As Light As Plastic; As Strong As Steel

February 7, 2022 by 38 Comments

Chemical engineers at MIT have pulled off something that was once thought impossible. By polymerizing material in two different directions at once, they have created a polymer that is very strong. You can read a pre-print version of the paper over on Arxiv.

Polymers owe many of their useful properties to the fact that they make long chains. Molecules known as monomers join together in strings held together by covalent bonds. Polymer chains may be cross-linked which changes its properties, but it has long been thought that material that had chains going through the X and Y axis would have desirable properties, but making these reliably is a challenge.

Part of the problem is that it is hard to line up molecules, even large monomers. If one monomer in the chain rotates a bit, it will create a defect in the 2D structure and that defect will grow rapidly as you add more monomers. The new technique is relatively easy to do and is irreversible which is good because reversible chains tend to have undesirable characteristics like low chemical stability. Synthesis does require a few chemicals like melamine, calcium chloride, pyridine, and trimesic acid. Along with N-Methyl-2-pyrrolidone, the mixture eventually forms a gel. The team took pieces of gel and soaked it in ethanol. With some filtering, ultrasonics, centrifuging, and washing with water and acetone, the material was ready for vacuum drying and was made into a powder.

The powder is dissolved in acid and placed on a spinning silicon wafer to form a polymerized nanofilm. Other 2D films have been produced, of course, such as graphene, but polymer films may have a number of applications. In particular, in contrast to conventional polymers, sheets of this material are impermeable to gas and liquid, which could make it very useful as a coating.

According to the MIT press release, the film’s elastic modulus is about four and six times greater than that of bulletproof glass. The amount of force required to break the material is about twice that of steel. It doesn’t sound like this material will be oozing out of our 3D printers anytime soon. But maybe one day you’ll be able to get 2D super-strong resin.

For all their faults, conventional polymers changed the world as we know it. Some polymers occur naturally, and some use natural ingredients, too.

Plastics: Photopolymers For 3D Printing And Beyond

December 21, 2021 by 9 Comments

Chances are good that if you’ve done any 3D printing, it was of the standard fused deposition modeling variety. FDM is pretty simple stuff — get a bit of plastic filament hot enough, squeeze the molten goo out of a fine nozzle, control the position of the nozzle more or less precisely in three dimensions, and repeat for hours on end until your print is done. To the outsider it looks like magic, but to us it’s just another Saturday afternoon.

Resin printing is another thing altogether, and a lot closer to magic for most of us. The current crop of stereolithography printers just have a high-resolution LCD display between a UV light source and a build tank with a transparent bottom. Prints are built up layer by layer by flashing UV light patterns into the tank as a build plate slowly lifts it up from the resin, like some creature emerging from the primordial goo.

Of course it’s all just science, but if there is any magic in SLA printing, surely it’s in the resins used for it. Their nondescript brown plastic bottles and information-poor labels give little clue as to their ingredients, although their hydrocarbon reek and viscous, sticky texture are pretty good clues. Let’s take a look inside the resin bottle and find out what it is that makes the magic of SLA happen.

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Less Stinky Resin Two Ways

May 13, 2021 by 12 Comments

After watching [Uncle Jessy’s] video about soy-based 3D printing resin from Elegoo and their miniature air purifiers, we couldn’t decide if the resin doesn’t smell as bad as some other resins or if the air purifier works wonders. Maybe it is a bit of both.

We’ve used Eryone super low odor resin and it has less smell than, say, paint. It sounds like the Elegoo is similar. However, we are always suspicious of claims that any resin is really made with natural ingredients. As [Brent], who apparently has a PhD in chemistry, pointed out, AnyCubic Eco resin makes similar claims but is likely only partially made from soy. Sure, a little less than half is soy-based, but then there’s the other half. Still, we suppose it is better than nothing. That video (also below) is worth watching if you ever wondered why resin solidifies under UV light or what a monomer is.

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Spider Silk, Spider Silk, Made Using A Strain Of Yeast

November 6, 2020 by 25 Comments

Companies spend thousands developing a project for the market, hoping their investment will return big. Investing like this happens every day and won’t shock anyone. What may surprise you is someone who spends more than a decade and thousands of their own dollars to make an open-source version of a highly-marketable product. In this case, we’re talking about genetically modified yeast that produces spider silk. If that sounds like a lead-in to some Spiderman jokes and sci-fi references, you are correct on both accounts. [Justin Atkin] had some geneticist work under his belt when he started, so he planned to follow familiar procedures like extracting black widow DNA, isolating and copying the silk genes, and pasting them into a yeast strain. Easy peasy, right? Naturally, good science doesn’t happen overnight.

There are a few contenders for the strongest spider silk among which the golden silk orb-weaver gets the most attention, but the black widow’s webbing is nearly as strong, and [Justin] is happy to wear black widow inspired bling, whereas the golden orb-weaver looks like it crawled out of Starship Troopers. His first attempt to extract DNA starts with a vial of preserved nightmare fuel spider specimens because that is a thing you can just go online and buy. Sadly, they were candied in alcohol, and that obliterates DNA, so he moved to dried specimens from breeders, which also failed to produce results, and those were just the landmark hangups.

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Need A Small Keyboard? Build Your Own!

April 23, 2019 by 72 Comments

If you want keyboards, we can get you keyboards. If you want a small keyboard, you might be out of luck. Unless you’re hacking Blackberry keyboards or futzing around with tiny tact switches, there’s no good solution to small, thin, customization keyboards. There’s one option though: silicone keyboards. No one’s done it yet, so I figured I might as well.

Unfortunately, there is no readily available information on the design, construction, or manufacture of custom silicone keypads. There is a little documentation out there, but every factory that does this seems to have copy and pasted the information from each other. Asking a company in China about how to do it is a game of Chinese Whispers. Despite this, I managed to build a custom silicone keypad, and now I’m sharing this information on how to do it with you.

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Plastics: PETG

January 29, 2019 by 30 Comments

You’d be hard-pressed to walk down nearly any aisle of a modern food store without coming across something made of plastic. From jars of peanut butter to bottles of soda, along with the trays that hold cookies firmly in place to prevent breakage or let a meal go directly from freezer to microwave, food is often in very close contact with a plastic that is specifically engineered for the job: polyethylene terephthalate, or PET.

For makers of non-food objects, PET and more importantly its derivative, PETG, also happen to have excellent properties that make them the superior choice for 3D-printing filament for some applications. Here’s a look at the chemistry of polyester resins, and how just one slight change can turn a synthetic fiber into a rather useful 3D-printing filament.

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Open Source Fader Bank Modulates Our Hearts

January 27, 2019 by 9 Comments

Here at Hackaday, we love knobs and buttons. So what could be better than one button? How about 16! No deep philosophy about the true nature of Making here; [infovore], [tehn], and [shellfritsch] put together a very slick, very adaptable bank of 16 analog faders for controlling music synthesis. If you don’t recognize those names it might help to mention that [tehn] is one of the folks behind monome, a company built on their iconic grid controller. Monome now produces a variety of lovingly crafted music creation tools.

Over the years we’ve written about some of the many clones and DIY versions of the monome grid controller, so it’s exciting to see an open source hardware release by the creators themselves!

The unambiguously named 16n follows in the footsteps of the monome grid in the sense that it’s not really for something specific. The grid is a musical instrument insofar as it can be connected to a computer (or a modular synth, etc) and used as a control input for another tool that creates sound. Likewise, the 16n is designed to be easily integrated into a music creation workflow. It can speak a variety of interfaces, like purely analog control voltage (it has one jack per fader), or i2c to connect to certain other monome devices like Ansible and Teletype. Under the hood, the 16n is actually a Teensy, so it’s fluent in MIDI over USB and nearly anything else you can imagine.

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