Displaying The Time Is Elemental With This Periodic Table Clock

March 7, 2023 by Dan Maloney 8 Comments

We see a lot of clocks here at Hackaday, so many now that it’s hard to surprise us. After all, there are only so many ways to divide the day into intervals, as well as a finite supply of geeky and quirky ways to display the results, right?

That’s why this periodic table clock really caught our eye. [gocivici]’s idea is a simple one: light up three different elements with three different colors for hours, minutes, and seconds, and read off the time using the atomic number of the elements. So, if it’s 13:03:23, that would light up aluminum in blue, lithium in green, and vanadium in red. The periodic table was designed in Adobe Illustrator and UV printed on a sheet of translucent plastic by an advertising company that specializes in such things, but we’d imagine other methods could be used. The display is backed by light guides and a baseplate to hold the WS2812D addressable LEDs, and a DS1307 RTC module gives the Arduino Nano a sense of time. The 3D printed frame of the clock has buttons for setting the time and controlling the clock; the brief video below shows it going through its paces.

We really like the attention to detail [gocivici] showed here; that UV printing really gave some great results. And what’s not to like about the geekiness of this clock? Sure, it may not be as action-packed as a game of periodic table Battleship, but it would make a great conversation starter.

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Researchers Find “Inert” Components In Batteries Lead To Cell Self-Discharge

February 6, 2023 by Donald Papp 11 Comments

When it comes to portable power, lithium-ion batteries are where it’s at. Unsurprisingly, there’s a lot of work being done to better understand how to maximize battery life and usable capacity.

Red electrolytic solution, which should normally be clear.

While engaged in such work, [Dr. Michael Metzger] and his colleagues at Dalhousie University opened up a number of lithium-ion cells that had been subjected to a variety of temperatures and found something surprising: the electrolytic solution within was a bright red when it was expected to be clear.

It turns out that PET — commonly used as an inert polymer in cell assembly — releases a molecule that leads to self-discharge of the cells when it breaks down, and this molecule was responsible for the color change. The molecule is called a redox shuttle, because it travels back and forth between the cathode and the anode. This is how an electrochemical cell works, but the problem is this happens all the time, even when the battery isn’t connected to anything, causing self-discharge.

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Making The One Ring By Electroplating Gold On A 3D Print

January 12, 2023 by Lewin Day 11 Comments

Electroplating is a great way to add strength or shine to a 3D print. However, we don’t see too many people trying it with gold. [HEN3DRIK] isn’t afraid to experiment, though, and pulled off some amazing, high-quality jewelry-grade plating!

The design for the project was the so-called Ring of Power from Lord of the Rings. The print was created on a resin printer at a high quality level, washed thoroughly to remove any remaining resin, and then cured. The print was then post-processed with sandpaper to make it as smooth as possible. Conductive paint was then applied, ready to take on the plating layers. [HEN3DRIK] first started by plating copper to build up a tough base layer, then nickel to prevent mixing between the copper and gold. The gold is then finally plated on top. Plating the copper is done with the ring constantly rotating to get as even a coat as possible. In contrast, the gold plating is done with a brush to avoid wasting the highly-expensive plating solution.

The final result is a gleaming gold ring that probably feels strangely light in the hand. The technique is time consuming, thanks to the need to plate multiple layers, but the results are to die for. We’ve seen [HEN3DRIK]’s fine work before, too. Video after the break.

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Two-Dimensional Polymer Is A New Ultra-Strong Material

March 23, 2022 by Lewin Day 26 Comments

Plastics, by and large, are well-understood materials. Not as strong as most metals, but often much lighter, these man-made polymers have found innumerable applications that have revolutionized the way we live. The properties of plastics have been improved in many ways over the years, with composite materials like fiberglass and carbon fiber proving to have strength and lightness far beyond the simple properties of basic polymers alone.

However, a group of engineers at MIT have been working on a revolutionary type of polymer that promises greater strength then ever before while remaining remarkably light weight. It’s all down to the material’s two-dimensional molecular structure, something once thought to be prohibitively difficult in the world of polymer science.

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Grocery Store Rocket Fuel: Don’t Try This At Home!

February 25, 2022 by Ryan Flowers 29 Comments

It seems like whenever the topic of rocket science comes up, the conversation quickly shifts to that of rocket fuels. As discussed in the excellent [Scott Manley] video below the break, there are many rocket fuels that can be found in some way, state, or form at your local grocery or liquor store. The video itself is a reaction to some college students in Utah who caused an evacuation when the rocket fuel they were cooking up exploded.

[Scott] himself theorizes that the fuel they were cooking was Rocket Candy, a volatile mix of sugar and potassium nitrate that is known to go Kaboom on occasion. And as it turns out, the combination might not even be legal in your area because as much as it can be used as rocket fuel, it can also be used for other things that go boom.

So, what else at your local megamart can be used to get to orbit? [Scott] talks about different kinds of alcohols, gasses, cleaners- all things that can be used as rocket fuel. He also talks about all of the solid reasons you don’t want to do this at home.

If this type of things gets your molecules excited, you might enjoy a bit we posted recently about using another grocery store staple to save Martian colonists from being held back by gravity.

Big Chemistry: From Gasoline To Wintergreen

February 22, 2022 by Dan Maloney 18 Comments

Most of us probably have some vivid memories of high school or college chemistry lab, where the principles of the science were demonstrated, and where we all got at least a little practice in experimental methods. Measuring, diluting, precipitating, titrating, all generally conducted under safe conditions using stuff that wasn’t likely to blow up or burn.

But dropwise additions and reaction volumes measured in milliliters are not the stuff upon which to build a global economy that feeds, clothes, and provides for eight billion people. For chemistry to go beyond the lab, it needs to be scaled up, often to a point that’s hard to conceptualize. Big chemistry and big engineering go hand in hand, delivering processes that transform the simplest, most abundant substances into the things that, for better or worse, make life possible.

To get a better idea of how big chemistry does that, we’re going to take a look at one simple molecule that we’ve probably all used at one time or another: the common artificial flavoring wintergreen. It’s an innocuous ingredient in a wide range of foods and medicines, but the infrastructure required to make it and all its precursors is a snapshot of just how important big chemistry really is.

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As Light As Plastic; As Strong As Steel

February 7, 2022 by Al Williams 38 Comments

Chemical engineers at MIT have pulled off something that was once thought impossible. By polymerizing material in two different directions at once, they have created a polymer that is very strong. You can read a pre-print version of the paper over on Arxiv.

Polymers owe many of their useful properties to the fact that they make long chains. Molecules known as monomers join together in strings held together by covalent bonds. Polymer chains may be cross-linked which changes its properties, but it has long been thought that material that had chains going through the X and Y axis would have desirable properties, but making these reliably is a challenge.

Part of the problem is that it is hard to line up molecules, even large monomers. If one monomer in the chain rotates a bit, it will create a defect in the 2D structure and that defect will grow rapidly as you add more monomers. The new technique is relatively easy to do and is irreversible which is good because reversible chains tend to have undesirable characteristics like low chemical stability. Synthesis does require a few chemicals like melamine, calcium chloride, pyridine, and trimesic acid. Along with N-Methyl-2-pyrrolidone, the mixture eventually forms a gel. The team took pieces of gel and soaked it in ethanol. With some filtering, ultrasonics, centrifuging, and washing with water and acetone, the material was ready for vacuum drying and was made into a powder.

The powder is dissolved in acid and placed on a spinning silicon wafer to form a polymerized nanofilm. Other 2D films have been produced, of course, such as graphene, but polymer films may have a number of applications. In particular, in contrast to conventional polymers, sheets of this material are impermeable to gas and liquid, which could make it very useful as a coating.

According to the MIT press release, the film’s elastic modulus is about four and six times greater than that of bulletproof glass. The amount of force required to break the material is about twice that of steel. It doesn’t sound like this material will be oozing out of our 3D printers anytime soon. But maybe one day you’ll be able to get 2D super-strong resin.

For all their faults, conventional polymers changed the world as we know it. Some polymers occur naturally, and some use natural ingredients, too.