History Of The Diode

The history of the diode is a fun one as it’s rife with accidental discoveries, sometimes having to wait decades for a use for what was found. Two examples of that are our first two topics: thermionic emission and semiconductor diodes. So let’s dive in.

Vacuum Tubes/Thermionic Diodes

Our first accidental discovery was of thermionic emission, which many years later lead to the vacuum tube. Thermionic emission is basically heating a metal, or a coated metal, causing the emission of electrons from its surface.

Electroscope
Electroscope

In 1873 Frederick Guthrie had charged his electroscope positively and then brought a piece of white-hot metal near the electroscope’s terminal. The white-hot metal emitted electrons to the terminal, which of course neutralized the electroscope’s positive charge, causing the leafs to come together. A negatively charged electroscope can’t be discharged this way though, since the hot metal emits electrons only, i.e. negative charge. Thus the direction of electron flow was one-way and the earliest diode was born.

Thomas Edison independently discovered this effect in 1880 when trying to work out why the carbon-filaments in his light bulbs were often burning out at their positive-connected ends. In exploring the problem, he created a special evacuated bulb wherein he had a piece of metal connected to the positive end of the circuit and held near the filament. He found that an invisible current flowed from the filament to the metal. For this reason, thermionic emission is sometimes referred to as the Edison effect.

Thermionic diode
Thermionic diode. By Svjo [CC BY-SA 3.0], via Wikimedia Commons
But it took until 1904 for the first practical use of the effect to appear. John Ambrose Fleming had actually consulted for the Edison Electric Light Company from 1881-1891 but was now working for the Marconi Wireless Telegraph Company. In 1901 the company demonstrated the first radio transmission across the Atlantic, the letter “S” in the form or three dots in Morse code. But there was so much difficulty in telling the received signal apart from the background noise, that the result was disputed (and still is). This made Fleming realize that a more sensitive detector than the coherer they’d been using was needed. And so in 1904 he tried an Edison effect bulb. It worked well, rectifying the high frequency oscillations and passing the signals on to a galvanometer. He filed for a patent and the Fleming valve, the two element vacuum tube or thermionic diode, came into being, heralding decades of technological developments in many subsequent types of vacuum tubes.

Vacuum tubes began to be replaced in power supplies in the 1940s by selenium diodes and in the 1960s by semiconductor diodes but are still used today in high power applications. There’s also been a resurgence in their use by audiophiles and recording studios. But that’s only the start of our history.

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Books You Should Read: Instruments Of Amplification

Psst… Wanna make a canning jar diode? A tennis ball triode? How about a semiconductor transistor? Or do you just enjoy sitting back and following along an interesting narrative of something being made, while picking up a wealth of background, tips and sparking all sorts of ideas? In my case I wanted to make a cuprous oxide semiconductor diode and that lead me to H.P. Friedrichs’ wonderful book Instruments of Amplification. It includes such a huge collection of amplifier knowledge and is a delight to read thanks to a narrative style and frequent hands-on experiments.

Friedrichs first authored another very popular book, The Voice of the Crystal, about making crystal radios, and wanted to write a second one. For those not familiar with crystal radios, they’re fun to make radios that are powered solely by the incoming radio waves; there are no batteries. But that also means the volume is low.

Readers of that book suggested a good follow-up would be one about amplifier circuits, to amplify the crystal radio’s volume. However, there were already an abundance of such books. Friedrichs realized the best follow-up would be one on how to make the amplifying components from scratch, the “instruments of amplification”.  It would be unique and in the made-from-scratch spirit of crystal radios. The book, Instruments of Amplification was born.

The Experiments

Microphonic relays
Microphonic relays, via H.P. Friedrichs Homepage

The book includes just the right amount of a history, giving background on what an amplifier is and how they first came in the electrical world. Telegraph operators wanted to send signals over greater and greater distances and the solution was to use the mix of electronics and mechanics found in the telegraph relay. This is the springboard for his first project and narrative: the microphonic relay.

The microphonic relay example shown on the right places a speaker facing a microphone; the speaker is the input with the microphone amplifying the output. He uses a carbon microphone salvaged from an old telephone headset, housing everything in an enclosure of copper pipe caps, steel bar stock, nuts and bolts mounted on an elegant looking wood base. All the projects are made with simple parts, with care, and they end up looking great.

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Zero Parts-Count Temperature Sensor

Quick: What’s the forward voltage drop on a conducting diode? If you answered something like 0.6 to 0.7 V, you get a passing grade, but you’re going to have to read on. If you answered V_F = \frac{T-T_0}{k} where T0 and k are device-specific constants to be determined experimentally, you get a gold Jolly Wrencher.

vsd%2C+n-01[Jakub] earned his Wrencher, and then some. Because not only did he use the above equation to make a temperature sensor, he did so with a diode that you might have even forgotten that you have on hand — the one inside the silicon of a MOSFET — the intrinsic body diode.

[Jakub]’s main project is an Arduino-controlled electronic load that he calls the MightWatt, and a beefy power MOSFET is used as the variable resistance element. When it’s pulling 20 or 30 A, it gets hot. How hot exactly is hard to measure without a temperature sensor, and the best possible temperature sensor would be one that was built into the MOSFET’s die itself.

There’s a bunch of detail in his write-up about how he switches the load in and out to measure the forward drop, and how he calibrates the whole thing. It’s technical, but give it a read, it’s good stuff. This is a great trick to have up your sleeve.

And if you’re in the mood for more stupid diode tricks, we recommend using them as solar cells or just stringing a bunch of them together to make a thermal camera.

Hackaday Prize Entries: Inventing New Logic Families

One of the favorite pastimes of electronics hobbyists is clock making. Clocks are a simple enough concept with a well-defined goal, but it’s the implementation that matters. If you want to build a clock powered only by tubes and mains voltage, that’s a great skill tester. A relay-based timepiece is equally cool, and everyone should build a Nixie tube clock once in their lives.

For [Ted]’s Hackaday Prize entry, he’s building a clock. Usually, this would be little cause for celebration, but this is not like any clock you’ve ever seen. [Ted] is building this clock using only diodes, and he’s inventing new logic families to do it.

Using diodes as logic elements has been around since the first computers, but these computers had a few transistors thrown in. While it is possible to make AND and OR gates using only diodes, a universal logic gate – NANDs and NORs – are impossible. For the computers of the 1950s, that means tubes or transistors and DTL logic.

For the past few years, [Ted] has been working on a diode-only logic family, and it appears he’s solved the problem. The new logic family includes a NOR gate constructed using only diodes, resistors, and inductors. The key design feature of these gates is a single diode to switch an RF power supply on and off. It relies on an undocumented property of the diodes, but it does work.

Although [Ted] can create a NOR gate without transistors — a feat never before documented in the history of electronics — that doesn’t mean this is a useful alternative to transistor logic. The fan-out of the gates is terrible, the clock uses about 60 Watts, and the gates require an AC power supply. While it is theoretically possible to build a computer out of these gates, it’s doubtful if anyone has the patience to do so. It’s more of a curiosity, but it is a demonstration of one of the most mind-bending projects we’ve ever seen.

You can check out a video of the diode clock below.

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Home Brew Vacuum Tubes Are Easier Than You Think

It all began with a cheap Chinese rotary vane vacuum pump and a desire to learn the witchcraft of DIY vacuum tubes. It ended with a string of successes – a working vacuum chamber, light bulbs, glow tubes, diodes, and eventually this homebrew power triode and the audio amplifier built around it.

[Simplifier]’s workshop seems like a pretty cool place. It must have a bit of an early 20th-century vibe, like the shop that [John Fleming] used for his early work on vacuum tubes. Glass work, metal work, electronics – looks like [Simplifier] has a little bit of everything going on. True to his handle, once [Simplifier] had a cheap but effective vacuum rig he started with the easiest projects – incandescent and gas discharge lamps. Satisfied that he could make solid electrical and physical connections and evacuate the tubes, he moved on to diodes and eventually triodes. The quality of the tubes is pretty impressive – stray gasses are removed with a bake-out oven and induction-heated titanium getters. And the performance is pretty solid, as the video below reveals.

Very impressive overall, and it’s not just the fact that he’s building tubes from scratch – we’ve seen that before. What shines here is that specialized equipment is not needed to make working and reliable tubes – just a MAPP torch, simple hand tools, and a low-end vacuum rig. Anybody could – and probably should – give this a try.

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Home Made Diodes From Copper Oxide

We’re all familiar with semiconductor devices, and we should remember the explanation from high-school physics classes that they contain junctions between two types of semiconductor material. “N” type which in the for-schoolchildren explanation has a surplus of electrons, and “P” type which has “Holes”, or a deficit of electrons.

Unless our careers have taken us deep into the science of the semiconductor industry though that’s probably as close as we’ve come to the semiconductors themselves. To us a diode or a transistor is a neatly packaged device with handy wires. We’ve never really seen what’s inside, let alone made any real semiconductor devices ourselves.

[Hales] though has other ideas. With the dream of creating a paintable semiconductor layer for ad-hoc creation of simple diodes, he’s been experimenting with oxidising copper to make a surface of cupric oxide onto which he can make a contact for a simple diode.

What makes his experiments particularly impressive though is not merely that he’s created a working diode, albeit one with a low reverse breakdown voltage. He’s done it not in a gleaming laboratory with a full stock of chemicals and equipment, but on his bench with a candle, and drops of water. He takes us through the whole process, with full details of his semiconductor manufacture as well as his diode test rig to trace the device’s I/V curve. Well worth a read, even if you never intend to make a diode yourself.

We’ve featured a cuprous oxide diode once before here at Hackaday, albeit a rather fancier device. If this article has piqued your interests about diodes, may we direct you to this informative video on the subject?

The diode looks black, leading me to believe it’s cupric oxide and not cuprous oxide. Feel free to argue that point in the comments anyway – Ed.

Sciencing DVD-RW Laser Diodes

If you’ve played around with laser diodes that you’ve scavenged from old equipment, you know that it can be a hit-or-miss proposition. (And if you haven’t, what are you waiting for?) Besides the real risk of killing the diode on extraction by either overheating it or zapping it with static electricity, there’s always the question of how much current to put into the thing.

[DeepSOIC] decided to answer the latter question — with science! — for a DVD-burner laser that he’s got. His apparatus is both low-tech and absolutely brilliant, and it looks like he’s getting good data. So let’s have a peek.

Laser Detector on 3D Printer Scrap
Laser Detector on 3D Printer Scrap

First up is the detector, which is nothing more than a photodiode, 100k ohm load resistor, and a big capacitor for a power supply. We’d use a coin-cell battery, but given how low the discharge currents are, the cap makes a great rechargeable alternative. The output of the photo diode goes straight into the scope probe.

He then points the photodiode at the laser spot (on a keyboard?) and pulses the laser by charging up a capacitor and discharging it through the laser and a resistor to limit total current. The instantaneous current through the laser diode is also measured on the scope. Plotting both the current drawn and the measured brightness from the photodiode gives him an L/I curve — “lumens” versus current.

laser_curve

Look on the curve for where it stops being a straight line, slightly before the wiggles set in. That’s about the maximum continuous operating current. It’s good practice to de-rate that to 90% just to be on the safe side. Here it looks like the maximum current is 280 mA, so you probably shouldn’t run above 250 mA for a long time. If the diode’s body gets hot, heatsink it.

If you want to know everything about lasers in general, and diode lasers in particular, you can’t beat Sam’s Laser FAQ. We love [DeepSOIC]’s testing rig, though, and would love to see the schematic of his test driver. We’ve used “Sam’s Laser Diode Test Supply 1” for years, and we love it, but a pulsed laser tester would be a cool addition to the lab.

What to do with your junk DVD-ROM laser? Use the other leftover parts to make a CNC engraver? But we don’t need to tell you what to do with lasers. Just don’t look into the beam with your remaining good eye!