can be found in some way, state, or form at your local grocery or liquor store. The video itself is a reaction to some college students in Utah who caused an evacuation when the rocket fuel they were cooking up exploded.

[Scott] himself theorizes that the fuel they were cooking was Rocket Candy, a volatile mix of sugar and potassium nitrate that is known to go Kaboom on occasion. And as it turns out, the combination might not even be legal in your area because as much as it can be used as rocket fuel, it can also be used for other things that go boom.

So, what else at your local megamart can be used to get to orbit? [Scott] talks about different kinds of alcohols, gasses, cleaners- all things that can be used as rocket fuel. He also talks about all of the solid reasons you don’t want to do this at home.

If this type of things gets your molecules excited, you might enjoy a bit we posted recently about using another grocery store staple to save Martian colonists from being held back by gravity.

Big Chemistry: From Gasoline To Wintergreen

February 22, 2022 by Dan Maloney 18 Comments

Most of us probably have some vivid memories of high school or college chemistry lab, where the principles of the science were demonstrated, and where we all got at least a little practice in experimental methods. Measuring, diluting, precipitating, titrating, all generally conducted under safe conditions using stuff that wasn’t likely to blow up or burn.

But dropwise additions and reaction volumes measured in milliliters are not the stuff upon which to build a global economy that feeds, clothes, and provides for eight billion people. For chemistry to go beyond the lab, it needs to be scaled up, often to a point that’s hard to conceptualize. Big chemistry and big engineering go hand in hand, delivering processes that transform the simplest, most abundant substances into the things that, for better or worse, make life possible.

To get a better idea of how big chemistry does that, we’re going to take a look at one simple molecule that we’ve probably all used at one time or another: the common artificial flavoring wintergreen. It’s an innocuous ingredient in a wide range of foods and medicines, but the infrastructure required to make it and all its precursors is a snapshot of just how important big chemistry really is.

Continue reading “Big Chemistry: From Gasoline To Wintergreen” →

Mining And Refining: Lithium, Powering The Future With Brine

February 9, 2022 by Dan Maloney 28 Comments

Many years ago, I read an article about the new hotness: lithium batteries. The author opened with what he no doubt thought was a clever pop culture reference by saying that the mere mention of lithium would “strike fear in the hearts of Klingons.” It was a weak reference to the fictional “dilithium crystals” of Star Trek fame, and even then I found it a bit cheesy, but I guess he had to lead with something.

Decades later, a deeper understanding of the lore makes it clear that a Klingon’s only fear is death with dishonor, but there is a species here on earth that lives in dread of lithium: CEOs of electric vehicle manufacturing concerns. For them, it’s not the presence of lithium that strikes fear, but the relative absence of it; while it’s the 25th most abundant element in the Earth’s crust, and gigatons are dissolved into the oceans of the world, lithium is very reactive and thus tends to be diffuse, making it difficult to obtain concentrated in the quantities their businesses depend on.

As the electric vehicle and renewable energy markets continue to grow, the need for lithium to manufacture batteries will grow with it, potentially to the point where demand outstrips the mining industry’s production capability. To understand how that imbalance may be possible, we’ll take a look at how lithium is currently mined, as well as examine some new mining techniques that may help fill the coming lithium gap.

Continue reading “Mining And Refining: Lithium, Powering The Future With Brine” →

The Road Is Peppered With Rock Salt Alternatives

January 25, 2022 by Kristina Panos 79 Comments

Every winter, millions of tons of rock salt is sprinkled across roads in the US, mostly in the Midwest and Northeast regions. It’s a cheap and effective way to prevent accidents. Rock salt is chemically the same as the stuff that sits next to the pepper, except it isn’t as finely ground, and it doesn’t have sodium or potassium iodine added to it to prevent goiters. Both table salt and rock salt melt ice by lowering the freezing point of water. So does sugar.

Much of what we salt the Earth with every winter comes from underground networks of salt crystal that formed when various ancient seas dried up. As natural as it may be, rock salt is bad for the environment. For one thing, chloride is forever, and can’t easily be decoupled from the soil and water it taints when it washes away. Rock salt also corrodes concrete, makes its way into the groundwater, and is bad for pets. Worst of all, its efficacy drops along with the temperature. At 15° F (-9° C), rock salt loses more than 86% of its melting power.

Disposable Detroit

All this salt is not great for cars, either — it’s bad for the paint and eats up the frame. In the saltiest parts of the US, aka The Salt Belt, cars only last a handful of years before they become Flintstones mobiles. Well, not really, but salt is terrible for the brake lines and most of the undercarriage. Consumer woes aside, there’s a real environmental impact to manufacturing all these disposable cars to meet the demand.

But the problem is that we need to use salt, or at something like it. Even though millions of people are staying home a whole lot more, the trucking industry still relies on salted highways and local roads. So if you like stocked grocery stores and stuff arriving from the Bezos Barn in a timely fashion, you can see the problem. So what are the alternatives? Are there any?

Continue reading “The Road Is Peppered With Rock Salt Alternatives” →

Falling Down The Carbon Rabbit Hole

January 11, 2022 by Matthew Carlson 18 Comments

Research projects have a funny way of getting blown out of proportion by the non-experts, over-promising the often relatively small success that the dedicated folks doing the science have managed to eke out. Scaling-up cost-effectively is one of the biggest killers for commercializing research, which is why recent developments in creating carbon nanotube transistors have us hopeful.

Currently, most cutting-edge processes use FETs (Field Effect Transistors). As they’ve gotten smaller, we’ve added fins and other tricks to get around the fact that things get weird when they’re small. The industry is looking to move to GAAFETs (Gate All Around FET) as Intel and Samsung have declared their 3 nm processes (or equivalent) will use the new type of gate. As transistors have shrunk, the “off-state” leakage current has grown. GAAFETs are multi-gate devices, allowing better control of that leakage, among other things.

As usual, we’re already looking at what is past 3 nm towards 2 nm, and the concern is that GAAFET won’t scale past 3 nm. Carbon Nanotubes are an up-and-coming technology as they offer a few critical advantages. They conduct heat exceptionally well, exhibit higher transconductance, and conduct large amounts of power. In addition, they show higher electron mobility than conventional MOSFETs and often outperform them with less power even while being at larger sizes. This is all to say that they’re an awesome piece of tech with a few caveats. Continue reading “Falling Down The Carbon Rabbit Hole” →

Automated Mushroom Cultivation Yields Delicious Fried Goodies

January 9, 2022 by Donald Papp 30 Comments

[Kyle Gabriel] knows mushrooms, and his years of experience really shine through in his thorough documentation of an automated mushroom cultivation environment, created with off-the-shelf sensors and hardware as much as possible. The results speak for themselves, with some delicious fried oyster mushrooms to show for it!

Fried oyster mushrooms, grown from scratch.

The most influential conditions for mushroom cultivation are temperature, humidity, and CO2 concentration, and to automate handling the environmental conditions [Kyle] created Mycodo, an open-source system that leverages inexpensive hardware and parts while also having the ability to take regular photos to keep an eye on things.

Calling [Kyle]’s documentation “comprehensive” doesn’t do it justice, and he addresses everything from setting up a positive pressure air filtration system for a work area, to how to get usable cultures from foraged mushrooms, all the way through growth and harvesting. He even includes a delicious-looking recipe for fried mushrooms. It just doesn’t get more comprehensive than that.

We’ve seen [Kyle]’s earlier work before, and it’s fantastic to see the continued refinement. Check out a tour of the whole thing in the video embedded below (or skip to 16:11 if you want to make yourself hungry.)

Continue reading “Automated Mushroom Cultivation Yields Delicious Fried Goodies” →

Growing Spectacular Gem-Like Crystals From Rust And Simple Ingredients

January 4, 2022 by Dan Maloney 33 Comments

When we talk about crystals around here, we’re generally talking about the quartz variety used to make oscillators more stable, or perhaps ruby crystals used to make a laser. We hardly ever talk about homegrown crystals, though, and that’s a shame once you see how easy it is to make beautiful crystals from scratch.

We’ve got to say that we’re impressed by the size and aesthetics of the potassium ferrioxalate crystals [Chase Lean] makes with this recipe, and Zelda fans will no doubt appreciate their resemblance to green rupees. The process starts with rust, or ferric oxide, which can either be purchased or made. [Chase] chose to make his rust by soaking steel wool in a solution of saltwater and peroxide and heating the resulting sludge. A small amount of ferric oxide is added to a solution of oxalic acid, a commonly used cleaning and bleaching agent. Once the rust is dissolved, potassium carbonate is slowly added to the solution, turning it a bright green.

The rest of the process happens more or less naturally, as crystals begin to form in the saturated solution. And boy, did they grow — long, prismatic lime-green crystals, with a beautiful clarity and crisp edges and facets. The crystals don’t last long under light, though — they quickly lose their clarity and become a more opaque green.

[Chase]’s crystal-growing efforts have shown up here before, when he turned humble table salt into beautiful cubic crystals. We find the whole crystal-growing process fascinating, and we’re looking forward to more of this in the future.