Mining And Refining: Lead, Silver, And Zinc

If you are in need of a lesson on just how much things have changed in the last 60 years, an anecdote from my childhood might suffice. My grandfather was a junk man, augmenting the income from his regular job by collecting scrap metal and selling it to metal recyclers. He knew the current scrap value of every common metal, and his garage and yard were stuffed with barrels of steel shavings, old brake drums and rotors, and miles of copper wire.

But his most valuable scrap was lead, specifically the weights used to balance car wheels, which he’d buy as waste from tire shops. The weights had spring steel clips that had to be removed before the scrap dealers would take them, which my grandfather did by melting them in a big cauldron over a propane burner in the garage. I clearly remember hanging out with him during his “melts,” fascinated by the flames and simmering pools of molten lead, completely unconcerned by the potential danger of the situation.

Fast forward a few too many decades and in an ironic twist I find myself living very close to the place where all that lead probably came from, a place that was also blissfully unconcerned by the toxic consequences of pulling this valuable industrial metal from tunnels burrowed deep into the Bitterroot Mountains. It didn’t help that the lead-bearing ores also happened to be especially rich in other metals including zinc and copper. But the real prize was silver, present in such abundance that the most productive silver mine in the world was once located in a place that is known as “Silver Valley” to this day. Together, these three metals made fortunes for North Idaho, with unfortunate side effects from the mining and refining processes used to win them from the mountains.

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An L-shaped orange mounting structure with two white reservoirs on top, a set of pumps on the outer bottom edges, and a membrane cell bolted together in the center. The parts are connected by a series of transparent tubes.

Open Source Residential Energy Storage

Battery news typically covers the latest, greatest laboratory or industry breakthroughs to push modern devices further and faster. Could you build your own flow battery stationary storage for home-built solar and wind rigs though?

Based on the concept of appropriate technology, the system from the Flow Battery Research Collective will be easy to construct, easy to maintain, and safe to operate in a residential environment. Current experiments are focusing on Zn/I chemistry, but other aqueous chemistries could be used in the future. Instead of an ion exchange membrane, the battery uses readily attainable photo paper and is already showing similar order of magnitude performance to lab-developed cells.

Any components that aren’t off-the-shelf have been designed in FreeCAD. While they can be 3D printed, the researchers have found traditional milling yields better results which isn’t too surprising when you need something water-tight. More work is needed, but it is promising work toward a practical, DIY-able energy storage solution.

If you’re looking to build your own open source wind turbine or solar cells to charge up a home battery system, then we’ve got you covered. You can also break the chains of the power grid with off-the-shelf parts.

Blame It On The Sockets: Forensic Analysis Of The Arecibo Collapse

Nearly three years after the rapid unplanned disassembly of the Arecibo radio telescope, we finally have a culprit in the collapse: bad sockets.

In case you somehow missed it, back in 2020 we started getting ominous reports that the cables supporting the 900-ton instrument platform above the 300-meter primary reflector of what was at the time the world’s largest radio telescope were slowly coming undone. From the first sign of problems in August, when the first broken cable smashed a hole in the reflector, to the failure of a second cable in November, it surely seemed like Arecibo’s days were numbered, and that it would fall victim to all the other bad luck we seemed to be rapidly accruing in that fateful year. The inevitable finally happened on December 1, when over-stressed cables on support tower four finally gave way, sending the platform on a graceful swing into the side of the natural depression that cradled the reflector, damaging the telescope beyond all hope of repair.

The long run-up to the telescope’s final act had a silver lining in that it provided engineers and scientists with a chance to carefully observe the failure in real-time. So there was no real mystery as to what happened, at least from a big-picture perspective. But one always wants to know the fine-scale details of such failures, a task which fell to forensic investigation firm Thornton Tomasetti. They enlisted the help of the Columbia University Strength of Materials lab, which sent pieces of the failed cable to the Oak Ridge National Laboratory’s High Flux Isotope reactor for neutron imaging, which is like an X-ray study but uses streams of neutrons that interact with the material’s nuclei rather than their electrons.

The full report (PDF) reveals five proximate causes for the collapse, chief of which is “[T]he manual and inconsistent splay of the wires during cable socketing,” which we take to mean that the individual strands of the cables were not spread out correctly before the molten zinc “spelter socket” was molded around them. The resulting shear stress caused the zinc to slowly flow around the cable strands, letting them slip out of the surrounding steel socket and — well, you can watch the rest below for yourself.

As is usually the case with such failures, there are multiple causes, all of which are covered in the 300+ page report. But being able to pin the bulk of the failure on a single, easily understood — and easily addressed — defect is comforting, in a way. It’s cold comfort to astronomers and Arecibo staff, perhaps, but at least it’s a lesson that might prevent future failures of cable-supported structures.

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The Voltaic Pile: Building The First Battery

In the technologically-underpinned modern world, most of us interact with a battery of some sort every day. Whether that’s the starter battery in a car, the lithium battery in a phone, or even just the coin cell battery in a wrist watch, batteries underpin a lot of what makes society possible now. Not so in the early 1800s when chemists and physicists were first building and experimenting with batteries. And those batteries were enormous, non-rechargable, and fairly fragile to boot. Not something suited for powering much of anything, but if you want to explore what it would have been like to use one of these devices, follow along with [Christopher]’s build of a voltaic pile. Continue reading “The Voltaic Pile: Building The First Battery”

Zinc Fever: A Look At The Risks Of Working With Hot Metal

For as raucous as things can get in the comments section of Hackaday articles, we really love the give and take that happens there. Our readers have an astonishing breadth of backgrounds and experiences, and the fact that everyone so readily shares those experiences and the strongly held opinions that they engender is what makes this community so strong and so useful.

But with so many opinions and experiences being shared, it’s sometimes hard to cut through to the essential truth of an issue. This is particularly true where health and safety are at issue, a topic where it’s easy to get bogged down by an accumulation of anecdotes that mask the underlying biology. Case in point: I recently covered a shop-built tool cabinet build and made an off-hand remark about the inadvisability of welding zinc-plated drawer slides, having heard about the dangers of inhaling zinc fumes once upon a time. That led to a discussion in the comments section on both sides of the issue that left the risks of zinc-fume inhalation somewhat unclear.

To correct this, I decided to take a close look at the risks involved with welding and working zinc. As a welding wannabe, I’m keenly interested in anything that helps me not die in the shop, and as a biology geek, I’m also fascinated by the molecular mechanisms of diseases. I’ll explore both of these topics as we look at the dreaded  “zinc fever” and how to avoid it.

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One Way To Recharge Alkaline Batteries

It says it right on the side of every alkaline battery – do not attempt to recharge. By which of course the manufacturer means don’t try to force electrons back into the cell. But [Cody] figured he could work around that safety warning chemically, by replacing the guts of an alkaline dry cell.

The batteries in question were certainly old, gnarly looking, and pretty dead – [Cody] barely got a reading on his multimeter. As you can see after the break, he cleaned off the exterior corrosion and did a quick teardown of the dry cells, removing the remains of the zinc anode, now in the form of zinc oxide paste looking very much like what you’d slather on your nose before a day at the beach. He filled the resulting cavity with a putty of zinc dust, freshened up the electrolyte charge with a squirt of 20% potassium hydroxide, sealed up the cell with a little silicone caulking, and put the recycled cell to the test. Result: 1.27 volts. Not too shabby.

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On Not Getting Metal Fume Fever With Galvanized Conduit

galv

You can find galvanized steel pipes at Home Depots and construction sites all around the world. These relatively thin-walled steel pipes would make for great structural members if it weren’t for the fact they were covered in a protective layer of zinc. This layer of galvanization lends itself to crappy welds and some terrible fumes, but badass, TV personality, and hacker extraordinaire [Hackett] shows us how to strip the galvanization off these pipes with chemicals available at any hardware store.

Since the galvanization on these pipes covers the inside and the outside, grinding the small layer of zinc off these pipes is difficult at best. To be sure he gets all the zinc off this pipe, [Hackett] decided to chemically strip the pipes with a cup full of muriatic acid.

The process is simple enough – fill a cup with acid, dunk the ends of the pipes, and clean everything up with baking soda. A great way to turn scrap pipe into a usable material, make a cool paper mache volcano, and avoid ‘ol galvie flu

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