Plastic On The Mind: Assessing The Risks From Micro- And Nanoplastics

February 12, 2025 by 49 Comments

Perhaps one of the clearest indications of the Anthropocene may be the presence of plastic. Starting with the commercialization of Bakelite in 1907 by Leo Baekeland, plastics have taken the world by storm. Courtesy of being easy to mold into any imaginable shape along with a wide range of properties that depend on the exact polymer used, it’s hard to imagine modern-day society without plastics.

Yet as the saying goes, there never is a free lunch. In the case of plastics it would appear that the exact same properties that make them so desirable also risk them becoming a hazard to not just our environment, but also to ourselves. With plastics degrading mostly into ever smaller pieces once released into the environment, they eventually become small enough to hitch a ride from our food into our bloodstream and from there into our organs, including our brain as evidenced by a recent study.

Multiple studies have indicated that this bioaccumulation of plastics might be harmful, raising the question about how to mitigate and prevent both the ingestion of microplastics as well as producing them in the first place.

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Deteriorating section of the UCIL plant near Bhopal, India. (Credit: Luca Frediani, Wikimedia)

Cleaning Up Bhopal: The World’s Worst Industrial Disaster

January 7, 2025 by 44 Comments

Forty years ago, on the night of Sunday 2 December of 1984, people in the city of Bhopal and surrounding communities were settling in for what seemed like yet another regular night. The worst thing in their near future appeared to be having to go back to school and work the next day. Tragically, many of them would never wake up again, and for many thousands more their lives would forever be changed in the worst ways possible.

During that night, clouds of highly toxic methyl isocyanate (MIC) gas rolled through the streets and into houses, venting from the Bhopal pesticide plant until the leak petered out by 2 AM. Those who still could wake up did so coughing, with tearing eyes and stumbled into the streets to escape the gas cloud without a clear idea of where to go. By sunrise thousands were dead and many more were left severely ill.

Yet the worst was still to come, as the number of casualties kept rising, legal battles and the dodging of responsibility intensified, and the chemical contamination kept seeping into the ground at the crippled plant. Recently there finally seems to be progress in this clean-up with the removal of 337 tons of toxic waste for final disposal, but after four decades of misgivings and neglect, how close is Bhopal really to finally closing the chapter on this horrific disaster?

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On Carbon Fiber Types And Their Carcinogenic Risks

August 7, 2024 by 13 Comments

Initially only seeing brief popular use as the filament in incandescent lighting, carbon fibers (CF) experienced a resurgence during the 20th century as part of composite materials that are lighter and stronger than materials like steel and aluminium, for use in aircraft, boats and countless more applications. This rising popularity has also meant that the wider population is now exposed to fragments of CF, both from using CF-based products as well as from mechanically processing CF materials during (hobby) projects.

It is this popularity that has also led to the addition of short CF sections to FDM 3D printing filaments, where they improve the mechanical properties of the printed parts. However, during subsequent mechanical actions such as sanding, grinding, and cutting, CF dust is created and some fraction of these particles are small enough to be respirable. Of these, another fraction will bypass the respiratory system’s dust clearing mechanisms, to end up deep inside the lungs. This raises the question of whether CF fragments can be carcinogenic, much like the once very popular and very infamous example of asbestos mineral fibers.

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Dual-Wavelength SLA 3D Printing: Fast Continuous Printing With ROMP And FRP Resins

April 22, 2024 by 10 Comments

As widespread as 3D printing with stereolithography (SLA) is in the consumer market, these additive manufacturing (AM) machines are limited to a single UV light source and the polymerization of free-radical polymerization (FRP) resins. The effect is that the object is printed in layers, with each layer adhering not only to the previous layer, but also the transparent (FEP or similar) film at the bottom of the resin vat. The resulting peeling of the layer from the film both necessitates a pause in the printing process, but also puts significant stress on the part being printed. Over the years a few solutions have been developed, with Sandia National Laboratories’ SWOMP technology (PR version) being among the latest.

Unlike the more common FRP-based SLA resins, SWOMP (Selective Dual-Wavelength Olefin Metathesis 3D-Printing) uses ring-opening metathesis polymerization (ROMP), which itself has been commercialized since the 1970s, but was not previously used with photopolymerization in this fashion. For the monomer dicyclopentadiene (DCPD) was chosen, with HeatMet (HM) as the photo-active olefin metathesis catalyst. This enables the UV-sensitivity, with an added photobase generator (PBG) which can be used to selectively deactivate polymerization.

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Common Enzyme Breaks Down PLA Fast

February 4, 2024 by 50 Comments

The global issue of plastic waste has prompted scientists to seek innovative solutions for recycling. Single-use plastics, notorious for their environmental impact, require new methods for efficient and sustainable management. For some common plastics, though, salvation could be at hand, with researchers identifying a common enzyme that can be used to break them down fast.

Researchers at King’s College London have discovered an enzyme used in laundry detergents that can break down PLA plastics within 24 hours, using a little heat as an aid. Normally, this is achieved via composting methods that take weeks or months. This method transforms the plastics back into their original chemical components, offering a rapid and eco-friendly recycling process. The monomers can then be reused for manufacturing new plastic items.

One wonders if this could also be used in another way – perhaps in a multimaterial printer, allowing PLA to be used for supports and then broken down. It’s probably not that necessary, given other degradable materials exist, but it’s something to think about.

This project is a significant leap forward in recycling technology, showcasing the potential for enzymes to revolutionize how we handle plastic waste. It could also be a great way to recycle all those errant deformed Pikachus that keep ending up in your hackerspace’s 3D-printing waste basket. In any case, plastic waste is a problem the world needs to solve, and quickly, because it’s not going anywhere any time soon. Video after the break.

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Tech In Plain Sight: Super Glue

December 11, 2023 by 68 Comments

Many inventions happen not by design but through failure. They don’t happen through the failure directly, but because someone was paying attention and remembered the how and why of the failure, and learns from this. One of these inventions is Super Glue, the adhesive that every tinkerer and engineer has to hand to stick pretty much anything to anything, quickly. Although it was a complete failure for the original uses it was developed for, a chemist with good memory and an eye for a helpful product created it in a process he described as “one day of synchronicity and ten years of hard work.”

Super Glue was initially invented in 1942, when the chemist Harry Coover was working on a team trying to develop a clear plastic gun sight that would be cheaper than the metal ones already in use. The team cast a wide net, trying a range of new materials. Coover was testing a class of chemicals called cyanoacrylates. They had some promise, but they had one problem: they stuck to pretty much everything. Every time that Coover tried to use the material to cast a gun sight, it stuck to the container and was really hard to remove. 

When the samples he tried came into contact with water, even water vapor in the air, they immediately formed an incredibly resilient bond with most materials. That made them lousy manufacturing materials, so he put the cyanoacrylates aside when the contract was canceled. His employer B. F. Goodrich, patented the process of making cyanoacrylates in 1947, but didn’t note any particular uses for the materials: they were simply a curiosity. 

It wasn’t until 1951 when Coover, now at Eastman Kodak, remembered the sticky properties of cyanoacrylates. He and his colleague Fred Joyner were working on making heat-resistant canopies for the new generation of jet fighters, and they considered using these sticky chemicals as adhesives in the manufacturing process. According to Coover, he told Joyner about the materials and asked him to measure the refractive index to see if they might be suitable for use. He warned him to be careful, as the material would probably stick in the refractometer and damage it. Joyner tested the material and found it wasn’t suitable for a canopy but then went around the lab using it to stick things together. The two realized it could make an excellent adhesive for home and engineering use. Continue reading “Tech In Plain Sight: Super Glue” →

Two-Dimensional Polymer Is A New Ultra-Strong Material

March 23, 2022 by 26 Comments

Plastics, by and large, are well-understood materials. Not as strong as most metals, but often much lighter, these man-made polymers have found innumerable applications that have revolutionized the way we live. The properties of plastics have been improved in many ways over the years, with composite materials like fiberglass and carbon fiber proving to have strength and lightness far beyond the simple properties of basic polymers alone.

However, a group of engineers at MIT have been working on a revolutionary type of polymer that promises greater strength then ever before while remaining remarkably light weight. It’s all down to the material’s two-dimensional molecular structure, something once thought to be prohibitively difficult in the world of polymer science.

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