chemistry hacks

644 Articles

A homemade seven-segment OLED display

Making OLED Displays In The Home Lab

September 4, 2021 by 13 Comments

Just a general observation: when your project’s BOM includes ytterbium metal, chances are pretty good that it’s something interesting. We’d say that making your own OLED displays at home definitely falls into that category.

Of course, the making of organic light-emitting diodes requires more than just a rare-earth metal, not least of which is the experience in the field that [Jeroen Vleggaar] brings to this project. Having worked on OLEDs at Philips for years, [Jeroen] is well-positioned to tackle the complex process, involving things like physical vapor deposition and the organic chemistry of coordinated quinolones. And that’s not to mention the quantum physics of it all, which is nicely summarized in the first ten minutes or so of the video below. From there it’s all about making a couple of OLED displays using photolithography and the aforementioned PVD to build up a sandwich of Alq3, an electroluminescent organic compound, on a substrate of ITO (indium tin oxide) glass. We especially appreciate the use of a resin 3D printer to create the photoresist masks, as well as the details on the PVD process.

The displays themselves look fantastic — at least for a while. The organic segments begin to oxidize rapidly from pinholes in the material; a cleanroom would fix that, but this was just a demonstration, after all. And as a bonus, the blue-green glow of [Jeroen]’s displays reminds us strongly of the replica Apollo DSKY display that [Ben Krasnow] built a while back. Continue reading “Making OLED Displays In The Home Lab” →

Can Metal Plated 3D Prints Survive 400,000 Volts?

August 25, 2021 by 12 Comments

It appears they can. [Ian Charnas] wanted his very own Thor Hammer. He wasn’t happy to settle on the usual cosplay methods of spray painting over foam and similar flimsy materials. He presents a method for nickel plating onto a 3D printed model, using conductive nickel paint to prepare the plastic surface for plating. In order to reduce the use of hazardous chemistry, he simplifies things to use materials more likely to be found in the kitchen.

As the video after the break shows, [Ian] went through quite a lot of experimentation in order to get to a process that would be acceptable to him. As he says, “after all, if something is worth doing, it’s worth over-doing” which is definitely a good ethos to follow. Its fairly hard to plate metals and get a good finish, and 3D printed objects are by their nature, not terribly smooth. But, the effort was well rewarded, and the results look pretty good to us.

But what about the 400 kV I hear you ask? Well, it wouldn’t be Thor’s hammer, without an ungodly amount of lightning flying around, and since [Ian] is part of a tesla coil orchestra group, which well, it just kinda fell into place. After donning protective chainmail to cover his skin, he walks straight into the firing line of a large pair of musical tesla coils and survives for another day. Kind of makes his earlier escapade with jet-powered roller skates look mundane by comparison.

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Google’s Periodic Table

August 13, 2021 by 44 Comments

One of the nice things about the Internet is that you don’t need huge reference books anymore. You really don’t need big wall charts, either. A case in point: what science classroom didn’t have a periodic table of the elements? Now you can just look up an interactive one from Google. They say it is 3D and we suppose that’s the animations of the Bohr model for each atom. You can debate if it is a good idea to show people Bohr models or not, but it is what most of us learned, after all.

While the website is probably aimed more at students, it is a handy way to look up element properties and it is visually attractive, too. You probably remember, the columns are no accident in a periodic table, so the actual format doesn’t vary from one instance of it to another. However, we liked the col coding and the information panel that appears when you click on an element.

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Murata To Deliver Solid State Batteries To Market In The Fall

August 3, 2021 by 43 Comments

Solid state batteries have long been promised to us as the solution to our energy storage needs. Theoretically capable of greater storage densities than existing lithium-ion and lithium-polymer cells, while being far safer to boot, they would offer a huge performance boost in all manner of applications.

For those of us dreaming of a 1,000-mile range electric car or a 14-kilowatt power drill, the simple fact remains that the technology just isn’t quite there yet. However, Murata Manufacturing Co., Ltd. has just announced that it plans to ship solid state batteries in the fall, which from a glance at the calendar is just weeks away.

It’s exciting news, and we’re sure you’re dying to know – just what are they planning to ship, and how capable are the batteries? Let’s dive in.

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Discount Microfluidics From A $9 Spree At The Dollar Store

July 11, 2021 by 1 Comment

Microfluidics — working with tiny volumes of fluids in tiny channels — isn’t something you’d think would be inexpensive. Unless you read [Alexander Bissells’] post on how he created microfluidic devices using stuff from the dollar store. The channels in these devices can be much smaller than a millimeter and the fluid volumes are sometimes measured in femtoliters. At those scales, fluids don’t work like we intuitively think they will.

The parts list included gel tape, baby droppers, and some assorted containers and tools. Total price at the dollar store $9. One of the key finds in the dollar store was some small spray bottles. They weren’t important themselves, but they contain small lengths of silicone tubing and that was useful. Plastic fresnel lenses along with the tubing and gel tape worked to make “chips.” The gel tape also gets cut to make the channels. An eyedropper with some modifications makes a reasonable syringe.

We aren’t sure what you can practically do with any of these, but the T-junction looked pretty interesting. If you want some ideas on how these devices work in biology, including COVID-19 testing, check out this article. And just last week [Krishna Sanka] hosted a Hack Chat on microfluidics in biohacking, you can find the transcript on the project page. If you need a pump, this one uses 3D printer firmware to control it.

Kathleen Lonsdale Saw Through The Structure Of Benzene

June 29, 2021 by 14 Comments

The unspoken promise of new technologies is that they will advance and enhance our picture of the world — that goes double for the ones that are specifically designed to let us look closer at the physical world than we’ve ever been able to before. One such advancement was the invention of X-ray crystallography that let scientists peer into the spatial arrangements of atoms within a molecule. Kathleen Lonsdale got in on the ground floor of X-ray crystallography soon after its discovery in the early 20th century, and used it to prove conclusively that the benzene molecule is a flat hexagon of six carbon atoms, ending a decades-long scientific dispute once and for all.

Benzene is an organic chemical compound in the form of a colorless, flammable liquid. It has many uses as an additive in gasoline, and it is used to make plastics and synthetic rubber. It’s also a good solvent. Although the formula for benzene had been known for a long time, the dimensions and atomic structure remained a mystery for more than sixty years.

Kathleen Lonsdale was a crystallography pioneer and developed several techniques to study crystal structures using X-rays. She was brilliant, but she was also humble, hard-working, and adaptable, particularly as she managed three young children and a budding chemistry career. At the outbreak of World War II, she spent a month in jail for reasons related to her staunch pacifism, and later worked toward prison reform, visiting women’s prisons habitually.

After the war, Kathleen traveled the world to support movements that promote peace and was often asked to speak on science, religion, and the role of women in science. She received many honors in her lifetime, and became a Dame of the British Empire in 1956. Before all of that, she honored organic chemistry with her contributions.

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Tiny Tesla Valves Etched In Glass

June 20, 2021 by 8 Comments

While it’s in vogue right now to name fancy new technology after Tesla, the actual inventor had plenty of his own creations that would come to bear his namesake, including Tesla coils, Tesla oscillators, Tesla turbines and even the infamous Tesla tower. One of the lesser known inventions of his is the Tesla valve, a check valve that allows flow in one direction without any moving parts, and [Huygens Optics] shows us a method of etching tiny versions of these valves into glass.

The build starts out with a fairly lengthy warning, which is standard practice when working with hydroflouric acid. The acid is needed to actually perform the etching, but it’s much more complicated than a typical etch due to the small size of the Tesla valves. He starts by mixing a buffered oxide etch, a mix of the hydroflouric acid, ammonia, and hydrochloric acid, which gives a much more even etching than any single acid alone. Similar to etching PCBs, a protective mask is needed to ensure that the etch only occurs where it’s needed. For that there are several options, each with their own benefits and downsides, but in the end [Huygens Optics] ends up with one of the smallest Tesla valves ever produced.

In fact, the valves are so small that they can only be seen with the aid of a microscope. While viewing them under the microscope he was able to test with a small drop of water to confirm that they do work as intended. And, while the valves that he is creating in this build are designed to work on liquids, [Huygens Optics] notes that the reason for making them this small was to make tiny optical components which they are known for.

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