The Fab Lab Next Door: DIY Semiconductors

You think you’ve got it going on because you can wire up some eBay modules and make some LEDs blink, or because you designed your own PCB, or maybe even because you’re an RF wizard. Then you see that someone is fabricating semiconductors at home, and you realize there’s always another mountain to climb.

We were mesmerized when we first saw [Sam Zeloof]’s awesome garage-turned-semiconductor fab lab. He says he’s only been acquiring equipment since October of 2016, but in that short time he’s built quite an impressive array of gear; a spin-coating centrifuge, furnaces, tons of lab supplies and toxic chemicals, a turbomolecular vacuum pump, and a vacuum chamber that looks like something from a CERN lab.

[Sam]’s goal is to get set up for thin-film deposition so he can make integrated circuits, but with what he has on hand he’s managed to build a few diodes, some photovoltaic cells, and a couple of MOSFETs. He’s not growing silicon crystals and making his own wafers — yet — but relies on eBay to supply his wafers. The video below is a longish intro to [Sam]’s methods, and his YouTube channel has a video tour of his fab and a few videos on making specific devices.

[Sam] credits [Jeri Ellsworth]’s DIY semiconductor efforts, which we’ve covered before, as inspiration for his fab, and we’re going to be watching to see where he takes it from here. For now, though, we’d better boost the aspiration level of our future projects.

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Building Transistors With Transistors

Since the 1940s when the first transistor was created, transistors have evolved from ornery blocks of germanium wrangled into basic amplifiers into thousands and thousands of different devices made of all kinds of material that make any number of electrical applications possible, cheap, and reliable. MOSFETs can come in at least four types: P- or N-channel, and enhancement or depletion mode. They also bear different power ratings. And some varieties are more loved than others; for instance, depletion-mode, N-channel power MOSFETs are comparatively scarce. [DeepSOIC] was trying to find one before he decided to make his own by hacking a more readily available enhancement-mode transistor.

For those not intimately familiar with semiconductor physics, the difference between these two modes is essentially the difference between a relay that is normally closed and one that’s normally open. Enhancement-mode transistors are “normally off” and are easy to obtain and (for most of us) useful for almost all applications. On the other hand, if you need a “normally on” transistor, you will need to source a depletion mode transistor. [DeepSOIC] was able to create a depletion mode transistor by “torturing” the transistor to effectively retrain the semiconductor junctions in the device.

If you’re interested in semiconductors and how transistors work on an atomic level, [DeepSOIC]’s project will keep you on the edge of your seat. On the other hand, if you’re new to the field and looking to get a more basic understanding, look no further than these DIY diodes.

Honey, They Shrunk The Transistor

Silicon transistors keep shrinking (current state of the art is about 20 nanometers). However–in theory–once the gate goes to 5 nanometers, the electrons tunnel through the channel making it impossible to turn the transistor off. Berkeley researchers have used a different material to produce a transistor with a 1-nanometer gate. For point of reference, a human hair is about 50,000 nanometers thick.

The secret is to switch away from silicon in favor of another semiconductor. The team’s choice? Molybdenum disulfide. Never heard of it? You can buy it at any auto parts store since it is a common lubricant. Electrons have more effective mass as they travel through molybdenum disulfide than silicon. For a larger transistor, that’s not a good thing, but for a small transistor, it prevents the electron tunneling problem.

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History Of The Diode

The history of the diode is a fun one as it’s rife with accidental discoveries, sometimes having to wait decades for a use for what was found. Two examples of that are our first two topics: thermionic emission and semiconductor diodes. So let’s dive in.

Vacuum Tubes/Thermionic Diodes

Our first accidental discovery was of thermionic emission, which many years later lead to the vacuum tube. Thermionic emission is basically heating a metal, or a coated metal, causing the emission of electrons from its surface.

Electroscope
Electroscope

In 1873 Frederick Guthrie had charged his electroscope positively and then brought a piece of white-hot metal near the electroscope’s terminal. The white-hot metal emitted electrons to the terminal, which of course neutralized the electroscope’s positive charge, causing the leafs to come together. A negatively charged electroscope can’t be discharged this way though, since the hot metal emits electrons only, i.e. negative charge. Thus the direction of electron flow was one-way and the earliest diode was born.

Thomas Edison independently discovered this effect in 1880 when trying to work out why the carbon-filaments in his light bulbs were often burning out at their positive-connected ends. In exploring the problem, he created a special evacuated bulb wherein he had a piece of metal connected to the positive end of the circuit and held near the filament. He found that an invisible current flowed from the filament to the metal. For this reason, thermionic emission is sometimes referred to as the Edison effect.

Thermionic diode
Thermionic diode. By Svjo [CC BY-SA 3.0], via Wikimedia Commons
But it took until 1904 for the first practical use of the effect to appear. John Ambrose Fleming had actually consulted for the Edison Electric Light Company from 1881-1891 but was now working for the Marconi Wireless Telegraph Company. In 1901 the company demonstrated the first radio transmission across the Atlantic, the letter “S” in the form or three dots in Morse code. But there was so much difficulty in telling the received signal apart from the background noise, that the result was disputed (and still is). This made Fleming realize that a more sensitive detector than the coherer they’d been using was needed. And so in 1904 he tried an Edison effect bulb. It worked well, rectifying the high frequency oscillations and passing the signals on to a galvanometer. He filed for a patent and the Fleming valve, the two element vacuum tube or thermionic diode, came into being, heralding decades of technological developments in many subsequent types of vacuum tubes.

Vacuum tubes began to be replaced in power supplies in the 1940s by selenium diodes and in the 1960s by semiconductor diodes but are still used today in high power applications. There’s also been a resurgence in their use by audiophiles and recording studios. But that’s only the start of our history.

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Books You Should Read: Instruments Of Amplification

Psst… Wanna make a canning jar diode? A tennis ball triode? How about a semiconductor transistor? Or do you just enjoy sitting back and following along an interesting narrative of something being made, while picking up a wealth of background, tips and sparking all sorts of ideas? In my case I wanted to make a cuprous oxide semiconductor diode and that lead me to H.P. Friedrichs’ wonderful book Instruments of Amplification. It includes such a huge collection of amplifier knowledge and is a delight to read thanks to a narrative style and frequent hands-on experiments.

Friedrichs first authored another very popular book, The Voice of the Crystal, about making crystal radios, and wanted to write a second one. For those not familiar with crystal radios, they’re fun to make radios that are powered solely by the incoming radio waves; there are no batteries. But that also means the volume is low.

Readers of that book suggested a good follow-up would be one about amplifier circuits, to amplify the crystal radio’s volume. However, there were already an abundance of such books. Friedrichs realized the best follow-up would be one on how to make the amplifying components from scratch, the “instruments of amplification”.  It would be unique and in the made-from-scratch spirit of crystal radios. The book, Instruments of Amplification was born.

The Experiments

Microphonic relays
Microphonic relays, via H.P. Friedrichs Homepage

The book includes just the right amount of a history, giving background on what an amplifier is and how they first came in the electrical world. Telegraph operators wanted to send signals over greater and greater distances and the solution was to use the mix of electronics and mechanics found in the telegraph relay. This is the springboard for his first project and narrative: the microphonic relay.

The microphonic relay example shown on the right places a speaker facing a microphone; the speaker is the input with the microphone amplifying the output. He uses a carbon microphone salvaged from an old telephone headset, housing everything in an enclosure of copper pipe caps, steel bar stock, nuts and bolts mounted on an elegant looking wood base. All the projects are made with simple parts, with care, and they end up looking great.

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Infrared Detector Selects Over A Wide Range

You can classify infrared light into three broad ranges: short wave, medium wave, and long wave. Traditionally, sensors concentrate on one or two bands, and each band has its own purpose. Short wave IR, for example, produces images similar to visible light images. Long wave is good for thermal imaging.

Researchers have announced a new detector that, by adjusting a bias, can detect all three bands using a simple approach that stacks different absorption layers over a semiconductor substrate. The device only requires two terminals and is very efficient, although the efficiency varies based on the band.

We’ve covered infrared sensing before. We’ve even seen DSLRs hacked into IR sensors. This new research might be a bit much to duplicate in your garage. After all, it requires tellurium doped gallium antimonide substrates and sophisticated processing equipment. However, this research will probably lead to practical devices that will find their way into projects before too long.

Home Made Diodes From Copper Oxide

We’re all familiar with semiconductor devices, and we should remember the explanation from high-school physics classes that they contain junctions between two types of semiconductor material. “N” type which in the for-schoolchildren explanation has a surplus of electrons, and “P” type which has “Holes”, or a deficit of electrons.

Unless our careers have taken us deep into the science of the semiconductor industry though that’s probably as close as we’ve come to the semiconductors themselves. To us a diode or a transistor is a neatly packaged device with handy wires. We’ve never really seen what’s inside, let alone made any real semiconductor devices ourselves.

[Hales] though has other ideas. With the dream of creating a paintable semiconductor layer for ad-hoc creation of simple diodes, he’s been experimenting with oxidising copper to make a surface of cupric oxide onto which he can make a contact for a simple diode.

What makes his experiments particularly impressive though is not merely that he’s created a working diode, albeit one with a low reverse breakdown voltage. He’s done it not in a gleaming laboratory with a full stock of chemicals and equipment, but on his bench with a candle, and drops of water. He takes us through the whole process, with full details of his semiconductor manufacture as well as his diode test rig to trace the device’s I/V curve. Well worth a read, even if you never intend to make a diode yourself.

We’ve featured a cuprous oxide diode once before here at Hackaday, albeit a rather fancier device. If this article has piqued your interests about diodes, may we direct you to this informative video on the subject?

The diode looks black, leading me to believe it’s cupric oxide and not cuprous oxide. Feel free to argue that point in the comments anyway – Ed.