chemistry hacks

610 Articles

A Quick And Easy Recipe For Synthetic Rubies

March 6, 2020 by 37 Comments

With what it takes to make synthetic diamonds – the crushing pressures, the searing temperatures – you’d think similar conditions would be needed for any synthetic gemstone. Apparently not, though, as [NightHawkInLight] reveals his trivially easy method for making synthetic rubies.

Like their gemstone cousin the sapphire, rubies are just a variety of corundum, or aluminum oxide. Where sapphire gets its blue tint mainly from iron, rubies get their pink to blood-red hue from chromium. So [NightHawkInLight]’s recipe starts with aluminum oxide grit-blasting powder and chromium (III) oxide, a common green pigment and one of the safer compounds in a family that includes spectacularly toxic species like hexavalent chromium compounds. When mixed together, the two powders are heated in a graphite crucible using an arc welder with a carbon electrode. The crucible appears to be made from an EDM electrode; we’ve seen them used for air bearings before, but small crucibles are another great use for the stuff. There’s some finesse required to keep the nascent rubies from scattering all over the place, but in the end, [NightHawkInLight] was rewarded with a large, deep pink ruby.

This looks like a fun, quick little project to try sometime. We wonder if the method can be refined to create the guts of a ruby laser, or if perhaps it can be used to create sapphires instead.

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Printing Liquid Concrete

February 24, 2020 by 9 Comments

In the world of additive manufacturing, there’s always need materials being added to the list of potential filaments to use for printing objects. A method of rapid liquid printing of concrete designed by [Anatoly Berezkin] of Stoneflower 3D makes it possible to print a large variety of shapes from concrete while avoiding the negative effects of fast dehydration. The technique is based on an approach to printing polyurethanes, developed by MIT in 2017. This technique requires physically drawing a 3D object within a gel suspension using a chemical curing process. The gel allows gravity to not affect the printing process, as well as helping out with the curinng. Berezkin, an engineer and hobbyist working out of his garage, has published other work including print heads, ceramic printing, and micro printing sets.

One might be skeptical of whether the weight of the material could cause potential collapse during the printing process, or whether it is simply unrealistic to print objects given the time needed for the concrete to dry. Their demo shows the process being done in household items – bowls and tupperware – combining affordable items such as clay, concrete, and sand for the matrix and mortar. The viscous clay is strong enough to act as a good scaffold for keeping the concrete structure in place as it is being printed. As their video demonstrates, at least for simply objects, the process seems relatively fast.

RLPC doesn’t require toxic chemicals or proprietary components such as gels and suspensions. Its immersion of the final printed object in a humid environment is also superior to the standard process of liquid deposition for hardening concrete. Moreover, the process simply requires clay or retarded mortar for the matrix and mortar paste for turning into concrete. It’s advertised as eco-friendly, but just the simplicity of the materials needed for the matrix and mortar make this a promising technique.

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Put The Power Of PCR In Your Pocket With This Open-Source Thermal Cycler

January 26, 2020 by 23 Comments

When the first thermal cyclers for the polymerase chain reaction came out in the 1980s, they were as expensive as a market driven by grant money could make them. Things haven’t got much better over the years, largely shutting STEM classes and biohackers out of the PCR market. That may be about to change, though, if the €99.00 PocketPCR thermal cycler takes hold.

PCR amplifies DNA in a three-step process: denaturation, which melts double-stranded DNA into single strands; annealing, which lets small pieces of primer DNA bind to either side of the region of interest; and elongation, where the enzyme DNA polymerase zips along the single strands starting at the primer to replicate the DNA. The cycle repeats and copies of the original DNA accumulate exponentially. Like any thermal cycler, [Urs Gaudenz]’s PocketPCR automates those temperature shifts, using a combination of PCB-mounted heating elements and a cooling fan. The coils rapidly heat a reaction block up to the 99°C denaturation temperature, the fan brings that down to the 68°C needed for annealing, and then the temperature ramps back up to 72°C  for elongation with thermostable DNA polymerase. PID loops keep the reaction temperature precisely controlled. The whole thing is, as the name suggests, small enough to fit in a pocket, and can either be purchased in kit form or scratch-built from the build files on GitHub.

We applaud [Urs]’ efforts to get the power of PCR into the hands of citizen scientists. Quick and dirty thermal cyclers are one thing, but Pocket PCR has a great fit and finish that makes it more accessible.

Thanks to [Abe Tusk] for the tip.

A Beginner’s Guide To X-Ray Crystallography

January 21, 2020 by 6 Comments

In graduate school, I had a seminar course where one of the sections was about X-ray crystallography. I was excited, because being able to discern the three-dimensional structure of macromolecules just by shining X-rays on them seemed like magic to me. And thanks to a lackluster professor, after the section it remained just as much of a mystery.

If only I’d had [Steve Mould] as a teacher back then. His latest video does an outstanding job explaining X-ray crystallography by scaling up the problem considerably, using the longer wavelength of light and a macroscopic target. He begins with a review of diffraction patterns, those alternating light and dark bands of constructive and destructive interference that result when light shines on two closely spaced slits — the famous “Double-Slit Experiment” that showed light behaves both as a particle and as a wave and provided our first glimpse of quantum mechanics. [Steve] then doubled down on the double-slit, placing another pair of slits in the path of the first. This revealed a grid of spots rather than alternating bands, with the angle between axes dependent on the angle of the slit pairs to each other.

Photograph 51, an X-ray crystallogram of the B-form of DNA, by Gosling and Franklin, 1952. Source: Wikipedia

 

To complete the demonstration, [Steve] then used diffraction to image the helical tungsten filament of an incandescent light bulb. Shining a laser through the helix resulted in a pattern bearing a striking resemblance to what’s probably the most famous X-ray crystallogram ever: [Rosalind Franklin]’s portrait of DNA. It all makes perfect sense, and it’s easy to see how the process works when scaled down both in terms of the target size and the wavelength of light used to probe it.

Hats off to [Steve] for making something that’s ordinarily complex so easily understandable, and for filling in a long-standing gap in my knowledge.

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A Safer, Self-Healing Polymer Battery

January 15, 2020 by 4 Comments

Lithium-ion batteries are notorious for spontaneously combusting, with seemingly so many ways that it can be triggered. While they are a compact and relatively affordable rechargeable battery for hobbyists, damage to the batteries can be dangerous and lead to fires.

Several engineers from the University of Illinois have developed a solid polymer-based electrolyte that is able to self-heal after damage, preventing explosions.The material can also be recycled without the use of high temperatures or harsh chemical catalysts. The results of the study were published in the Journal of the American Chemical Society.

As the batteries go through cycles of charge and discharge, they develop branch-like structures known as dendrites. These dendrites, composed of solid lithium, can cause electrical shorts and hotspots, growing large enough to puncture internal parts of the battery and causing explosive chemical reactions between the electrodes and electrolyte liquids. While engineers have been looking to replace liquid electrolytes in lithium-ion batteries with solid materials, many have been brittle and not highly conductive.

The high temperatures inside a battery melt most solid ion-conducting polymers, making them a less attractive option for non-liquid electrolytes. Further studies producing solid electrolytes from networks of cross-linked polymer strands delays the growth of dendrites but produces structures that are too complex to be recovered after damage. In response, the researchers at University of Illinois developed a similar network polymer electrolyte where the cross-link point undergoes exchange reactions and swaps out polymer strands. The polymers stiffen upon heating, minimizing the dendrite problem and more easily breaking down and resolidifying the electrolyte after damage.

Unlike conventional polymer electrolytes, the new polymer also shows properties of conductivity and stiffness increasing with heating. The material dissolves in water at room temperature, making it both energy-efficient and environmentally friendly as well.

Tetraethyl Lead: The Solution To One, And Cause Of Many New Problems

January 15, 2020 by 101 Comments

From the 1920s until the 1970s, most gasoline cars in the USA were using fuel that had lead mixed into it. The reason for this was to reduce the engine knocking effect from abnormal combustion in internal combustion engines of the time. While lead — in the form of tetraethyllead — was effective at this, even the 1920s saw both the existence of alternative antiknock agents and an uncomfortable awareness of the health implications of lead exposure.

We’ll look at what drove the adoption of tetraethyllead, and why it was phased out once the environmental and health-related issues came into focus. But what about its antiknock effects? We’ll also be looking at the alternative antiknock agents that took its place and how this engine knocking issue is handled these days.

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A DNA-Based Computer Calculates Square Roots Up To 900

January 12, 2020 by 20 Comments

While DNA-based computing may not be taking over silicon quite so soon, there is progress in the works. In a paper published by Small, researchers from the University of Rochester demonstrate a molecular computing system capable of calculating square roots of integers up to 900. The computer is built from synthetic biochemical logic gates using hybridization, a process where two strands of DNA join to form double-stranded DNA, and strand displacement reactions.

DNA-based circuits have already been shown to implement complex logic functions, but most existing circuits prior to the recent paper were unable to calculate square root operations. This required 4-bit binary numbers – the new prototype implements a 10-bit square root logic circuit, operating up to the decimal integer 900.

The computer uses 32 strands of DNA for storing and processing information. The process uses three modules, starting off with encoding a number on the DNA. Each combination is attached to a florescent marker, which changes signal during hybridization in the second module. The process for calculating the square root controls the signals, with the results deducted from the final color according to a threshold set in the third module.

We’re beginning to see the end of Moore’s Law approaching, with companies like Intel and AMD struggling to shrink transistors 10 nm wide. Nevertheless, with DNA molecules still about 10 time smaller than the best transistors today and DNA computing systems continuing to gain in sophistication, biochemical circuits could potentially be holding solutions to increasing the speed of computing beyond silicon computing.