lithium

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Hackaday Links: October 27, 2024

October 27, 2024 by 14 Comments

Problem solved? If the problem is supplying enough lithium to build batteries for all the electric vehicles that will be needed by 2030, then a new lithium deposit in Arkansas might be a resounding “Yes!” The discovery involves the Smackover Formation — and we’ll be honest here that half the reason we chose to feature this story was to be able to write “Smackover Formation” — which is a limestone aquifer covering a vast arc from the Rio Grande River in Texas through to the western tip of the Florida panhandle. Parts of the aquifer, including the bit that bulges up into southern Arkansas, bear a brine rich in lithium salts, far more so than any of the brines currently commercially exploited for lithium metal production elsewhere in the world. Given the measured concentration and estimated volume of brine in the formation, there could be between 5 million and 19 million tons of lithium in the formation; even at the lower end of the range, that’s enough to build nine times the number of EV batteries needed.

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Better Battery Design Through Science

August 2, 2024 by 6 Comments

Before the age of lithium batteries, any project needing to carry its own power had to rely on batteries that were much less energy-dense and affordable. In many ways, we take modern lithium technology for granted, and can easily put massive batteries in our projects by the standards of just a few decades ago. While the affordability of lithium batteries has certainly decreased the amount of energy we need to put in to our projects to properly size batteries, there’s still a lot of work to be done if you’re working on a bigger project or just want to get the maximize the efficiency and effectiveness of your DIY battery pack.

The main problem with choosing a battery, as [ionworks] explains, is that batteries can’t be built for both high energy and high power, at least not without making major concessions for weight or cost. After diving in to all of the possible ways of customizing a battery, the battery guide jumps in to using PyBaMM to perform computational modeling of potential battery designs to hopefully avoid the cumbersome task of testing all of the possible ways of building a battery. With this tool virtually all of a battery’s characteristics can be simulated and potential problems with your setup can be uncovered before you chose (or start production of) a specific battery system.

While customizing a battery pack to this extent might not be a consideration for most of us unless the project is going to be big enough to run something like an electric car or a whole-house generator, it’s a worthwhile tool to know about as even smaller projects like ebikes can benefit from choosing the right cell for the application. Some of the nuances of battery pack design can be found in this guide to building packs from the standard 18650 cells.

Header: Lead holder, CC BY-SA 3.0 .

Sun On The Run: Diving Into Solar With A Mobile PV System

January 17, 2024 by 36 Comments

For obvious reasons, there has been a lot of interest in small-scale residential solar power systems lately. Even in my neck of the woods, where the sun doesn’t shine much from October to April, solar arrays are sprouting up on rooftops in a lot of local neighborhoods. And it’s not just here in suburbia; drive a little way out into the country or spend some time looking around in Google maps and it won’t take long to spy a sizable array of PV panels sitting in a field next to someone’s ranch house or barn.

Solar has gotten to the point where the expense of an installation is no longer a serious barrier to entry, at least if you’re willing to put in a little sweat equity and not farm the project out to a contractor. Doing it yourself requires some specialized tools and knowledge, though, over and above your standard suite of DIY skills. So, in the spirit of sharing hard-won knowledge, I decided to take the somewhat unusual step of writing up one of my personal projects, which has been in progress for a couple of years now and resulted in a solar power system that isn’t on a rooftop or a ground-mounted array at all, but rather is completely mobile: my solar trailer.

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Aqueous Battery Solves Lithium’s Problems

January 4, 2024 by 15 Comments

The demand for grid storage ramps up as more renewable energy sources comes online, but existing technology might not be up to the challenge. Lithium is the most popular option for battery storage right now, not just due to the physical properties of the batteries, but also because we’re manufacturing them at a massive scale already. Unfortunately they do have downsides, especially with performance in cold temperatures and a risk of fires, which has researchers looking for alternatives like aqueous batteries which mitigate these issues.

An aqueous battery uses a water-based electrolyte to move ions from one electrode to the other. Compared to lithium, which uses lithium salts for the electrolyte, this reduces energy density somewhat but improves safety since water is much less flammable. The one downside is that during overcharging or over-current situations, hydrogen gas can be produced by electrolysis of the water, which generally needs to be vented out of the battery. This doesn’t necessarily damage the battery but can cause other issues. To avoid this problem, researchers found that adding a manganese oxide to the battery and using palladium as a catalyst caused any hydrogen generated within the battery’s electrolyte to turn back into water and return to the electrolyte solution without issue.

Of course, these batteries likely won’t completely replace lithium ion batteries especially in things like EVs due to their lower energy density. It’s also not yet clear whether this technology, like others we’ve featured, will scale up enough to be used for large-scale applications either, but any solution that solves some of the problems of lithium, like the environmental cost or safety issues, while adding more storage to an increasingly renewable grid, is always welcome.

Old Prius Gets Upgraded Batteries

December 18, 2023 by 24 Comments

So many of the batteries made today are lithium batteries of some sort, from mobile phones, laptops, and drones to electric cars and grid storage solutions. But this technology is relatively new; even as late as the 90s and early 00s the only widely-available batteries for things like power tools or the new hybrid vehicles coming on the market were nickel-metal hydride (NiMH). While it was good for the time, they don’t hold up to all of the advantages lithium has. There’s still plenty of hybrid vehicles on the road using these batteries, so if you’re driving an older Prius and want to give it a modern refresh, there’s a quick option to swap your old batteries.

Despite lithium technology being available for several decades, the switch to lithium for the Toyota Prius wasn’t instant, with many variants still using NiMH batteries as late as the 2020s largely because the NiMH batteries are less expensive and less maintenance-intensive than lithium batteries are. As these batteries lose capacity, the cars are still driveable but the advantages of the hybrid drivetrain won’t be as accessible anymore. The upgrade, from a company called Project Lithium, replaces these batteries with modern lithium technology that can improve the efficiency and performance of these cars even above their original capabilities since lithium batteries have more power density.

With the Toyota Prius being among the most reliable vehicles on the road thanks to the electric motor in the hybrid drivetrain taking a lot of stress off of the internal combustion engine, it’s often worth upgrading these old batteries to modern ones to squeeze every last mile from these workhorses as possible. With many of the replacement processes being almost as simple as lifting out an old battery and placing a new one in, it can be a no-brainer if that’s the only issue with the vehicle otherwise. This is also true of all-electric vehicles as well, although the process to replace the battery can be a little more involved.

Thanks to [JohnU] for the tip!

Rock Salt May Lead The Way To Better Batteries

October 5, 2023 by 58 Comments

The regular refrain here when it comes to announcements of new battery chemistries hailed as potentially miraculous is that if we had a pound, dollar, or Euro for each one we’ve heard, by now we’d be millionaires. But still they keep coming, and it’s inevitable that there will one or two that break through the practicality barrier and really do deliver on their promise. Which brings us tot he story which has come our way today, the suggestion that something as simple as rock salt could triple the energy density of a lithium-ion vehicle battery.

The research led from Lawrence Berkeley National Laboratory started around the use of cobalt in the battery cathode, an expensive and finite resource with the added concern of being in large part a conflict mineral from the Democratic Republic of Congo. Cobalt is used in  the cathodes because its oxide crystals form a stable layered structure into which the lithium ions can percolate. Alternative layered-structure metal oxides perform less well in retaining the lithium ions, making them unsuccessful substitutes. It seems that the three-dimensional structure of a rock salt crystal performs up to three times better than any layered oxide, which is where the excitement comes from.

Of course, if it were that simple we’d all be using three-times-more-powerful, half-price 18650s right now, which of course we aren’t. The challenge comes in making a rock salt cathode which both holds the lithium ions, and keeps that property reliably over the thousands of charge cycles needed for a real-world application. This one may yet be anther dollar on that metaphorical pile, but it just might give us the batteries we’ve been looking for.

Then again, when you’re looking at exciting battery chemistry, why limit yourself to lithium?

Determining The Size Of The New US Lithium Deposit Amidst Exploding Demand

September 13, 2023 by 22 Comments

With demand for lithium in the world market projected to increase by 2040 to as much as eight times the demand in 2022, finding new deposits of this metal has become a priority. Currently most of the world’s lithium comes from Australia, Chile, China and Argentina, with potential new mining sites under investigation. One of these sites is the McDermitt caldera in the US, a likely remnant of the Yellowstone hotspot and resulting volcanic activity. According to a recent study (Chemistry World article) by Thomas R. Benson and colleagues in Science Advances, this site may not only contain between 20 to 40 million tons of lithium in the form of the mineral clay illite, but was also formed using a rather unique process.

This particular group of mineral clays can contain a number of other chemicals, which in this particular case is lithium due to the unique way in which the about 40 meter thick layer of sediment was formed. Although lithium is a very common metal, its high reactivity means that it is never found in its elementary form, but instead bound to other elements. Lithium is thinly distributed within the Earth’s crust and oceans. Incidentally, the Earth’s oceans contain by far the largest amount of lithium, at approximately 230 billion tons.

So how much lithium could be extracted from this new area, and how does this compare to the increasing demand?

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