Chemistry

126 Articles

Extracting Bismuth From Pepto Bismol

March 15, 2019 by 17 Comments

Bismuth is a very odd metal that you see in cosmetic pigments and as a replacement for lead, since it is less toxic. You will also see it — or an alloy — in fire sprinklers since it melts readily. However, the most common place you might encounter bismuth is Pepto Bismol — the ubiquitous pink liquid you use when your stomach is upset. [NileRed] tried extracting the bismuth from Pepto Bismol some time ago, but didn’t get good results. He decided that even though the process would not be cost-effective he wanted to try again, and you can see the crystals produced in the video below.

It turns out that you don’t need the pink liquid brand name. [Red Nile] started with ten boxes of generic chewable tablets — that’s 480 pills. A little bit of dilute hydrochloric acid eats the pills apart and generates a few reactions that he explains in the video.

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Common Chemicals Combine To Make Metallic Sodium

February 26, 2019 by 16 Comments

There’s no debating that metallic sodium is exciting stuff, but getting your hands on some can be problematic, what with the need to ship it in a mineral oil bath to keep it from exploding. So why not make your own? No problem, just pass a few thousand amps of current through an 800° pot of molten table salt. Easy as pie.

Thankfully, there’s now a more approachable method courtesy of this clever chemical hack that makes metallic sodium in quantity without using electrolysis. [NurdRage], aka [Dr. N. Butyl Lithium], has developed a process to extract metallic sodium from sodium hydroxide. In fact, everything [NurdRage] used to make the large slugs of sodium is easily and cheaply available – NaOH from drain cleaner, magnesium from fire starters, and mineral oil to keep things calm. The reaction requires an unusual catalyst – menthol – which is easily obtained online. He also gave the reaction a jump-start with a small amount of sodium metal, which can be produced by the lower-yielding but far more spectacular thermochemical dioxane method; lithium harvested from old batteries can be substituted in a pinch. The reaction will require a great deal of care to make sure nothing goes wrong, but in the end, sizable chunks of the soft, gray metal are produced at phenomenal yields of 90% and more. The video below walks you through the whole process.

It looks as though [NurdRage]’s method can be scaled up substantially or done in repeated small batches to create even more sodium. But what do you do when you make too much sodium metal and need to dispose of it? Not a problem.

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Make Your Own Phosphorescent Material

February 6, 2019 by 9 Comments

Phosphors are key to a whole swathe of display and lighting technologies. Cathode ray tubes, vacuum fluorsecent displays, and even some white LEDs all use phosphors to produce light. [Hydrogen Time] decided to make a green phosphorescent material, and has shared the process on Youtube, embedded below.

The aim is to produce zinc sulfide crystals doped with copper impurities. This creates a phosphor with a familiar green glow. [Hydrogen Time] starts by noting that it’s important to make sure all chemicals used are of good quality, as even slight impurities can spoil the final product.

Zinc sulfide is made into an aqueous solution, before a highly diluted copper sulfate solution is added, along with ammonium chloride to act as a flux. The mixture is stirred, before being heated in a tube flushed with argon. After firing, the phosphor is washed with water and allowed to cool.

The final product is demonstrated to glow a vibrant green under UV light, showing the process to be successful. [Hydrogen Time] intends to use the homebrew phosphor in future work to produce a display. It recalls us of [Jeri Ellsworth], producing her own EL wire at home. Video after the break.

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AI Patent Trolls Now On The Job For Drug Companies

January 30, 2019 by 39 Comments

Love it or loathe it, the pharmaceutical industry is really good at protecting its intellectual property. Drug companies pour billions into discovering new drugs and bringing them to market, and they do whatever it takes to make sure they have exclusive positions to profit from their innovations for as long a possible. Patent applications are meticulously crafted to keep the competition at bay for as long as possible, which is why it often takes ages for cheaper generic versions of blockbuster medications to hit the market, to the chagrin of patients, insurers, and policymakers alike.

Drug companies now appear poised to benefit from the artificial intelligence revolution to solidify their patent positions even further. New computational methods are being employed to not only plan the synthesis of new drugs, but to also find alternative pathways to the same end product that might present a patent loophole. AI just might change the face of drug development in the near future, and not necessarily for the better.

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Plastics: PETG

January 29, 2019 by 30 Comments

You’d be hard-pressed to walk down nearly any aisle of a modern food store without coming across something made of plastic. From jars of peanut butter to bottles of soda, along with the trays that hold cookies firmly in place to prevent breakage or let a meal go directly from freezer to microwave, food is often in very close contact with a plastic that is specifically engineered for the job: polyethylene terephthalate, or PET.

For makers of non-food objects, PET and more importantly its derivative, PETG, also happen to have excellent properties that make them the superior choice for 3D-printing filament for some applications. Here’s a look at the chemistry of polyester resins, and how just one slight change can turn a synthetic fiber into a rather useful 3D-printing filament.

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Electrolysis Tank Removes Rust

November 24, 2018 by 18 Comments

If you have something rusty, you can get a wire brush and a lot of elbow grease. Or you can let electricity do the work for you in an electrolysis tank. [Miller’s Planet] shows you how to build such a tank, but even better, he explains why it works in a very detailed way.

The tank uses a sodium carbonate electrolyte — just water and washing powder. In the reaction, free electrons from the electrolyte displace the oxygen from the rusted metal piece. A glass container, a steel rod, and a power supply make up the rest.

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Hacked Heating Instruments For The DIY Biology Lab

November 12, 2018 by 4 Comments

[Justin] from The Thought Emporium takes on a common molecular biology problem with these homebrew heating instruments for the DIY biology lab.

The action at the molecular biology bench boils down to a few simple tasks: suck stuff, spit stuff, cool stuff, and heat stuff. Pipettes take care of the sucking and spitting, while ice buckets and refrigerators do the cooling. The heating, however, can be problematic; vessels of various sizes need to be accommodated at different, carefully controlled temperatures. It’s not uncommon to see dozens of different incubators, heat blocks, heat plates, and even walk-in environmental chambers in the typical lab, all acquired and maintained at great cost. It’s enough to discourage any would-be biohacker from starting a lab.

[Justin] knew It doesn’t need to be that way, though. So he tackled two common devices:  the incubator and the heating block. The build used as many off-the-shelf components as possible, keeping costs down. The incubator is dead simple: an insulated plastic picnic cooler with a thermostatically controlled reptile heating pad. That proves to be more than serviceable up to 40°, at the high end of what most yeast and bacterial cultures require.

The heat block, used to heat small plastic reaction vessels called Eppendorf tubes, was a little more complicated to construct. Scrap heat sinks yielded aluminum stock, which despite going through a bit of a machinist’s nightmare on the drill press came out surprisingly nice. Heat for the block is provided by a commercial Peltier module and controller; it looks good up to 42°, a common temperature for heat-shocking yeast and tricking them into taking up foreign DNA.

We’re impressed with how cheaply [Justin] was able to throw together these instruments, and we’re looking forward to seeing how he utilizes them. He’s already biohacked himself, so seeing what happens to yeast and bacteria in his DIY lab should be interesting.

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