Harvesting Rechargeable Batteries From Single-Use Devices

The price of lithium batteries has plummeted in recent years as various manufacturers scale up production and other construction and process improvements are found. This is a good thing if you’re an EV manufacturer, but can be problematic if you’re managing something like a landfill and find that the price has fallen so low that rechargeable lithium batteries are showing up in the waste stream in single-use devices. Unlike alkaline batteries, these batteries can explode if not handled properly, meaning that steps to make sure they’re disposed of properly are much more important. [Becky] found these batteries in single-use disposable vape pens and so set about putting them to better use rather than simply throwing them away.

While she doesn’t use the devices herself, she was able to source a bunch of used ones locally from various buy-nothing groups. Disassembling the small vape pens is fairly straightforward, but care needed to be taken to avoid contacting some of the chemical residue inside of the devices. After cleaning the batteries, most of the rest of the device is discarded. The batteries are small but capable and made of various lithium chemistries, which means that most need support from a charging circuit before being used in any other projects. Some of the larger units do have charging circuitry, though, but often it’s little more than a few transistors which means that it might be best for peace-of-mind to deploy a trusted charging solution anyway.

While we have seen projects repurposing 18650 cells from various battery packs like power tools and older laptops, it’s not too far of a leap to find out that the same theory can be applied to these smaller cells. The only truly surprising thing is that these batteries are included in single-use devices at all, and perhaps also that there are few or no regulations limiting the sale of devices with lithium batteries that are clearly intended to be thrown away when they really should be getting recycled.

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Morse Code Clock For Training Hams

It might seem antiquated, but Morse code still has a number of advantages compared to other modes of communication, especially over radio waves. It’s low bandwidth compared to voice or even text, and can be discerned against background noise even at extremely low signal strengths. Not every regulatory agency requires amateur operators to learn Morse any more, but for those that do it can be a challenge, so [Cristiano Monteiro] built this clock to help get some practice.

The project is based around his favorite microcontroller, the PIC16F1827, and uses a DS1307 to keep track of time. A single RGB LED at the top of the project enclosure flashes the codes for hours in blue and minutes in red at the beginning of every minute, and in between flashes green for each second.

Another design goal of this build was to have it operate with as little power as possible, so with a TP4056 control board, single lithium 18650 battery, and some code optimization, [Cristiano] believes he can get around 60 days of operation between charges.

For a project to help an aspiring radio operator learn Morse, a simple build like this can go a long way. For anyone else looking to build something similar we’d note that the DS1307 has a tendency to drift fairly quickly, and something like a DS3231 or even this similar Morse code clock which uses NTP would go a long way to keeping more accurate time.

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Researchers Find “Inert” Components In Batteries Lead To Cell Self-Discharge

When it comes to portable power, lithium-ion batteries are where it’s at. Unsurprisingly, there’s a lot of work being done to better understand how to maximize battery life and usable capacity.

Red electrolytic solution, which should normally be clear.

While engaged in such work, [Dr. Michael Metzger] and his colleagues at Dalhousie University opened up a number of lithium-ion cells that had been subjected to a variety of temperatures and found something surprising: the electrolytic solution within was a bright red when it was expected to be clear.

It turns out that PET — commonly used as an inert polymer in cell assembly — releases a molecule that leads to self-discharge of the cells when it breaks down, and this molecule was responsible for the color change. The molecule is called a redox shuttle, because it travels back and forth between the cathode and the anode. This is how an electrochemical cell works, but the problem is this happens all the time, even when the battery isn’t connected to anything, causing self-discharge.

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Hackaday Links: February 5, 2023

Well, this week’s Links article is likely to prove a bit on the spicy side, thanks in no small part to the Chinese balloon that spent the better part of the week meandering across the United States. Putting aside the politics of the whole thing — which we’ll admit is hard to do, given the state of the world today — there are some interesting technical aspects to this story, which the popular press has predictably ignored. Like the size of this thing — it’s enormous. This is not even remotely on the same scale as the hundreds of radiosonde-carrying balloons sent aloft every day, at least if the back-of-the-envelope math thoughtfully sent to us by [Dr_T] holds up. If the “the size of three buses” description given in most media reports is accurate, that means a diameter of about 40 meters, for a volume of 33,500 cubic meters. If it’s filled with helium — a pretty safe bet — that makes its lifting capacity something like three metric tons. So maybe it was a good idea to wait until it was off the Carolinas to shoot it down.

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Copy And Paste Lithium Battery Protection

Lithium batteries have, nearly single-handedly, ushered in the era of the electric car, as well as battery energy storage of grid power and plenty of other technological advances not possible with older battery chemistries. There’s just one major downside: these lithium cells can be extremely finicky. If you’re adding one to your own project you’ll have to be extremely careful to treat them exactly how they are designed to be treated using something like this boilerplate battery protection circuit created by [DIY GUY Chris].

The circuit is based around the TP4056 integrated circuit, which handles the charging of a single lithium cell — in this design using supplied power from a USB port. The circuit is able to charge a cell based on the cell’s current charge state, temperature, and a model of the cell. It’s also paired with a DW01A chip which protects the cell from various undesirable conditions such as over-current, overcharge, and over-voltage.

The best thing about this design isn’t the design itself, but that [DIY GUY Chris] built the circuit schematic specifically to be easily copied into PCB designs for other projects, which means that lithium batteries can more easily be integrated directly into his other builds. Be sure to check out our primer on how to deal with lithium batteries before trying one of your own designs, though.

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A cartoon vehicle is connected to two wires. One is connected to an illustrated Li anode and the other to a γ-sulfur/carbon nanofiber electrode. Lithium ions and organic carbonate representations float between the two electrodes below the car. A red dotted line between the electrodes symbolizes the separator.

Lithium Sulfur Battery Cycle Life Gets A Boost

Lithium sulfur batteries are often touted as the next major chemistry for electric vehicle applications, if only their cycle life wasn’t so short. But that might be changing soon, as a group of researchers at Drexel University has developed a sulfur cathode capable of more than 4000 cycles.

Most research into the Li-S couple has used volatile ether electrolytes which severely limit the possible commercialization of the technology. The team at Drexel was able to use a carbonate electrolyte like those already well-explored for more traditional Li-ion cells by using a stabilized monoclinic γ-sulfur deposited on carbon nanofibers.

The process to create these cathodes appears less finicky than previous methods that required tight control of the porosity of the carbon host and also increases the amount of active material in the cathode by a significant margin. Analysis shows that this phase of sulfur avoids the formation of intermediate fouling polysulfides which accounts for it’s impressive cycle life. As the authors state, this is far from a commercial-ready system, but it is a major step toward the next generation of batteries.

We’ve covered the elements lithium and sulfur in depth before as well as an aluminum sulfur battery that could be big for grid storage.

Mining And Refining: Cobalt, The Unfortunately Necessary Metal

The story of humankind is largely a tale of conflict, often brought about by the uneven distribution of resources. For as long as we’ve been down out of the trees, and probably considerably before that too, our ancestors have been struggling to get what they need to survive, as often as not at the expense of another, more fortunate tribe. Food, water, land, it doesn’t matter; if They have it and We don’t, chances are good that there’s going to be a fight.

Few resources are as unevenly distributed across our planet as cobalt is. The metal makes up only a fraction of a percent of the Earth’s crust, and commercially significant concentrations are few and far between, enough so that those who have some often end up at odds with those who need it. And need it we do; what started in antiquity as mainly a rich blue pigment for glass and ceramics has become essential for important industrial alloys, high-power magnets, and the anodes of lithium batteries, among other uses.

Getting access to our limited supply of cobalt and refining it into a useful metal isn’t a trivial process, and unfortunately its outsized importance to technological society forces it into a geopolitical role that has done a lot to add to human misery. Luckily, market forces and new technology are making once-marginal sources viable, which just may help us get the cobalt we need without all the conflict.

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