Who Needs Gasoline When You’ve Got Sodium?

March 23, 2023 by Dave Rowntree 58 Comments

YouTuber and serial debunker [Thunderf00t] was thinking about the use of sodium to counteract global warming. The theory is that sodium can be used as a fuel when combusted with air, producing a cloud of sodium hydroxide which apparently can have a cooling effect if enough of it is kicking around the upper atmosphere. The idea is to either use sodium directly as a fuel, or as a fuel additive, to increase the aerosol content of vehicle emissions and maybe reduce their impact a little.

One slight complication to using sodium as a fuel is that it’s solid at room temperature, so it would need to be either delivered as pellets or in liquid form. That’s not a major hurdle as the melting point is a smidge below 100 degrees Celsius and well within the operating region of an internal combustion engine, but you can imagine the impact of metal solidifying in your fuel system. Luckily, just like with solder eutectic mixes, sodium-potassium alloy happens to remain in liquid form at handleable temperatures and only has a slight tendency to spontaneously ignite. So that’s good.

Initial experiments using ultrasonic evaporators proved somewhat unsuccessful due to the alloy’s electrical conductivity and tendency to set everything on fire. The next attempt was using a standard automotive fuel injector from the petrol version of the Ford Fiesta. Using a suitable container, a three-way valve to allow the introduction of fuels, and an inert argon feed (preventing spontaneous combustion in the air), delivering the liquid metal fuel into the fuel injector seems straightforward enough.

[Thunderf00t] started with ethanol, then worked up to pentane before finally attempting to use the feisty sodium-potassium, once the bugs had been shaken out of the high-speed video setup. [Thunderf00t] does stress the importance of materials selection when handling this potential liquid metal fuel, since it apparently just bursts into flames in a violent manner on contact with incompatible materials. Heck, this stuff even reacts with PTFE, which is generally considered a very resistant material. We’re totally convinced we’d not like to see this stuff being pumped from a roadside gas station, at all, but it sure is a fun concept to think about.

Sodium-Potassium alloy doesn’t feature on these pages too often, but here’s a little fountain of the stuff, just because why not?

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3D Printing With Rice Might Be Nice

February 17, 2023 by Al Williams 36 Comments

The United Nations Industrial Development Organization recently pointed out a possible replacement for petrochemical-based polymers: rice resin. A Japanese company makes the material from inedible rice and also makes a biodegradable polymer known as Neoryza, which seems to contain some amount of rice as well. The rice resin contains 10 to 70% rice waste. You can see a video with English subtitles about the material below.

According to the video, there is plenty of waste rice. The resulting resin isn’t as toxic as petrochemical-based plastics and doesn’t consume food crops like other plant-based polymers. The video shows the rice resin being extruded like a normal polymer, so it should work like any other thermoplastic.

The video says the properties are similar to petrochemical-based plastics and no special equipment is required to handle it. They also claim that production is easier because, unlike other bioplastics, they don’t generate ethanol as the first part of the process. Waste rice should be cheap to obtain since it is essentially trash today. We aren’t sure what polymers are used in the 90 to 30% of the plastic that isn’t rice, but presumably, that is being brought in as a raw material.

We’ll be interested to see if anyone tries to make 3D printing filament from the stuff. We know that it is being used to replace polyethylene in furniture. We couldn’t help but think about using waste coffee grounds in 3D printing. If you want to compare this to PLA, we’ve talked quite a bit about the corny polymer.

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Researchers Find “Inert” Components In Batteries Lead To Cell Self-Discharge

February 6, 2023 by Donald Papp 11 Comments

When it comes to portable power, lithium-ion batteries are where it’s at. Unsurprisingly, there’s a lot of work being done to better understand how to maximize battery life and usable capacity.

Red electrolytic solution, which should normally be clear.

While engaged in such work, [Dr. Michael Metzger] and his colleagues at Dalhousie University opened up a number of lithium-ion cells that had been subjected to a variety of temperatures and found something surprising: the electrolytic solution within was a bright red when it was expected to be clear.

It turns out that PET — commonly used as an inert polymer in cell assembly — releases a molecule that leads to self-discharge of the cells when it breaks down, and this molecule was responsible for the color change. The molecule is called a redox shuttle, because it travels back and forth between the cathode and the anode. This is how an electrochemical cell works, but the problem is this happens all the time, even when the battery isn’t connected to anything, causing self-discharge.

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Old Ham Wisdom Leads To Better Aluminum Painting

January 24, 2023 by Al Williams 50 Comments

When [bdk6] tried painting aluminum for electronic projects, he found it didn’t tend to stay painted. It would easily scratch off or, eventually, even flake off. The problem is the paint doesn’t want to adhere to the aluminum oxide coating around the metal. Research ensued, and he found an article in an old ham radio magazine about a technique that he could adapt to get good results painting aluminum.

Actually, paint apparently adheres poorly, even to non-oxidized aluminum. So the plan is to clean and remove as much aluminum oxide as possible. Then the process will convert the aluminum surface to something the paint sticks to better. Of course, you also need the right kind of paint.

The key ingredients are phosphoric acid and zinc phosphate. Phosphoric acid is found in soft drinks, but is also sold as a concrete and metal prep for painting. The zinc phosphate is part of a special paint known as a self-etching primer.

Cleaning takes soap, elbow grease, and sandpaper. The next step is a long soak in the phosphoric acid. Then you apply a few coats of self-etching primer and sand. Once it is all set, you can paint with your normal paint. That’s usually epoxy-based paint for [bdk6].

Of course, you can also dye aluminum while anodizing it. Soldering aluminum also has its challenges.

Making The One Ring By Electroplating Gold On A 3D Print

January 12, 2023 by Lewin Day 11 Comments

Electroplating is a great way to add strength or shine to a 3D print. However, we don’t see too many people trying it with gold. [HEN3DRIK] isn’t afraid to experiment, though, and pulled off some amazing, high-quality jewelry-grade plating!

The design for the project was the so-called Ring of Power from Lord of the Rings. The print was created on a resin printer at a high quality level, washed thoroughly to remove any remaining resin, and then cured. The print was then post-processed with sandpaper to make it as smooth as possible. Conductive paint was then applied, ready to take on the plating layers. [HEN3DRIK] first started by plating copper to build up a tough base layer, then nickel to prevent mixing between the copper and gold. The gold is then finally plated on top. Plating the copper is done with the ring constantly rotating to get as even a coat as possible. In contrast, the gold plating is done with a brush to avoid wasting the highly-expensive plating solution.

The final result is a gleaming gold ring that probably feels strangely light in the hand. The technique is time consuming, thanks to the need to plate multiple layers, but the results are to die for. We’ve seen [HEN3DRIK]’s fine work before, too. Video after the break.

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Wipe On, Wipe Off: Make Your Own Rain Repellent

January 9, 2023 by Kristina Panos 55 Comments

Once upon a time, we drove an old six-volt VW Beetle. One sad day, the wiper motor went out, and as this happened before the Internet heyday, there were no readily-available parts around that we were aware of. After briefly considering rubbing a potato on the windshield as prescribed by the old wives’ tale, we were quite grateful for the invention of Rain-X — a water-repelling chemical treatment for car windshields.

Boy would we have loved to know how to make it ourselves from readily-available chemicals. As you’ll see in the video below, it doesn’t take much more than dimethicone, sulfuric acid, and a cocktail of alcohols. [Terry] starts with dimethicone, which he activates with a healthy dose of concentrated sulfuric acid, done under the safety of an exhaust hood. After about 20 minutes on the stir mix-a-lot plate, [Terry] added ethanol and isopropyl alcohols. Finally, it was off to the garage with the mixture in a spray bottle.

After meticulously cleaning the windshield, [Terry] applied the solution in small areas and rubbed it in with a towel to create a thin bond between it and the glass. This creates a perfectly normal haze, which can be removed after a bit with a clean towel.

If you just love listening to your windshield wipers, at least make them move to a beat.

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Raspberry Pi biosensor with screen-printed electrodes

Raspberry Pi And PpLOGGER Make A Low-Cost Chemiluminescence Detector

December 31, 2022 by Orlando Hoilett 11 Comments

[Laena] and her colleagues at the La Trobe Institute for Molecular Science in Melbourne, Australia used a Raspberry Pi to make a low-cost electrochemiluminescence (ECL) detector to measure inflammation markers, which could be used to detect cardiovascular disease or sepsis early enough to give doctors a better chance at saving a patient’s life.

ECL reactions emit light as a result of an electrically-activated chemical reaction, making them very useful for detecting biochemical markers in blood, saliva, or other biological samples. ECL setups are fundamentally fairly straightforward. The device includes a voltage reference generator to initiate the chemical reaction and a photomultiplier tube (PMT) to measure the emitted light. The PMT outputs a current which is then converted to a voltage using a transimpedance amplifier (TIA). That signal is then sampled by the DAQCplate expansion board and the live output can be viewed in ppLOGGER in real-time.

Using the RPi allowed the team to do some necessary, but pretty simple signal processing, like converting the TIA voltage back to a photocurrent and integrating the current to obtain the ECL intensities. They mention the added signal processing potential of the RPi was a huge advantage of their setup over similar devices, however, simple integration can be done pretty easily on most any microcontroller. Naturally, they compared their device to a standard ECL setup and found that the results were fairly comparable between the two instruments. Their custom device showed a slightly lower limit of detection than the standard setup.

Their device costs roughly $1756 USD in non-bulk quantities with the PMT being the majority of the cost ($1500). Even at almost $2000, their device provides more than $8000 in savings compared to ECL instruments on the market. Though cost is much more than just the bill of materials, we like seeing the community making efforts to democratize science, and [Laena] and her colleagues did just that. I wonder if they can help us figure out the venus fly trap while they’re at it?