An Inexpensive Way To Break Down Plastic

March 27, 2025 by Bryan Cockfield 11 Comments

Plastic has been a revolutionary material over the past century, with an uncountable number of uses and an incredibly low price to boot. Unfortunately, this low cost has led to its use in many places where other materials might be better suited, and when this huge amount of material breaks down in the environment it can be incredibly persistent and harmful. This has led to many attempts to recycle it, and one of the more promising efforts recently came out of a lab at Northwestern University.

Plastics exist as polymers, long chains of monomers that have been joined together chemically. The holy grail of plastic recycling would be to convert the polymers back to monomers and then use them to re-make the plastics from scratch. This method uses a catalyst to break down polyethylene terephthalate (PET), one of the more common plastics. Once broken down, the PET is exposed to moist air which converts it into its constituent monomers which can then be used to make more PET for other uses.

Of course, the other thing that any “holy grail” of plastic recycling needs is to actually be cheaper and easier than making new plastic from crude oil, and since this method is still confined to the lab it remains to be seen if it will one day achieve this milestone as well. In the meantime, PET can also be recycled fairly easily by anyone who happens to have a 3D printer around.

Benchtop Haber-Bosch Makes Ammonia At Home

March 21, 2025 by Dan Maloney 23 Comments

Humans weren’t the first organisms on this planet to figure out how to turn the abundance of nitrogen in the atmosphere into a chemically useful form; that honor goes to some microbes that learned how to make the most of the primordial soup they called home. But to our credit, once [Messrs. Haber and Bosch] figured out how to make ammonia from thin air, we really went gangbusters on it, to the tune of 8 million tons per year of the stuff.

While it’s not likely that [benchtop take on the Haber-Bosch process demonstrated by [Marb’s lab] will turn out more than the barest fraction of that, it’s still pretty cool to see the ammonia-making process executed in such an up close and personal way. The industrial version of Haber-Bosch uses heat, pressure, and catalysts to overcome the objections of diatomic nitrogen to splitting apart and forming NH₃; [Marb]’s version does much the same, albeit at tamer pressures.

[Marb]’s process starts with hydrogen made by dripping sulfuric acid onto zinc strips and drying it through a bed of silica gel. The dried hydrogen then makes its way into a quartz glass reaction tube, which is heated by a modified camp stove. Directly above the flame is a ceramic boat filled with catalyst, which is a mixture of aluminum oxide and iron powder; does that sound like the recipe for thermite to anyone else?

A vial of Berthelot’s reagent, which [Marb] used in his recent blood ammonia assay, indicates when ammonia is produced. To start a run, [Marb] first purges the apparatus with nitrogen, to prevent any hydrogen-related catastrophes. After starting the hydrogen generator and flaring off the excess, he heats up the catalyst bed and starts pushing pure nitrogen through the chamber. In short order the Berthelot reagent starts turning dark blue, indicating the production of ammonia.

It’s a great demonstration of the process, but what we like about it is the fantastic tips about building lab apparatus on the cheap. Particularly the idea of using hardware store pipe clamps to secure glassware; the mold-it-yourself silicone stoppers were cool too.

Continue reading “Benchtop Haber-Bosch Makes Ammonia At Home” →

Five colors of Cast21 on five different wrists.

Cast21 Brings Healing Into 2024

September 14, 2024 by Kristina Panos 16 Comments

It takes but an ill-fated second to break a bone, and several long weeks for it to heal in a cast. And even if you have one of those newfangled fiberglass casts, you still can’t get the thing wet, and it’s gonna be itchy under there because your skin can’t breathe. Isn’t it high time for something better?

Enter Cast21, co-founded by Chief Technical Officer [Jason Troutner], who has been in casts more than 50 times due to sports injuries and surgeries. He teamed up with a biomedical design engineer and an electrical engineer to break the norms associated with traditional casts and design a new solution that addresses their drawbacks.

So, how does it work already? The latticework cast is made from a network of silicone tubes that harden once injected with resin and a catalyst mixture. It takes ten seconds to fill the latticework with resin and three minutes for it to cure, and the whole process is much faster than plaster or fiberglass.

This new cast can be used along with electrical stimulation therapy, which can reduce healing time and prevent muscle atrophy.

Cast21 is not only breathable, it’s also waterproof, meaning no more trash bags on your arm to take a shower. The doctor doesn’t even need a saw to remove it, just cut in two places along the seam. It can even be used as a splint afterward.

It’s great to see advancements in simple medical technologies like the cast. And it looks almost as cool as this 3D-printed exoskeleton cast we saw ten years ago.

Thanks to [Keith Olson] for the tip!

Aqueous Battery Solves Lithium’s Problems

January 4, 2024 by Bryan Cockfield 15 Comments

The demand for grid storage ramps up as more renewable energy sources comes online, but existing technology might not be up to the challenge. Lithium is the most popular option for battery storage right now, not just due to the physical properties of the batteries, but also because we’re manufacturing them at a massive scale already. Unfortunately they do have downsides, especially with performance in cold temperatures and a risk of fires, which has researchers looking for alternatives like aqueous batteries which mitigate these issues.

An aqueous battery uses a water-based electrolyte to move ions from one electrode to the other. Compared to lithium, which uses lithium salts for the electrolyte, this reduces energy density somewhat but improves safety since water is much less flammable. The one downside is that during overcharging or over-current situations, hydrogen gas can be produced by electrolysis of the water, which generally needs to be vented out of the battery. This doesn’t necessarily damage the battery but can cause other issues. To avoid this problem, researchers found that adding a manganese oxide to the battery and using palladium as a catalyst caused any hydrogen generated within the battery’s electrolyte to turn back into water and return to the electrolyte solution without issue.

Of course, these batteries likely won’t completely replace lithium ion batteries especially in things like EVs due to their lower energy density. It’s also not yet clear whether this technology, like others we’ve featured, will scale up enough to be used for large-scale applications either, but any solution that solves some of the problems of lithium, like the environmental cost or safety issues, while adding more storage to an increasingly renewable grid, is always welcome.

Lighting Up With Chemistry, 1823-Style

July 19, 2023 by Dan Maloney 9 Comments

With our mass-produced butane lighters and matches made in the billions, fire is never more than a flick of the finger away these days. But starting a fire 200 years ago? That’s a different story.

One method we’d never heard of was Döbereiner’s lamp, an 1823 invention by German chemist Johann Wolfgang Döbereiner. At first glance, the device seems a little sketchy, what with a tank of sulfuric acid and a piece of zinc to create a stream of hydrogen gas ignited by a platinum catalyst. But as [Marb’s Lab] shows with the recreation in the video below, while it’s not exactly as pocket-friendly as a Zippo, the device actually has some inherent safety features.

[Marb]’s version is built mainly from laboratory glassware, with a beaker of dilute sulfuric acid — “Add acid to water, like you ought-er!” — bathing a chunk of zinc on a fixed support. An inverted glass funnel acts as a gas collector, which feeds the hydrogen gas to a nozzle through a pinch valve. The hydrogen gas never mixes with oxygen — that would be bad — and the production of gas stops once the gas displaces the sulfuric acid below the level of the zinc pellet. It’s a clever self-limiting feature that probably contributed to the commercial success of the invention back in the day.

To produce a flame, Döbereiner originally used a platinum sponge, which catalyzed the reaction between hydrogen and oxygen in the air; the heat produced by the reaction was enough to ignite the mixture and produce an open flame. [Marb] couldn’t come up with enough of the precious metal, so instead harvested the catalyst from a lighter fluid-fueled hand warmer. The catalyst wasn’t quite enough to generate an open flame, but it glowed pretty brightly, and would be more than enough to start a fire.

Hats off to [Marb] for the great lesson is chemical ingenuity and history. We’ve seen similar old-school catalytic lighters before, too.

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Powering A Cellphone With Gasoline

September 1, 2022 by Lewin Day 24 Comments

Batteries are a really useful way to store energy, but their energy density in regards to both weight and volume is disappointing. In these regards, they really can’t compete with fossil fuels. Thus, [bryan.lowder] decided to see if he could charge a phone with fossil fuels as safely and inoffensively as possible.

Obviously, with many national grids relying on fossil fuels for a large part of their generation, most of us are already charging our phones with fossil fuels to some degree. However, the aim here was to do so more directly, without incurring transmission losses from the long runs through the power grid. Continue reading “Powering A Cellphone With Gasoline” →

A V2 Rocket Inspired Steam Turbine Skateboard Is Just Around The Corner

April 12, 2022 by Dave Rowntree 19 Comments

[Integza] never fails to amuse with his numerous (and sometimes really sketchy) attempts to create usable thrust, by pretty much all means possible and the latest video (embedded below) attempting to run a reaction turbine from decomposing hydrogen peroxide, doesn’t fail to disappoint. The inspiration came from the WWII V2 rocket, which used Sodium Permanganate to breakdown Hydrogen Peroxide. This produced high pressure steam, which spun a turbine, which in turn drove the turbopumps that delivered the needed huge quantity of alcohol and liquid oxygen into the combustion chamber.

After an initial test of this permanganate-peroxide reaction proved somewhat disappointing (and messy) he moved on to a more controllable approach — using a catalytic converter from a petrol scooter in place of the messy permanganate. This worked, so the next task was to build the turbine. Naturally, this was 3D printed, and the resulting design appeared to work pretty well with compressed air as the power source. After scaling up the design, and shifting to CNC-machined aluminium, it was starting to look a bit more serious. The final test shows the turbine being put through its paces, running from the new precious metal catalyst setup, but as can be seen from the video, there is work to be done.

There appears to be a fair amount of liquid peroxide passing through into the turbine, which is obviously not desirable. Perhaps the next changes should be the mount the catalyser vertically, to prevent the liquid from leaving so easily, as well as adding some baffling to control the flow of the liquid, in order to force it to recycle inside the reaction vessel? We can’t wait to see where this goes, hopefully the steam-turbine powered skateboard idea could actually be doable? Who knows? But we’re sure [Integza] will find a way!

With steam power, there’s more than one way to get usable rotational work, like using a reciprocating engine, which can be expanded to a whole machine shop, and whilst boiling water (or catalytically decomposing Hydrogen Peroxide) provides high pressure gas, how about just using boiling liquid nitrogen? Possibly not.

Continue reading “A V2 Rocket Inspired Steam Turbine Skateboard Is Just Around The Corner” →